Abstract
The preparation of a polymer nanocomposite by compounding an aqueous polymer emulsion with an aqueous dispersion of montmorillonite clay is described. A styrene-acrylate copolymer emulsion and a purified native montmorillonite clay from Latvian deposits are used. An X-ray diffraction analysis and differential scanning calorimetric thermograms are shown. Data on the influence of montmorillonite concentration on the tensile stress-strain diagram, elasticity, yield stress, breaking stress, and ultimate elongation of the processed nanocomposite material are obtained.
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S. Komarneni, “Nanocomposites,” J. Mater. Chem., 2, No. 12, 1219–1230 (1992).
V. A. Struk, A. V. Rogachev, A. A. Skaskevich, O. V. Kholodilov, and M. Lyuty, “Nanomaterials and nanotechnologies for mechanical engineering (review),” Mater. Tekhnol. Instrum., 7, No. 3, 53–65 (2002).
T. J. Pinnavaia and G. W. Beall (eds.), Polymer-Clay Nanocomposites, John Wiley & Sons, Chichester-New York (2001).
R. Krishnamoorti and R. A. Vaia (eds.), Polymer Nanocomposites: Synthesis, Characterization, and Modeling, American Chemical Society, Washington (2001).
M. Alexandre and Ph. Dubois, “Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials,” Mater. Sci. Eng, 28, 1–63 (2000).
A. K. Mikitaev, A. A. Kaladzhyan, O. B. Lednev, and M. A. Mikitaev, “Nanocomposite polymer materials based on organoclays,” Plast. Massy, No. 12, 45–50 (2004).
S. M. Lomakin and G. E. Zaikov, “Polymer nanocomposites of lowered combustibility based on layered silicates,” Vysokomol. Soed., 47B, No. 1, 104–120 (2005).
Xiang Ling Ji, Jiao Kai Jing, Wei Jiang, and Bing Zheng Jiang, “Tensile modulus of polymer nanocomposites,” Polym. Eng. Sci., 42, No. 5, 983–993 (2002).
T. D. Fornes and D. R. Paul, “Modeling the properties of nylon 6/clay nanocomposites using composite theories,” Polymer, 44, 4993–5013 (2003).
N. Sheng, M. C. Boyce, D. M. Parks, G. C. Rutledge, J. I. Abes, and R. E. Cohen, “Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle,” Polymer, 45, 487–506 (2004).
A. N. Wilkinson, P. Matikainen, G. C. Lees, C. M. Liauw, Z. Man, and J. L. Stanford, “Structure and mechanical properties of melt-intercalated polyamide 6-montmorillonite nanocomposites,” in: Proc. Joint Meeting: 8th Europ. Symp. Polymer Blends and Eurofillers 2005, Belgium, Bruges (2005), CD-version, Paper No. F/155.
M. Zelenkova Myskova, J. Zelenka, V. Spacek, and F. Socha, “Properties of epoxy systems with clay nanocomposites,” Mech. Compos. Mater., 39, No. 2, 111–122 (2003).
J.-J. Luo and I. M. Daniel, “Characterization and modeling of mechanical behavior of polymer/clay nanocomposites,” Compos. Sci. Technol., 63, 1607–1616 (2003).
M. A. Osman, V. Mittal, and H. R. Lusti, “The aspect ratio and gas permeation in polymer-layered silicate nanocomposites,” Macromol. Rapid Commun., 25, 1145–1149 (2004).
M. A. Osman, V. Mittal, M. Morbidelli, and U. W. Suter, “Epoxy-layered silicate nanocomposites and their gas permeation,” Macromolecules, 37, 7250–7257 (2004).
Ph. H. Nam, P. Maiti, M. Okamoto, T. Kotaka, N. Nasegawa, and A. Usuki, “A hierarchical structure and properties of intercalated polypropylene/clay nanocomposites,” Polymer, 42, 9633–9640 (2001).
X. Liu and Q. Wu, “PP/clay nanocomposites prepared by grafting-melt intercalation,” Polymer, 42, 10013–10019 (2001).
E. M. Antipov, A. A. Barannikov, V. A. Gerasin, B. F. Shklyaruk, L. A. Tsamalashvili, H. R. Fisher, and I. V. Razumovskaya, “Structure and deformational behavior of nanocomposites based on polypropylene and modified clays,” Vysokomol. Soed., 45A, No. 11, 1885–1899 (2003).
