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Vinyl Modified Cloisite 30B Clay as an Efficient Filler for the Synthesis of Poly(styrene-co-butyl acrylate)/Clay Nanocomposite by Emulsion Polymerization

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Abstract

Synthesis of latex based on polystyrene/poly(butyl acrylate) with layered silicate using emulsion polymerization procedure is described. In order to make the organic modified montmorillonite (Cloisite 30B) more compatible with polymer matrix, it was reacted with vinyltricholorosilane as a coupling agent to replace the edge hydroxyl groups of the layered silicate with a vinyl moiety. XRD and scanning electron microscopy were applied to study the interlayer and surface changes of the clay in the prepared material. Exfoliated and intercalated nanocomposites were obtained for clay content of 0.3–1.0% while agglomeration was occurred at higher clay loadings. The nanolattices were studied by thermogravimetric analysis and differential scanning calorimetry.

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REFERENCES

  1. V. Castelvetro and C. De Vita, Adv. Colloid Interface Sci. 167, 108 (2004).

    Google Scholar 

  2. M. Salami-Kalajahi, V. Haddadi-Asl, S. Rahimi-Razin, F. Behboodi-Sadabad, H. Roghani-Mamaqani, and M. Hemmat, Chem. Eng. J. 174, 368 (2011).

    Article  CAS  Google Scholar 

  3. H. Roghani-Mamaqani, V. Haddadi-Asl, M. Najafi, and M. Salami-Kalajahi, J. Appl. Polym. Sci. 120, 1431 (2011).

    Article  CAS  Google Scholar 

  4. C. Esma Yeniova and U. Yilmazer, J. Appl. Polym. Sci. 127, 3673 (2013).

    Article  Google Scholar 

  5. K. H. Saeed and S. Y. Park, J. Polym. Res. 17, 535 (2010).

    Article  CAS  Google Scholar 

  6. B. N. Jang, M. Costache, and C. A. Wilkie, Polymer 46, 10678 (2005).

    Article  CAS  Google Scholar 

  7. S. Nazarenko, P. Meneghetti, P. Julmon, B. G. Olson, and S. Qutubuddin, J. Polym. Sci., Part B: Polym. Phys. 45, 1733 (2007).

