Skip to main content
Log in

Effects of green laser fluence on the characteristics of graphene nanosheets synthesized by laser ablation method in liquid nitrogen medium

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

We have studied the effects of laser fluence on the characteristics of graphene nanosheets produced by pulsed laser ablation technique. In this work, The second harmonic of a Q-switched Nd:YAG laser at 532 nm wavelength and 5 Hz repetition rate with different laser fluences in the range of 0.5–1.8 J/cm2 was used to irradiate the graphite target in liquid nitrogen medium. The products of ablation were characterized using Fourier transform infrared spectroscopy, field emission scanning electron microscopy, X-ray diffraction pattern, UV–Vis absorption spectroscopy, Raman spectrum and transmission electron microscopy. The Raman spectroscopy indicates that the quality of the graphene nanosheets was decreased while their structure defects were increased as the laser fluence was increased from 0.5 to 1.4 J/cm2. Our results suggest that the amount of defects and the number of layers in graphene nanosheets can be changed by adjusting the laser fluence. This study could be a useful guidance for producing of high quality of graphene nanosheets by laser ablation method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Abramov, D., Arakelian, S., Kochuev, D., Makov, S., Prokoshev, V., Khorkov, K.: Interaction of femtosecond laser radiation with carbon materials: exfoliation of graphene structures and synthesis of low-dimensional carbon structures. Nanosyst. Phys. Chem. Math. 7(1), 220–225 (2016)

    Google Scholar 

  • Akmar, S.N., Yazid, M., Isa, I., Bakar, S.A., Hashim, N.: Facile, cost effective and green synthesis of graphene in alkaline aqueous solution. Int. Electrochem. Sci. 10, 7977–7984 (2015)

    Google Scholar 

  • Allen, J.M., Tung, V.C., Kaner, R.B.: Honeycomb carbon: a review of graphene. Chem. Rev. 110, 132–145 (2010)

    Article  Google Scholar 

  • Anand, K., Singh, O., Singh, M.P., Kaur, J., Singh, R.C.: Hydrogen sensor based on graphene/ZnO nanocomposite. Sens. Actuator B 195, 409–415 (2014)

    Article  Google Scholar 

  • Beams, R., Gustavo Cancado, L., Novotny, L.: Raman characterization of defects and dopants in graphene. Phys. Condens. Matter 27, 083002 (2015)

    Article  ADS  Google Scholar 

  • Bhandari, S., Deepa, M., Joshi, G.A., Saxena, A.P., Srivastava, A.K.: Revelation of graphene-Au for direct write deposition and characterization. Nanoscale Res. Lett. 6, 424 (2011)

    Article  ADS  Google Scholar 

  • Bolotin, K.I., Sikes, K.J., Jiang, Z., Klima, M., Fudenberg, G., Hone, J., Kim, P., Stormer, H.L.: Ultrahigh electron mobility in suspended graphene. Solid State Commun. 146, 351–355 (2008)

    Article  ADS  Google Scholar 

  • Calizo, I., Bejenari, I., Rahman, M., Liu, G., Balandin, A.: Ultraviolet Raman microscopy of single and multilayer graphene. Appl. Phys. 106, 043509 (2009)

    Article  Google Scholar 

  • Casiraghi, C.: Doping dependence of the Raman peaks intensity of graphene close to the Dirac point. Phys. Rev. B 80, 233407 (2009)

    Article  ADS  Google Scholar 

  • Cheng, M., Yang, R., Zhang, L., Shi, Z., Yang, W., Wang, D., Xie, G., Shi, D., Zhang, G.: Restoration of graphene from graphene oxide by defect repair. Carbon 5, 02581–2587 (2012)

    Article  Google Scholar 

  • Delhaes, P.: Graphite and Precursors. CRC Press, Boca Raton (2001). ISBN 90-5699-228-7

  • Ding, J., Wang, M., Zhang, X., Yang, Z., Song, X., Ran, C.: Photoluminescence investigation about zinc oxide with graphene oxide & reduced graphene oxide buffer layers. Colloid Interface Sci. 416, 289–293 (2014)

    Article  ADS  Google Scholar 

  • Dorranian, D., Solati, E., Dejam, L.: Photoluminescence of ZnO nanoparticles generated by laser ablation in deionized water. Appl. Phys. A 109, 307–314 (2012)

    Article  ADS  Google Scholar 

  • Ghanbari, H., Sarraf-Mamoory, R., Sabbaghzadeh, J., Chehrghani, A., Malekfar, R.: Nonlinear optical absorption of carbon nanostructures synthesized by laser ablation of highly oriented pyrolytic graphite in organic solvents. Opt. Photonics 7, 113–124 (2013)