E. M. Antipov, M. A. Guseva, V. A. Gerasin, Yu. M. Korolev, A. V. Rebrov, H. R. Fisher, and I. V. Razumovskaya, “Structure and deformational behavior of nanocomposites based on low-density polyethylene and modified clays,” Vysokomol. Soed., 45A, No. 11, 1874–1884 (2003).
N. Yu. Kovaleva, P. N. Brevnov, V. G. Grinev, S. P. Kuznetsov, I. V. Pozdnyakov, S. N. Chvalun, E. A. Sinevich, and L. A. Novokshenova, “Synthesis of nanocomposites based on polyethylene and layered silicates by the method of intercalation polymerization,” Vysokomol. Soed., 46A, No. 6, 1045–1051 (2004).
J.-X. Li, J. Wu, and C.-M. Chan, “Thermoplastic nanocomposites,” Polymer, 41, 6935–6937 (2000).
K. Yano, A. Usuki, A. Okada, T. Kurauchi, and O. Kamigaito, “Synthesis and properties of polyimide-clay hybrid,” J. Polym. Sci. Pt. A, Polym. Chem., 31, 2493–2498 (1993).
T. Lan, P. D. Kaviratna, and T. J. Pinnavaia, “On the nature of polyimide-clay hybrid composites, ” Chem. Mater., 6, 573–575 (1994).
R. Magaraphan, W. Lilaynthalert, A. Sirivat, and J. W. Schwank, “Preparation, structure, properties, and thermal behavior of rigid-rod polyimide/montmorillonite nanocomposites,” Compos. Sci. Technol., 61, 1253–1264 (2001).
M. Okamoto, S. Morita, Y. H. Kim, T. Kotaka, and H. Tateyama, “Dispersed structure change of smectic clay/poly (methyl methacrylate) nanocomposites by copolymerization with polar comonomers,” Polymer, 42, 1201–1206 (2001).
W. Chen, Q. Xu, and R. Z. Yuan, “The influence of polymer state on the electrical properties of polymer/layered-silicate nanocomposites,” Compos. Sci. Technol., 61, 935–939 (2001).
Ph. B. Messersmith and E. P. Giannelis, “Synthesis and barrier properties of poly(ɛ-caprolactone)-layered silicate nanocomposites,” J. Polym. Sci. Pt. A, Polym. Chem., 33, 1047–1057 (1995).
R. A. Sheptalin, E. V. Koverzanova, S. M. Lomakin, and V. S. Osipchik, “Particular features of combustibility and thermal destruction of a nanocomposite of elastic polyurethane foam based on organo-modified layered alumosilicate,” Plast. Massy, No. 4, 20–26 (2004).
I. A. Tutorskii and B. V. Pokid’ko, “Elastomeric nanocomposites with layered silicates. II. Properties of nanocomposites,” Kauchuk Resina, No. 6, 33–36 (2004).
W. E. Worrall, Clays and Ceramic Raw Materials, Applied Science Publishers Ltd., London (1975).
A. I. Avgustinnik, Ceramics [in Russian], Stroyizdat, Moscow (1975).
J. Freimanis, A. Actins, A. Stinkule, R. Svinka, and V. Svinka, “Organoclay from some Latvian clays,” Latv. Kim. Z., No. 1, 69–77 (2003).
J. L. Bonczek, W. G. Harris, and P. Nkedi-Kizza, “Monolayer to bilayer transitional arrangements of hexadecyltrimethylammonium cations on Na-montmorillonite,” Clays Clay Miner., 50, No. 1, 11–17 (2002).
Yu. S. Lipatov, Physicochemical Fundamentals of Polymer Filling [in Russian], Khimiya, Moscow (1991).
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Translated from Mekhanika Kompozitnykh Materialov, Vol. 42, No. 1, pp. 61–74, January–February, 2006.
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Maksimov, R.D., Gaidukovs, S., Kalnins, M. et al. A nanocomposite based on a styrene-acrylate copolymer and native montmorillonite clay 1. Preparation, testing, and properties. Mech Compos Mater 42, 45–54 (2006). https://doi.org/10.1007/s11029-006-0015-6
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DOI: https://doi.org/10.1007/s11029-006-0015-6