Skip to main content
Log in

Synthesis and characterization of platinum nano sized particles by laser ablation in C2H6O2 solution

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

Platinum nano sized particles (Pt NPs) are superior catalysts for many intentions, such as glucose sensors, cancer therapy, gas sensors, etc. Here, Pt NPs were produced by pulsed laser ablation in C2H6O2 solution using Q-switched Nd:YAG laser, for the first time. Then, the influence of the laser fluence during synthesis of them was investigated; and they were characterized by UV–vis spectroscopy, TEM, FE-SEM, XRD, FT-IR, and Raman spectroscopy. The results showed that with increasing laser fluence, the mean particle size of the spherical NPs enhanced. Meanwhile, they had a polycrystalline cubic structure. Correspondingly, the plasmon peak position of generated NPs in the absorption spectra shifted from 257 to 266 nm, with a rise of laser fluence. The IR and Raman spectroscopy was used to achieve the information about the surface state of Pt NPs. We propose that the optimum adjusted laser fluence is an important factor to increase the ablation efficiency.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Abdelsalam, M.E., Mahajan, S., Bartlett, P.N., Baumberg, J.J., Russell, A.E.: SERS at structured palladium and platinum surfaces. J. Am. Chem. Soc. 129, 7399–7406 (2007)

    Article  Google Scholar 

  • Agarwala, P., Agarwala, V., Garg, R.: Effect of different organic solvents and annealing temperatures on optical property of TiO2 nanoparticles. Int. J. Tech. Res. Appl. 2, 61–64 (2014)

    Google Scholar 

  • Amendola, V., Meneghetti, M.: What controls the composition and the structure of nanomaterials generated by laser ablation in liquid solution? Phys. Chem. Chem. Phys. 15, 3027–3046 (2013)

    Article  Google Scholar 

  • Bigall, N.C., Härtling, T., Klose, M., Simon, P., Eng, L.M., Eychmüller, A.: Monodisperse platinum nanospheres with adjustable diameters from 10 to 100 nm: synthesis and distinct optical properties. Nano Lett. 8, 4588–4592 (2008)

    Article  ADS  Google Scholar 

  • Binh, N.T., Thanh, N.D., Dong, N.Q., Trinh, N.T.: Preparation of platinum nanoparticles in solution of polyvinyl pyrrolydone (PVP) by laser ablation method. VNU J. Sci. Math. Phys. 30, 18 (2014)

    Google Scholar 

  • Castillo Rodriguez, G.A., Guillen, G.G., Mendivil Palma, M.I., Das Roy, A.M., Guzman-Hernandez, T.K.: Synthesis and characterization of hercynite nanoparticles by pulsed laser ablation in liquid technique. Int. J. Appl. Ceram. Technol. 12, E34–E43 (2015)

    Article  Google Scholar 

  • Chakravadhanula, V.S.K., Mishra, Y.K., Kotnur, V.G., Avasthi, D.K., Strunskus, T., Zaporotchenko, V., et al.: Microstructural and plasmonic modifications in Ag–TiO2 and Au–TiO2 nanocomposites through ion beam irradiation. Beilstein J. Nanotechnol. 5, 1419–1431 (2014)

    Article  Google Scholar 

  • Coates, J.: Interpretation of Infrared Spectra, a Practical Approach. Encyclopedia of Analytical Chemistry, p. 10815. Wiley, Chichester (2000)

    Google Scholar 

  • Cristoforetti, G., Pitzalis, E., Spiniello, R., Ishak, R., Muniz-Miranda, M.: Production of palladium nanoparticles by pulsed laser ablation in water and their characterization. J. Phys. Chem. C 115, 5073–5083 (2011)

    Article  Google Scholar 

  • Cueto, M., Sanz, M., Oujja, M., Gámez, F., Martínez-Haya, B., Castillejo, M.: Platinum nanoparticles prepared by laser ablation in aqueous solutions: fabrication and application to laser desorption ionization. J. Phys. Chem. C 115, 22217–22224 (2011)

    Article  Google Scholar 

  • Dablemont, C., Lang, P., Mangeney, C., Piquemal, J.Y., Petkov, V., Herbst, F., et al.: FTIR and XPS study of Pt nanoparticle functionalization and interaction with alumina. Langmuir 24, 5832–5841 (2008)

    Article  Google Scholar 

  • Dana, D., Mayo, W., Miller, F.A., Hannah, R.W.: Course Notes on the Interpretation of Infrared and Raman Spectra. Wiley, Hoboken (2003)

