Abstract
Laser ablation (LAL) and irradiation in liquids (LIL) are becoming two of the most studied and dominant ways of synthesis and modification for nanostructured materials. Such rapid development is due to a fast and economic way to obtain nanoparticles of any material. Starting from solid targets submerged in water or other liquids, it is possible to obtain noble metals, metal alloys, metal oxides, and graphene nanoparticles, simply by irradiating the target with a focused laser beam. Moreover, it is also possible to modify already existing nanoparticles, generating defects in their structures or reshaping them, through laser irradiation of their colloidal dispersion using an unfocused laser beam. In this chapter, a focus on the fundaments of laser ablation and modification in liquids is reported as well as some advances in the synthesis and modification of new nanostructures with their relative application in different fields of research such as bio-sensing, catalysis, and optoelectronics. The example of the synthesis of ultra-pure silver nanoparticles by LAL and their application as surface-enhanced Raman scattering (SERS) active substrate for biosensing application is provided. In such a study, it is possible to detect and characterize a protein involved in diabetes mellitus type 2 (amylin), at nanomolar concentration. LIL has been also considered to modify commercial TiO2 and graphene oxide (GO) colloids. Such unconventional treatment has shown to enhance the performances of these two materials, towards photocatalytic water splitting and water purification applications, thanks to the modification of the morphology and oxygen functionalities of these materials. As an added value, the LIL of TiO2 and GO is a more green technique and tunable methodology concerning conventional reduction methods. Laser irradiation of GO results in conferring to the material an antimicrobial activity not shown by the untreated one. Similarly, the performance in the photocatalytic H2 production of laser-treated TiO2 samples is examined pointing out that the TiO2 structural modifications induced by the LIL process are fundamentals to strongly increase the photocatalytic performance.
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References
G. Schmid, Nanoparticles: From Theory to Application (Wiley, 2006)
S.K. Kulkarni, Nanotechnology: Principles and Practices (Springer, 2014)
D. Vollath, Nanomaterials: An Introduction to Synthesis, Properties and Applications (Wiley, 2012)
J. Jeevanandam, A. Barhoum, Y.S. Chan et al., Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations. Beilstein J. Nanotechnol. 9, 1050–1074 (2018)
M. Shafiq, S. Anjum, C. Hano et al., An overview of the applications of nanomaterials and nanodevices in the food industry. Foods 9, 148 (2020)
H. Wang, X. Liang, J. Wang et al., Multifunctional inorganic nanomaterials for energy applications. Nanoscale 12, 14–42 (2020)
M. Rycenga, C.M. Cobley, J. Zeng et al., Controlling the synthesis and assembly of silver nanostructures for plasmonic applications. Chem. Rev. 111, 3669–3712 (2011)
X. Zhang, A. Hu, T. Zhang et al., Self-assembly of large-scale and ultrathin silver nanoplate films with tunable plasmon resonance properties. ACS Nano 5, 9082–9092 (2011)
D. Zhang, B. Gökce, S. Barcikowski, Laser synthesis and processing of colloids: fundamentals and applications. Chem. Rev. 117, 3990–4103 (2017)
S. Barcikowski, G. Compagnini, Advanced nanoparticle generation and excitation by lasers in liquids. Phys. Chem. Chem. Phys. 15, 3022–3026 (2013)
G.W. Yang, Laser ablation in liquids: applications in the synthesis of nanocrystals. Prog. Mater Sci. 52, 648–698 (2007)