    Article  CAS  Google Scholar 

  8. Y. Yang, D. Wu, Ch. Li, L. Liu, X. Cheng, and H. Zhao, Polymer 47, 7374 (2006).

    Article  CAS  Google Scholar 

  9. X. Fan, C. Xia, T. Fulghum, M. K. Park, J. Locklin, and R. C. Advincula, Langmuir 19, 916 (2003).

    Article  CAS  Google Scholar 

  10. X. Fan, C. Xia, C. Xia, and R. C. Advincula, Langmuir 19, 4381 (2003).

    Article  CAS  Google Scholar 

  11. R. Suprakas Sinha and O. Masami, Prog. Polym. Sci. 28, 1539 (2003).

    Article  Google Scholar 

  12. H. Roghani-Mamaqani, V. Haddadi-Asl, M. Najafi, and M. Salami-Kalajahi. J. Appl. Polym. Sci. 123, 409 (2012).

    Article  CAS  Google Scholar 

  13. V. Mittal, J. Colloid Interface Sci. 314, 141 (2007).

    Article  CAS  PubMed  Google Scholar 

  14. T. Wang, M. Wang, Z. Zhang, X. Ge, and Y. Fang, Mater. Lett. 61, 3723 (2007).

    Article  CAS  Google Scholar 

  15. J. C. Chen, W. Q. Luo, H. D. Wang, J. M. Xiang, H. F. Jin, F. Chen, and Z. W. Cai, Appl. Surf. Sci. 256, 2490(2010).

    Article  CAS  Google Scholar 

  16. Y. S. Chen, C. C. Chen, and S. S. Hou, J. Appl. Polym. Sci. 115, 4162 (2010).

    Google Scholar 

  17. N. N. Herrera, J. M. Letoffe, J. L. Putaux, L. David, and E. B. Lami, Langmuir 20, 1564 (2004).

    Article  CAS  Google Scholar 

  18. M. N. Gorgani, K. Karimian, and F. Mohanazadeh, J. Am. Chem. Soc. 107, 4156 (1985).

    Google Scholar 

  19. N. A. Agudelo, L. D. Perez, and B. L. Lopez, Appl. Surf. Sci. 257, 8581 (2011).

    Article  CAS  Google Scholar 

  20. Y. Mansoori, S. V. Atghia, S. Shah Sanaei, M. R. Zamanloo, and G. H. Imanzadeh, Macromol. Res. 18, 1174 (2010).

    Article  CAS  Google Scholar 

  21. Y. Mansoori, S. V. Atghia, M. R. Zamanloo, G. H. Iman-zadeh, and M. Sirousazar, Eur. Polym. J. 46, 1844 (2010)

    Article  CAS  Google Scholar 

  22. Y. Mansoori, A. Akhtarparast, M. R. Zamanloo, G. H. Imanzadeh, and T. M. Masooleh, Polym. Compos. 32, 1225 (2011).

    Article  CAS  Google Scholar 

  23. T. G. Waddell, D. E. Leyden, and M. T. Debello, J. Am. Chem. Soc. 103, 5303(1981).

    Article  CAS  Google Scholar 

  24. T. C. Chang, Y. T. Wang, Y. S. Hong, and Y. S. Chiu, J. Polym. Sci., Part A: Polym. Chem. 38, 1972 (2000).

    Article  CAS  Google Scholar 

  25. Q. W. Zhang, Y. H. Zhang, and S. M. Chen, Appl. Chem. 19, 874 (2002).

    CAS  Google Scholar 

  26. L. Bokobza, G. Gamaud, and J. E. Mark, Chem. Mater. 14, 162 (2003).

    Article  Google Scholar 

  27. H. Xia, C. Zhang, and Q. Wang, J. Appl. Polym. Sci. 80, 1130 (2001).

    Article  CAS  Google Scholar 

  28. T. G. Waddell, D. E. Leyden, and M. T. Debello, J. Am. Chem. Soc. 103, 5303 (1981).

    Article  CAS  Google Scholar 

  29. Y. Mansoori and A. A. Entezami, Iran. Polym. J. 6, 27 (1997).

    CAS  Google Scholar 

  30. J. Zhang, R. K. Gupta, and C. A. Wilkie, Polymer 47, 4537 (2006).

    Article  CAS  Google Scholar 

  31. A. Akelah and A. Moet, J. Mater. Sci. 31, 3589 (1996).

    Article  CAS  Google Scholar 

  32. M. Salami-Kalajahi, V. Haddadi-Asl, and H. Roghani-Mamaqani, Sci. Iran. 19, 2004 (2012).

    Article  Google Scholar 

  33. X. Tai, J. H. Ma, Z. Du, and W. Wang, Appl. Surf. Sci. 268, 489(2013).

    Article  CAS  Google Scholar 

  34. S. C. Tjong and Y. H. Ruan, J. Appl. Polym. Sci. 110, 864(2008).

    Article  CAS  Google Scholar 

  35. N. A. Salahuddin, Polym. Adv. Technol. 15, 251 (2004).

    Article  CAS  Google Scholar 

  36. K. Dinakaran and M. K. Alagar, Polym. Adv. Technol. 14, 574 (2003).

    Article  CAS  Google Scholar 

  37. A. Samakande, R. D. Sanderson, and P. C. Hartmann, J. Polym. Sci., Part A: Polym. Chem. 46, 7114 (2008).

    Article  CAS  Google Scholar 

  38. J. W. Gilman, C. L. Jackson, A. B. Morgan, R. Hayyis, Jr., E. Manias, E. P. Giannelis, M. Wuthenow, D. Hilton, and S. H. Phillips, Chem. Mater. 12, 1866 (2000).

    Article  CAS  Google Scholar 

  39. A. Leszczynska, J. Njuguna, K. Pielichowski, and J. R. Banerjee, Thermochim. Acta 453, 75 (2007).

    Article  CAS  Google Scholar 

  40. B. A. Bhanvase, D. V. Pinjari, P. R. Gogate, S. H. Sonawane, and A. B. Pandit, Chem. Eng. J. 181, 770 (2012).

    Article  Google Scholar 

  41. W. A. Zhang, D. Z. Chen, H. Y. Xu, X. F. Shen, and Y. E. Fang, Eur. Polym. J. 39, 2323 (2003).

    Article  CAS  Google Scholar 

  42. S. K. Nayk and S. Mohanty, J. Appl. Polym. Sci. 112, 778 (2009).

    Article  Google Scholar 

  43. J. T. Kim, D. Y. Lee, T. S. Oh, and D. H. Lee, J. Appl. Polym. Sci. 89, 2633 (2003).

    Article  CAS  Google Scholar 

  44. A. P. Patino-Soto, S. Sanchez-Valdes, and L. F. Ramos-Devalle, J. Polym. Sci., Part B: Polym. Phys. 46, 190 (2008).

    CAS  Google Scholar 

  45. J. M. Yeh, S. J. Liou, and Y. W. Chang, J. Appl. Polym. Sci. 91, 3489 (2004).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Shahre-rey Branch, Islamic Azad University, Tehran, Iran

    Mehri Sadeghi Ganjeh & Abolfath Akbarzadeh

  2. Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran

    Neda Ahmadinejad

Authors
  1. Mehri Sadeghi Ganjeh
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  2. Neda Ahmadinejad
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  3. Abolfath Akbarzadeh
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Correspondence to Neda Ahmadinejad.

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Mehri Sadeghi Ganjeh, Ahmadinejad, N. & Akbarzadeh, A. Vinyl Modified Cloisite 30B Clay as an Efficient Filler for the Synthesis of Poly(styrene-co-butyl acrylate)/Clay Nanocomposite by Emulsion Polymerization. Polym. Sci. Ser. B 61, 493–502 (2019). https://doi.org/10.1134/S1560090419040043

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