    Google Scholar 

  • Díaz, C., Valenzuela, M.L., Baez, R., Segovia, M.: Solid state morphology and size tuning of nanostructured platinum using macromolecular complexes. J. Chil. Chem. Soc. 60, 2716–2720 (2015)

    Article  Google Scholar 

  • Dolgaev, S.I., Simakin, A.V., Voronov, V.V., Shafeev, G.A., Bozon-Verduraz, F.: Nanoparticles produced by laser ablation of solids in liquid environment. Appl. Phys. A 79, 1127–1132 (2004)

    Article  ADS  Google Scholar 

  • Dung Dang, T.M., Thu Le, T.T., Fribourg Blanc, E., Chien Dang, M.: Synthesis and optical properties of copper nanoparticles prepared by a chemical reduction method. Adv. Nat. Sci. Nanosci. Nanotech. 2, 15009–15012 (2011)

    Article  Google Scholar 

  • Eslamifar, M.: Hyper-rayleigh scattering and surface-enhanced Raman scattering studies of platinum nanoparticle suspensions. Int. J. Res. Rev. Appl. Sci. 19, 1–5 (2014a)

    Google Scholar 

  • Eslamifar, M.: Comparison of the nonlinear optical properties of platinum nanoparticles in both pulsed and continuous regime.  Int. J. Res. Rev. Appl. Sci. 21, 82–87 (2014b)

    Google Scholar 

  • Eustis, S., El-Sayed, M.A.: Why gold nanoparticles are more precious than pretty gold: noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes. Chem. Soc. Rev. 35, 209–217 (2005)

    Article  Google Scholar 

  • Feng Li, J., Fan Huang, Y., Ding, Y., Lin Yang, Z., Bo Li, S., Shun Zhou, X., et al.: Shell-isolated nanoparticle-enhanced Raman spectroscopy. Nature 464, 392–395 (2010)

    Article  ADS  Google Scholar 

  • Frederix, F., Friedt, J.M., Choi, K.H., Laureyn, W., Campitelli, A., Mondelaers, D., et al.: Biosensing based on light absorption of nanoscaled gold and silver particles. Anal. Chem. 75, 6894–6900 (2003)

    Article  Google Scholar 

  • Galindo, R.B., Rodriguez, P.Y.R., Urbina, B.A.P., Orta, C.A.A., Fernandez, O.S.R., Pliego, G.C., et al.: Synthesis of copper nanoparticles by thermal decomposition and their antimicrobial properties. J. Nanomater. 2014, 1–5 (2014)

    Article  Google Scholar 

  • Gharibshahi, E., Saion, E.: Influence of dose on particle size and optical properties of colloidal platinum nanoparticles. Int. J. Mol. Sci. 13, 14723–14741 (2012)

    Article  Google Scholar 

  • Golightly, J.S., Castleman, A.W.J.: Analysis of titanium nanoparticles created by laser irradiation under liquid environments. J. Phys. Chem. B. 110, 19979–19984 (2006)

    Article  Google Scholar 

  • Gómez, R., Pérez, J.M., Solla-Gullón, J., Montiel, V., Aldaz, A.: In situ surface enhanced Raman spectroscopy on electrodes with platinum and palladium nanoparticle ensembles. J. Phys. Chem. B. 108, 9943–9949 (2004)

    Article  Google Scholar 

  • Gómez, R., Solla-Gullón, J., Pérez, J.M., Aldaz, A.: Nanoparticles‐on‐electrode approach for in situ surface‐enhanced Raman spectroscopy studies with platinum‐group metals: examples and prospects. J. Raman Spectrosc. 36, 613–622 (2005)

    Article  ADS  Google Scholar 

  • Henrist, C., Traina, K., Hubert, C., Toussaint, G., Rulmont, A., Cloots, R.: Study of the morphology of copper hydroxynitrate nanoplatelets obtained by controlled double jet precipitation and urea hydrolysis. J. Cryst. Grow. 254, 176–187 (2003)

    Article  ADS  Google Scholar 

  • Henzie, J., Lee, J., Lee, M.H., Hasan, W., Odom, T.W.: Nanofabrication of plasmonic structures. Annu. Rev. Phys. Chem. 60, 147–165 (2009)