V. Amendola, M. Meneghetti, Laser ablation synthesis in solution and size manipulation of noble metal nanoparticles. Phys. Chem. Chem. Phys. 11, 3805–3821 (2009)
F. Taccogna, M. Dell’Aglio, M. Rutigliano et al., On the growth mechanism of nanoparticles in plasma during pulsed laser ablation in liquids. Plasma Sources Sci. Technol. 26, 045002 (2017) (10pp)
G. Yang, Laser Ablation in Liquids: Principles and Applications in the Preparation of Nanomaterials (Pan, Stanford, 2012)
V. Amendola, D. Amans, Y. Ishikawa et al., Room‐temperature laser synthesis in liquid of oxide, metal‐oxide core‐shells and doped oxide nanoparticles. Chem. A Eur. J. 26(42) (2020)
G. González-Rubio, A. Guerrero-Martínez, L.M. Liz-Marzán, Reshaping, fragmentation, and assembly of gold nanoparticles assisted by pulse lasers. Acc. Chem. Res. 49, 678–686 (2016)
L. Delfour, T.E. Itina, Mechanisms of ultrashort laser-induced fragmentation of metal nanoparticles in liquids: numerical insights. J. Phys. Chem. C 119, 13893–13900 (2015)
H. Wang, A. Pyatenko, K. Kawaguchi et al., Selective pulsed heating for the synthesis of semiconductor and metal submicrometer spheres. Angew. Chem. Int. Ed. 49, 6361–6364 (2010)
H. Wang, A. Pyatenko, K. Kawaguchi et al., General bottom-up construction of spherical particles by pulsed laser irradiation of colloidal nanoparticles: a case study on CuO. Chem. Eur. J. 18, 163–169 (2012)
G. Messina, M. Sinatra, V. Bonanni et al., Tuning the composition of alloy nanoparticles through laser mixing: the role of surface plasmon resonance. J. Phys. Chem. C 120, 12810–12818 (2016)
G. Compagnini, E. Messina, O. Puglisi et al., Laser synthesis of Au/Ag colloidal nano-alloys: optical properties, structure and composition. Appl. Surf. Sci. 254, 1007–1011 (2007)
R. Fabbro, P. Peyer, L. Berthe et al., Physics and applications of laser-shock processing. J. Laser Appl. 10, 265–279 (1998)
L. Berthe, R. Fabbro, P. Peyer et al., Shock waves from a water-confined laser-generated plasma. J. Appl. Phys. 82, 2826–2832 (1997)
T. Sakka, S. Yawanage, Y.H. Ogata et al., Laser ablation at solid–liquid interfaces: an approach from optical emission spectra. J. Chem. Phys. 112, 8645–8653 (2000)
K. Saito, K. Takatani, T. Sakka et al., Observation of the light emitting region produced by pulsed laser irradiation to a solid–liquid interface. Appl. Surf. Sci. 197, 56–60 (2002)
L. Berthe, A. Sollier, R. Fabbro et al., The generation of laser shock waves in a water-confinement regime with 50 ns and 150 ns XeCl excimer laser pulses. J. Phys. D Appl. Phys. 33, 2142–2145 (2000)
D. Liu, C. Li, F. Zhou et al., Rapid synthesis of monodisperse au nanospheres through a laser irradiation-induced shape conversion, self-assembly and their electromagnetic coupling. Sci. Rep. 5, 7686 (2015) (9pp)
Y. Chen, Y. Tseng, C. Yeh, Laser-induced alloying Au–Pd and Ag–Pd colloidal mixtures: the formation of dispersed Au/Pd and Ag/Pd nanoparticles. J. Mater. Chem. 12, 1419–1422 (2002)
M.A. Buccheri, D. D’Angelo, S. Scalese et al., Modification of graphene oxide by laser irradiation: a new route to enhance antibacterial activity. Nanotechnology 27, 245704 (2016) (12pp)
X. Li, A. Pyatenko, Y. Shimizu et al., Fabrication of crystalline silicon spheres by selective laser heating in liquid medium. Langmuir 27, 5076–5080 (2011)
A. Pyatenko, M. Yamaguchi, M. Suzuki, Mechanisms of size reduction of colloidal silver and gold nanoparticles irradiated by Nd: YAG Laser. J. Phys. Chem. C 113, 9078–9085 (2009)
M. Fleischmann, P.J. Hendra, A.J. McQuillan, Raman spectra of pyridine adsorbed at a silver electrode. Chem. Phys. Lett. 26, 163–166 (1974)
