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Effect of Platinum on the Growth Rate of the Oxide Scale Formed on Cast Nickel Aluminide Intermetallic Alloys

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Abstract

Thermo-Gravimetric Analysis (TGA) and Scanning Electron Microscopy (SEM) data of the initial stages of oxidation of Ni50Al50 and Ni40Pt10Al50 alloys of low and high sulfur content at 900°C and 1100°C are reported. The results show that the addition of Pt promotes the growth of the transient θ-Al2O3 oxide scale. This effect is particularly sensitive in the initial stages of oxidation at 1100°C where Pt considerably increases the total mass gain. It is attenuated in the presence of a high sulfur content in the alloy, indicating a competitive effect of Pt and S on the segregation of Al. The slower θ-to-α transition observed in the presence of Pt leads to an extended lifetime of the θ phase layer, which is proposed to be beneficial to the relaxation of the stresses created by the growth of α-Al2O3.

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Authors and Affiliations

  1. Département Matériaux Métalliques et Procédés, ONERA, BP 72, 29 avenue de la division Leclerc, 92322, Châtillon Cedex, France

    Y. Cadoret, M. -P. Bacos & P. Josso

  2. CIRIMAT (UMR5085) CNRS-INPT-UPS, ENSIACET, 31077, Toulouse Cedex 4, France

    D. Monceau

  3. Laboratoire de Physico-Chimie des Surfaces, CNRS (UMR 7045) – Université Pierre et Marie Curie, Ecole Nationale Supérieure de Chimie de Paris, 11 rue Pierre et Marie Curie, 75231, Paris Cedex 05, France

    Y. Cadoret, V. Maurice & P. Marcus

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  1. Y. Cadoret
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  2. D. Monceau
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  4. P. Josso
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Correspondence to D. Monceau.

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Cadoret, Y., Monceau, D., Bacos, M.P. et al. Effect of Platinum on the Growth Rate of the Oxide Scale Formed on Cast Nickel Aluminide Intermetallic Alloys. Oxid Met 64, 185–205 (2005). https://doi.org/10.1007/s11085-005-6558-4

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  • DOI: https://doi.org/10.1007/s11085-005-6558-4

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