    Google Scholar 

  • Jabari Seresht, R., Jahanshahi, M., Rashidi, A., Asghar Ghoreyshi, A.: Synthesize and characterization of graphene nanosheets with high surface area and nano-porous structure. Appl. Surf. Sci. 276, 672–681 (2013)

    Article  ADS  Google Scholar 

  • Liu, Q., Liu, Z.F., Zhang, X.Y., Zhang, N., Yang, L.Y., Yin, S.G., Chen, Y.: Organic photovoltaic cells based on an acceptor of soluble graphene. Appl. Phys. Lett. 92, 223303–223313 (2008)

    Article  ADS  Google Scholar 

  • Malard, L.M., Pimenta, M.A., Dresselhaus, G., Dresselhaus, M.S.: Raman spectroscopy in graphene. Phys. Rep. 473, 51–87 (2009)

    Article  ADS  Google Scholar 

  • Moradi, M., Solati, E., Darvishi, S., Dorranian, D.: Properties of Au/ZnO nanocomposite prepared by laser irradiation of the mixture of individual colloids. Clust. Sci. 27, 127–138 (2016)

    Article  Google Scholar 

  • Mortazavi, Z., Parvin, P., Reyhani, A.: Fabrication of graphene based on Q-switched Nd:YAG laser ablation of graphite target in liquid nitrogen. Laser Phys. Lett. 9, 547–552 (2012)

    Article  ADS  Google Scholar 

  • Pang, S., Tsao, H.N., Feng, X., Mullen, K.: Patterned graphene electrodes from solution-processed graphite oxide films for organic field-effect transistors. Adv. Mater. 21, 3488–3491 (2009)

    Article  Google Scholar 

  • Peres, N.M.R., Guinea, F., Neto, A.H.C.: Electronic properties of disordered two-dimensional carbon. Phys. Rev. B 73, 125411 (2006)

    Article  ADS  Google Scholar 

  • Qian, M., Zhou, Y.S., Gao, Y., Park, J.B., Feng, T., Huang, S.M., Sun, Z., Jiang, L., Lu, Y.F.: Formation of graphene sheets through laser exfoliation of highly ordered pyrolytic graphite. Appl. Phys. Lett. 98, 173108 (2011)

    Article  ADS  Google Scholar 

  • Roth, S., Park, H.J.: Nanocarbonic transparent conductive films. Chem. Soc. Rev. 39, 2477–2483 (2010)

    Article  Google Scholar 

  • Sadeghi, H., Dorranian, D.: Influence of size and morphology on the optical properties of carbon nanostructures. Theor. Appl. Phys. (2015). https://doi.org/10.1007/s40094-015-0194-4

    Google Scholar 

  • Shao, Y., Wang, J., Engelhard, M., Wang, C., Lin, Y.: Facile and controllable electrochemical reduction of graphene oxide and its applications. Mater. Chem. 20, 743–748 (2010)

    Article  Google Scholar 

  • Stankovich, S., Dikin, D.A., Dommett, G.H.B., Kohlhaas, K.M., Zimney, E.J., Stach, E.A., Piner, R.D., Nguyen, S.T., Ruoff, R.S.: Graphene-based composite materials. Nature 442, 282–286 (2006)

    Article  ADS  Google Scholar 

  • Tabatabaie, N., Dorranian, D.: Effect of fluence on carbon nanostructures produced by laser ablation in liquid nitrogen. Appl. Phys. A 122, 558 (2016).

    Article  ADS  Google Scholar 

  • Tuinstra, F., Koenig, J.L.: Raman spectrum of graphite. Chem. Phys. 53, 1126–1130 (1970)

    ADS  Google Scholar 

  • Wang, X., Zhi, L.J., Müllen, K.: Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett. 8, 323–327 (2008)

    Article  ADS  Google Scholar 

  • Xu, C., Wang, X., Zhu, J.: Graphene—metal particle nanocomposites. Phys. Chem. C 112, 19841–19845 (2008)

    Article  Google Scholar 

  • Zhou, M., Tang, J., Cheng, Q., Xu, G., Cui, P., Qin, L.C.: Few-layer graphene obtained by electrochemical exfoliation of graphite cathode. Chem. Phys. Lett. 572, 61–65 (2013)

    Article  ADS  Google Scholar 

  • Zhu, C., Guo, S., Fang, Y., Dong, S.: Reducing sugar: new functional molecules for the green synthesis of graphene nanosheets. ACS Nano 4, 2429–2437 (2010)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Davoud Dorranian.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vaghri, E., Dorranian, D. Effects of green laser fluence on the characteristics of graphene nanosheets synthesized by laser ablation method in liquid nitrogen medium. Opt Quant Electron 50, 110 (2018). https://doi.org/10.1007/s11082-018-1374-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-018-1374-7

Keywords

Navigation