D.L. Jeanmaire, R.P. Van Duyne, Surface Raman electrochemistry. Part 1. Heterocyclic, aromatic and aliphatic amines adsorbed on the anodised silver electrode. J. Electroanal. Chem. 84, 1–20 (1977)
M.G. Albrecht, J.A. Creighton, Anomalously intense Raman spectra of pyridine at a silver electrode. J. Am. Chem. Soc. 99, 5215–5219 (1977)
R.P. Van Duyne, Laser excitation of Raman scattering from adsorbed molecules on electrode surfaces. Chem. Biochem. Appl. Lasers 4, 101–185 (1979)
E.C. Le Ru, E. Blackie, M. Meyer et al., Surface enhanced Raman scattering enhancement factors: a comprehensive study. J. Phys. Chem. C 111, 13794–13803 (2007)
S. Nie, S.R. Emory, Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275, 1102–1106 (1997)
G. Chen, Y. Wang, M. Yang et al., Measuring ensemble-averaged surface-enhanced Raman scattering in the hotspots of colloidal nanoparticle dimers and trimers. Am. Chem. Soc. 132, 3644–3645 (2010)
J.A. Hebda, A.D. Miranker, The interplay of catalysis and toxicity by amyloid intermediates on lipid bilayers: insights from type II diabetes. Biophysics 38, 125–152 (2009)
F.E. Cohen, S.B. Prusiner, Pathologic conformations of prion proteins. Ann. Rev. Biochem. 67, 793–819 (1998)
M. Pappalardo, M. Milardi, D. Grasso et al., Steered molecular dynamics studies reveal different unfolding pathways of prions from mammalian and non-mammalian species. New J. Chem. 31, 901–905 (2007)
D. Milardi, M.F.M. Sciacca, M. Pappalardo et al., The role of aromatic side-chains in amyloid growth and membrane interaction of the islet amyloid polypeptide fragment LANFLVH. Eur. Biophys. J. 40, 1–12 (2011)
R. Soong, J.R. Brender, P.M. Macdonald et al., Association of highly compact type II diabetes related islet amyloid polypeptide intermediate species at physiological temperature revealed by diffusion NMR spectroscopy. J. Am. Chem. Soc. 131, 7079–7085 (2009)
S. Scalisi, M.F.M. Sciacca, G. Zhavnerko et al., Self-assembling pathway of HiApp fibrils within lipid bilayers. Chem. BioChem. 11, 1856–1859 (2010)
P. Arosio, T.P.J. Knowles, S. Linse, On the lag phase in amyloid fibril formation. Phys. Chem. Chem. Phys. 17, 7606–7618 (2015)
S.A. Hudson, T. Ecroyd, W. Kee et al., The thioflavin T fluorescence assay for amyloid fibril detection can be biased by the presence of exogenous compounds. FEBS 276, 5960–5972 (2009)
R.N. Rambaran, L.C. Serpell, Amyloid fibrils. Prion 2, 112–117 (2008)
M. Pannuzzo, D. Milardi, A. Raudino et al., Analytical model and multiscale simulations of Aβ peptide aggregation in lipid membranes: towards a unifying description of conformational transitions, oligomerization and membrane damage. Phys. Chem. Chem. Phys. 15, 8940–8951 (2013)
V. Amendola, M. Meneghetti, S. Fiameni et al., SERS labels for quantitative assays: application to the quantification of gold nanoparticles uptaken by macrophage cells. Anal. Methods 3, 849–856 (2011)
G. Grasso, L. D’Urso, E. Messina et al., A mass spectrometry and surface enhanced Raman spectroscopy study of the interaction between linear carbon chains and noble metals. Carbon 47, 2611–2619 (2009)
I. ChoiYun, S. Huh, D. Erickson et al., Ultra-sensitive, label-free probing of the conformational characteristics of amyloid beta aggregates with a SERS active nanofluidic device. Microfluid. Nanofluid. 1, 663–669 (2012)
D. Bhowmik, K.R. Mote, C.M. MacLaughlin et al., Cell-membrane-mimicking lipid-coated nanoparticles confer Raman enhancement to membrane proteins and reveal membrane-attached amyloid-β conformation. ACS Nano 9, 9070–9077 (2015)