    Article  ADS  Google Scholar 

  • Karthik, A.D., Geetha, K.: Synthesis of copper precursor, copper and its oxide nanoparticles by green chemical reduction method and its antimicrobial activity. J. Appl. Pharmac. Sci. 3, 016–021 (2013)

    Google Scholar 

  • Khalef, W.K.: Preparation and characterization of TeO2 nanoparticles by pulsed laser ablation in water. J. Eng. Technol. 32, 396–405 (2013)

    Google Scholar 

  • Kim, N.H., Kim, K.: Adsorption characteristics of arylisocyanide on Au and Pt electrode surfaces: surface-enhanced Raman scattering study. J. Phys. Chem. B. 110, 1837–1842 (2006)

    Article  Google Scholar 

  • Krishnan, K., Krishnan, R.S. (1966) Raman and infrared spectra of ethylene glycol. In: Proceedings of the indian academy of sciences-section A, vol. 64, No. 2, p. 111.

  • Liu, P., Cui, H., Wang, C.X., Yang, G.W.: From nanocrystal synthesis to functional nanostructure fabrication: laser ablation in liquid. Phys. Chem. Chem. Phys. 12, 3942–3952 (2010)

    Article  Google Scholar 

  • Long, N.V., Ohtaki, M., Uchida, M., et al.: Synthesis and characterization of polyhedral Pt nanoparticles: their catalytic property, surface attachment, self-aggregation and assembly. J. Colloid. Interf. Sci. 359, 339–350 (2011)

    Article  Google Scholar 

  • Mafune, F., Kondow, T.: Selective laser fabrication of small nanoparticles and nano-networks in solution by irradiation of UV pulsed laser onto platinum nanoparticles. Chem. Phys. Lett. 383, 343–347 (2004)

    Article  ADS  Google Scholar 

  • Mafune, F., Kohno, J., Takeda, Y., Kondow, T.: Formation and size control of silver nanoparticles by laser ablation in aqueous solution. J. Phys. Chem. B. 104, 9111–9117 (2000)

    Article  Google Scholar 

  • Mafune, F., Kohno, J., Takeda, Y., Kondow, T.: Formation of stable platinum nanoparticles by laser ablation in water. J. Phys. Chem. B. 107, 4218–4223 (2003)

    Article  Google Scholar 

  • Mahdieh, M.H., Fattahi, B.: Size properties of colloidal nanoparticles produced by nanosecond pulsed laser ablation and studying the effects of liquid medium and laser fluence. Appl. Surf. Sci. 329, 47–57 (2014)

    Article  ADS  Google Scholar 

  • Mauricio Aguirre, J., Gutiérrez, A., Giraldo, O.: Simple route for the synthesis of copper hydroxy salts. J. Braz. Chem. Soc. 22, 546–551 (2011)

    Article  Google Scholar 

  • Mendivil, M.I., Krishnan, B., Castillo, G.A., Shaji, S.: Synthesis and properties of palladium nanoparticles by pulsed laser ablation in liquid. Appl. Surf. Sci. 348, 45–53 (2015)

    Article  Google Scholar 

  • Mie, G.: Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen. Ann. Phys. 330, 377–445 (1908)

    Article  MATH  Google Scholar 

  • Mornet, S., Vasseur, S., Grasset, F., Duguet, E.: Magnetic nanoparticle design for medical diagnosis and therapy. J. Mat. Chem. 14, 2161–2175 (2004)

    Article  Google Scholar 

  • Mortazavi, S.Z., Parvin, P., Reyhani, A., Nozad-Golikand, A., Mirershadi, S.: Effect of laser wavelength at IR (1064 nm) and UV (193 nm) on the structural formation of palladium nanoparticles in deionized water. J. Phys. Chem. C 115, 5049–5057 (2011)

    Article  Google Scholar 

  • Mrozek, M.F., Xie, Y., Weaver, M.J.: Surface-enhanced Raman scattering on uniform platinum-group overlayers: preparation by redox replacement of underpotential-deposited metals on gold. Anal. Chem. 73, 5953–5960 (2001)

    Article  Google Scholar 

  • Nakamoto, K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley, New York (2006)

    Book  Google Scholar 

  • Ndana, M., Grace, J.J., Baba, F.H., Mohammed, U.M.: Fourier transform infrared spectrophotometric analysis of functional groups in biodiesel produced from oils of ricinus communis, hevea brasiliensis and jatropha curcas seeds. Int. J. Sci. Environ. Technol. 2, 1116–1121 (2013)