D. Kurouski, T. Deckert-Gaudig, V. Deckert et al., Surface characterization of insulin protofilaments and fibril polymorphs using tip-enhanced Raman spectroscopy (TERS). Biophys. J. 106, 263–271 (2014)
D. Zhang, O. Neumann, H. Wang, V.M. Yuwono et al., Gold nanoparticles can induce the formation of protein-based aggregates at physiological pH. Nano Lett. 9, 666–671 (2009)
Y. Liao, Y. Chang, Y. Yoshiike et al., Negatively charged gold nanoparticles inhibit Alzheimer’s amyloid-β fibrillization, induce fibril dissociation, and mitigate neurotoxicity. Small 8, 3631–3639 (2012)
G. Brancolini, A. Corazza, M. Vuano et al., Probing the influence of citrate-capped gold nanoparticles on an amyloidogenic protein. ACS Nano 9, 2600–2613 (2015)
C. Rehbock, J. Jakobi, L. Gamrad et al., Current state of laser synthesis of metal and alloy nanoparticles as ligand-free reference materials for nano-toxicological assays. J. Nanotechnol. 5, 1523–1541 (2014)
W.H. Moore, S. Krimm, Vibrational analysis of peptides, polypeptides, and proteins. II. β-poly(L-alanine) and β-poly(L-alanylglycine). Biopolymers 15, 2465–2483 (1976)
W.L. Peticolas, Applications of Raman spectroscopy to biological macromolecules. Biochimie 57(4), 417–428 (1975)
B.G. Frushour, P.C. Painter, J.L. Koenig, Vibrational spectra of polypeptides. J. Macromol. Chem. 15, 29–115 (1976)
T.G. Spiro, B.P. Gaber, Laser Raman scattering as a probe of protein structure. Annu. Rev. Biochem. 46, 553–572 (1977)
J.F. Rabolt, W.H. Moore, S. Krimm, Vibrational analysis of peptides, polypeptides, and proteins. 3. alpha-poly(L-alanine). Macromolecules 10, 1065–1074 (1977)
J. Bandekar, S. Krimmt, Vibrational analysis of peptides, polypeptides, and proteins: characteristic amide bands of β-turns. Biophysics 76, 774–777 (1979)
C. Cabaleiro-Lago, F. Quinlan-Pluck, I. Lynch et al., Inhibition of amyloid β protein fibrillation by polymeric nanoparticles. J. Am. Chem. Soc. 130, 15437–15443 (2008)
L. D’Urso, M. Condorelli, O. Puglisi et al., Detection and characterization at nM concentration of oligomers formed by hIAPP, Aβ(1–40) and their equimolar mixture using SERS and MD simulations. Phys. Chem. Chem. Phys. 20, 20588–20596 (2018)
A. Mendez, F. Fernandez, G. Gasco, Removal of malachite green using carbon-based adsorbents. Desalination 206, 147–153 (2007)
M.Z. Iqbal, A.A. Abdala, Thermally reduced graphene: synthesis, characterization and dye removal applications. RSC Adv. 3, 24455–24464 (2013)
S. Filice, M. Mazurkiewicz-Pawlicka, A. Malolepszy et al., Sulfonated pentablock copolymer membranes and graphene oxide addition for efficient removal of metal ions from water. Nanomaterials 10, 1157 (2020)
M.J. Lü, J. Li, X.Y. Yang et al., Applications of graphene-based materials in environmental protection and detection. Chin. Sci. Bull. 58, 2698–2710 (2013)
S. Scalese, I. Nicotera, D. D’Angelo et al., Cationic and anionic azo-dye removal from water by sulfonated graphene oxide nanosheets in Nafion membranes. New J. Chem. 40, 3654–3663 (2016)
S. Yanga, S. Chena, Y. Changa, A. Caoa et al., Removal of methylene blue from aqueous solution by graphene oxide. J. Coll. Int. Sci. 359, 24–29 (2011)
S.F. Spanò, G. Isgrò, P. Russo et al., Tunable properties of graphene oxide reduced by laser irradiation. Appl. Phys. A 117, 19–23 (2014)
S. Park, R.S. Ruoff, Chemical methods for the production of graphenes. Nat. Nanotech. 4, 217–224 (2009)
M.A. Buccheri, D. D’Angelo, S. Scalese et al.: Modification of graphene oxide by laser irradiation: a new route to enhance antibacterial activity. Nanotechnology 27, 245704 (2016) (12pp)
A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972)
A. Fuerte, M.D. Hernandez-Alonso, A.J. Maira et al.: Visible light-activated nanosized doped-TiO2 photocatalysts. Chem. Comm. 24, 2718−2719 (2001)
Z.W. Seh, S.H. Liu, M. Low et al., Au-TiO2 photocatalysts with strong localization of plasmonic near-fields for efficient visible-light hydrogen generation. Adv. Mater. 24, 2310–2314 (2012)
R. Fiorenza, M. Bellardita, L. Palmisano et al., A comparison between photocatalytic and catalytic oxidation of 2-propanol over Au/TiO2–CeO2 catalysts. J. Mol. Catal. A Chem. 415, 56–64 (2016)
R. Fiorenza, M. Bellardita, L. D’Urso et al.: Au/TiO2-CeO2 catalysts for photocatalytic water splitting and VOCs oxidation reactions. Catalysts 6, 121 (2016) (13pp)
R. Asahi, T. Morikawa, T. Ohwaki et al., Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293, 269–271 (2001)
R. Fiorenza, M. Bellardita, S. Scirè, L. Palmisano, Photocatalytic H2 production over inverse opal TiO2 catalysts. Catal. Today 321–322, 113–119 (2019)
J.B. Varley, A. Janotti, C.G. Van de Walle, Mechanism of visible-light photocatalysis in nitrogen-doped TiO2. Adv. Mater. 23, 2343–2347 (2011)
S. Filice, D. D’Angelo, S.F. Spanò et al., Modification of graphene oxide and graphene oxide–TiO2 solutions by pulsed laser irradiation for dye removal from water. Mater. Sci. Semicond. Proc. 42, 50–53 (2015)
Y. Shiraishi, H. Sakamoto, Y. Sugano et al., Pt–Cu bimetallic alloy nanoparticles supported on anatase TiO2: highly active catalysts for aerobic oxidation driven by visible light. ACS Nano 7, 9287–9297 (2013)
D. Zhang, J. Liu, P. Li et al., Recent advances in surfactant-free, surface-charged, and defect-rich catalysts developed by laser ablation and processing in liquids. ChemNanoMat 3, 512–533 (2017)
L.H. Li, Z.X. Deng, J.X. Xiao, G.W. Yang, A metallic metal oxide (Ti5O9)-metal oxide (TiO2) nanocomposite as the heterojunction to enhance visible-light photocatalytic activity. Nanotechnology 26 (2015)
J. Yan, P. Liu, C. Ma et al., Plasmonic near-touching titanium oxide nanoparticles to realize solar energy harvesting and effective local heating. Nanoscale 8, 8826–8838 (2016)
X. Chen, D. Zhao, K. Liu et al., Laser-modified black titanium oxide nanospheres and their photocatalytic activities under visible light. ACS Appl. Mater. Interfaces 7, 16070–16077 (2015)
S. Filice, G. Compagnini, R. Fiorenza et al., Laser processing of TiO2 colloids for an enhanced photocatalytic water splitting activity. J. Colloid Interface Sci. 489, 131–137 (2017)
G. Zhu, Y. Shan, T. Lin et al., Hydrogenated blue titania with high solar absorption and greatly improved photocatalysis. Nanoscale 8, 4705–4712 (2016)
J. Tian, X. Hu, H. Yang et al., High yield production of reduced TiO2 with enhanced photocatalytic activity. Appl. Surf. Sci. 360, 738–743 (2016)
A.L. Linsebigler, G. Lu, J.T. Yates, Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem. Rev. 95, 735–758 (1995)
W.-N. Zhao, Z.-P. Liu, Mechanism and active site of photocatalytic water splitting on titania in aqueous surroundings. Chem. Sci. 5, 2256–2264 (2014)
R. Fiorenza, S. Sciré, L. D’Urso et al., Efficient H2 production by photocatalytic water splitting under UV or solar light over variously modified TiO2-based catalysts. Int. J. Hydrogen Energy 44, 14796–14807 (2019)
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Compagnini, G. et al. (2020). Laser-Induced Synthesis and Processing of Nanoparticles in the Liquid Phase for Biosensing and Catalysis. In: Hu, A. (eds) Laser Micro-Nano-Manufacturing and 3D Microprinting. Springer Series in Materials Science, vol 309. Springer, Cham. https://doi.org/10.1007/978-3-030-59313-1_4
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