    Google Scholar 

  • Nguyen, T.B., Nguyen, T.D.: Preparation of platinum nanoparticles in liquids by laser ablation method. Adv. Nat. Sci. Nanosci. Nanotechnol. 5, 035011(1)–035011(5) (2014)

    Google Scholar 

  • Nguyen, B.T., Nguyen, T.D., Nguyen, D.Q., Nguyen, T.T.: Preparation of platinum nanoparticles in solution of polyvinyl pyrrolydone (PVP) by laser ablation method. J. Sci. Math. Phys. 30, 18–24 (2014)

    Google Scholar 

  • Nichols, W.T., Sasaki, T., Koshizaki, N.: Laser ablation of a platinum target in water. III. Laser-induced reactions. J. Appl. Phys. 100, 114911 (2006)

    Article  ADS  Google Scholar 

  • Palma, M.I.M., Krishnan, B., Rodriguez, G.A.C., Das Roy, T.K., Avellaneda, D.A., Shaji, S.: Synthesis and properties of platinum nanoparticles by pulsed laser ablation in liquid. J. Nanomater. 18, 1 (2016)

    Article  Google Scholar 

  • Patel, K., Kapoor, S., Purshottam-Dave, D., Mukherjee, T.: Synthesis of Pt, Pd, Pt/Ag and Pd/Ag nanoparticles by microwave-polyol method. J. Chem. Sci. 117, 311–316 (2005)

    Article  Google Scholar 

  • Petroski, J., El-Sayed, M.A.: FTIR study of the adsorption of the capping material to different platinum nanoparticle shapes. J. Phys. Chem. A 107, 8371–8375 (2003)

    Article  Google Scholar 

  • Petrov, T., Markova-Deneva, I., Chauvet, O., Nikolov, R., Denev, I.: SEM an d FT-IR spectroscopy study of Cu, Sn and Cu-Sn nanoparticles. J. Uni. Chem. Tech. Metal. 47, 197–206 (2012)

    Google Scholar 

  • Piriyawong, V., Thongpool, V., Asanithi, P., Limsuwan, P.: Effect of laser pulse energy on the formation of alumina nanoparticles synthesized by laser ablation in water. Procedia Eng. 32, 1107–1112 (2012)

    Article  Google Scholar 

  • Pramila-Devamani, R.H., Sivakami, S.: Synthesis and characterization of copper chromate nanoparticles. Weekly Sci. Res. J. 1, 1–10 (2014)

    Google Scholar 

  • Qin, X., Miao, Z., Wang, X., Fang, Y., Zhang, D., Chen, Q., Shao, X.: Synthesis of platinum nanoparticles stabilized in polyvinyl alcohol and their electrocatalytic propertiesb. Anal. Bioanal. Electrochem. 3, 393–405 (2011)

    Google Scholar 

  • Rao, S.V., Podagatlapalli, G.K., Hamad, S.: Ultrafast laser ablation in liquids for nanomaterials and applications. J. Nanosci. Nanotechnol. 14, 1364–1388 (2014)

    Article  Google Scholar 

  • Sawodny, W., Niedenzu, K., Dawson, J.W.: The vibrational spectrum of ethylene glycol. Spectrochim. Acta 23A, 799–806 (1967)

    Article  ADS  Google Scholar 

  • Silverstein, R.M., Webster, F.X., Kiemle, D.J.: Spectrometric Identification of Organic Compounds. Wiley, New York (2005)

    Google Scholar 

  • Simakin, A.V., Voronov, V.V., Shafeev, G.A., Brayner, R., Bozon-Verduraz, F.: Nanodisks of Au and Ag produced by laser ablation in liquid environment. Chem. Phys. Let. 348, 182–186 (2001)

    Article  ADS  Google Scholar 

  • Smith, B.: Infrared Spectral Interpretation. CRC Press, Boca Raton (1999)

    Google Scholar 

  • Socrates, G.: Infrared and Raman Characteristic Group Frequencies: Tables and Charts. Wiley, Chichester (2001)

    Google Scholar 

  • Song, J.Y., Kwon, E.Y., Kim, B.S.: Biological synthesis of platinum nanoparticles using Diopyros kaki leaf extract. Bioprocess Biosyst. Eng. 33, 159 (2010)

    Article  Google Scholar 

  • Stepanov, A.L., Golubev, A.N., Nikitin, S.I., Osin, Y.N.: A review on the fabrication and properties of platinum nanoparticles. Rev. Adv. Mater. Sci. 38, 160–175 (2014)

    Google Scholar 

  • Stuart, B.H.: Infrared Spectroscopy: Fundamentals and Applications. Wiley, Chichester (2004)

    Book  Google Scholar 

  • Suffren, Y., Rollet, F.G., Reber, C.: Raman spectroscopy of transition metal complexes: molecular vibrational frequencies, phase transitions, isomers, and electronic structure. Comment Inorg. Chem. 32, 246–276 (2011)

    Article  Google Scholar 

  • Suresh, Y., Annapuma, S., Bhikshamaiah, G., Singh, A. K.: Int. Conf. Adv. Nanomater. Emerg. Eng. Technol. (2013), 63

  • Suresh, Y., Annapurna, S., Singh, A.K., Bhikshamaiah, G.: Green synthesis and characterization of tea decoction stabilized copper nanoparticles. Int. J. Innov. Res. Sci. Eng. Technol. 3, 11265–11270 (2014)

    Google Scholar 

  • Sylvestre, J.P., Kabashin, A.V., Sacher, E., Meunier, M., Luong, J.H.T.: Stabilization and size control of gold nanoparticles during laser ablation in aqueous cyclodextrins. J. Am. Chem. Soc. 126, 7176–7177 (2004)

    Article  Google Scholar 

  • Tian, Z.Q., Ren, B., Mao, B.W.: Extending surface Raman spectroscopy to transition metal surfaces for practical applications. 1. Vibrational properties of thiocyanate and carbon monoxide adsorbed on electrochemically activated platinum surfaces. J. Phys. Chem. B. 101, 1338–1346 (1997)

    Article  Google Scholar 

  • Ungula, J., Dejene, B. F.: Physica B Condens. Mater. Phys. (2015), 1

  • UV/VIS/IR Spectroscopy Analysis of Nanoparticles:Nano Composix, San Diego (2012)

  • Van Overschelde, O., Guisbiers, G., Snyders, R.: Green synthesis of selenium nanoparticles by excimer pulsed laser ablation in water. Appl. Mater. 1, 042114 (2013)

    Article  ADS  Google Scholar 

  • Vieira, L., Schennach, R., Gollas, B.: In situ PM-IRRAS of a glassy carbon electrode/deep eutectic solvent interface. Phys. Chem. Chem. Phys. 17, 12870–12880 (2015)

    Article  Google Scholar 

  • Wang, A., Han, J., Guo, L., Yu, J., Zeng, P.: Database of standard Raman spectra of minerals and related inorganic crystals. Appl. Spect. 48, 959–968 (1994)

    Article  ADS  Google Scholar 

  • Werner, D., Hashimoto, S., Tomita, T., Matsuo, S., Makita, Y.: Examination of silver nanoparticle fabrication by pulsed-laser ablation of flakes in primary alcohols. J. Phys. Chem. C 112, 1321–1329 (2008)

    Article  Google Scholar 

  • Xu, B., Song, R.G., Tang, P.H., Wang, J., Chai, G.Z., Zhang, Y.Z., Ye, Z.Z.: Preparation of Ag nanoparticles colloid by pulsed laser ablation in distilled water. Key Eng. Mater. 373, 346–349 (2008)

    Article  Google Scholar 

  • Yan, Z., Bao, R., Chrisey, D.B.: Excimer laser ablation of a Pt target in water: the observation of hollow particles. Nanotechnology 21, 145609 (2010)

    Article  ADS  Google Scholar 

  • Zeng, H., Du, X.W., Singh, S.C., Kulinich, S.A., Yang, S., He, J., et al.: Nanomaterials via laser ablation/irradiation in liquid: a review. Adv. Funct. Mater. 22, 1333–1353 (2012)

    Article  Google Scholar 

  • Zhou, M., Chen, S., Ren, H., Wu, L., Zhao, S.: RETRACTED: Electrochemical formation of platinum nanoparticles by a novel rotating cathode method. Physica E 27, 341–350 (2005)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mohammad Reza Hantehzadeh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Moniri, S., Hantehzadeh, M.R., Ghoranneviss, M. et al. Synthesis and characterization of platinum nano sized particles by laser ablation in C2H6O2 solution. Opt Quant Electron 49, 174 (2017). https://doi.org/10.1007/s11082-017-1007-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-017-1007-6

Keywords

Navigation