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Adhesion Strength of TiN Coatings Deposited on VT1-0 Titanium with Different Surface Conditions

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The TiN coating obtained by vacuum-arc spraying on the surface of commercially pure VT1-0 titanium and thermodiffusion saturation in a nitrogen atmosphere was studied. The coating was evaluated by thickness, phase composition, surface roughness, microhardness, and adhesive strength. Rockwell adhesion tests showed that the TiN coatings applied to both untreated and pre-nitrided titanium meet the HF2 adhesion level accepted for commercial application on products.

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References

  1. U. Kamachi Mudali, T. M. Sridhar, and R. A. J. Baldev, “Corrosion of bio implants,” Sādhanā, 28, Iss. 3–4, 601–637 (2003). https://doi.org/10.1007/bf02706450

  2. I. M. Pohrelyuk, O. V. Tkachuk, and R. V. Proskurnyak, “Corrosion resistance of the Ti–6Al–4V titanium alloy with nitride coatings in 0.9% NaCl,” JOM, 63, Is. 6, 35–40 (2011). https://doi.org/10.1007/s11837-011-0090-6

  3. I. M. Pohrelyuk, J. Padgurskas, S. M. Lavrys, A. G. Luk’yanenko, V. S. Trush, and R. Kreivaitis, “Topography, hardness, elastic modulus and wear resistance of nitride coatings on titanium,” in: Proc. of 9th Int. Sci. Conf. BALTTRIB’2017 (Kaunas, 16–17 November 2017), pp. 41–46. https://doi.org/10.15544/balttrib.2017.09

  4. I. M. Pohrelyuk, O. V. Ovchynnykov, A. S. Skrebtsov, Kh. S. Shvachko, R. V. Proskurnyak, and S. M. Lavrys, “Corrosion properties of titanium obtained by the method of powder metallurgy,” Mater. Sci., 52, No. 5, 700–705 (2017). https://doi.org/10.1007/s11003-017-0012-z

    Article  CAS  Google Scholar 

  5. F. Seahjani, and H. Cimenoglu, “Nitriding of Cp titanium,” Defect and Diffusion Forum, 312–315, 1010–1014 (2011). https://doi.org/10.4028/www.scientific.net/DDF.312-315.1010

    Article  CAS  Google Scholar 

  6. J. Sun, Q. T. Yao, Y. H. Zhang, X. D. Du, Y. C. Wu, and W. P. Tong, “Simultaneously improving surface mechanical properties and in vitro biocompatibility of pure titanium via surface mechanical attrition treatment combined with low-temperature plasma nitriding,” Surf. Coating. Technol., 309, 382–389 (2017). https://doi.org/10.1016/j.surfcoat.2016.11.095

    Article  CAS  Google Scholar 

  7. D.-C. Sin, H.-L. Kei, and X. Miao, “Surface coatings for ventricular assist devices,” Expert Review of Medical Devices, 6, Is. 1, 51–60 (2009). https://doi.org/10.1586/17434440.6.1.51

    Article  Google Scholar 

  8. I. Dion, C. Baquey, B. Candelon, and J. R. Monties, “Hemocompatibility of titanium nitride,” Int. J. of Artificial Organs., 15, Is. 10, 617–621 (1992). https://doi.org/10.1177/039139889201501009

  9. M. Schaldach, M. Hubmann, R. Hardt, and A. Weikl, “The detection and stimulus threshold behavior of titanium nitride cardiac pacemaker electrodes [Das Detektions- und Reizschwellenverhalten von Titannitrid-Herzschrittmacher-Elektroden],” Biomedizinische Technik, 34, 185–190 (1989).

    Article  CAS  PubMed  Google Scholar 

  10. S. F. Cogan, “Neural stimulation and recording electrodes,” Annu. Rev. Biomed. Eng., 10, 275–309 (2008). https://doi.org/10.1146/annurev.bioeng.10.061807.160518

    Article  CAS  PubMed  Google Scholar 

  11. P. R. Mezger, and N. H. J. Creugers, “Titanium nitride coatings in clinical dentistry,” J. of Dentistry, 20, Is. 6, 342–344 (1992). https://doi.org/10.1016/0300-5712(92)90021-4

  12. Y. M. Ko, and H. C. Choe, “Effects of TiN film coating on the electrochemical behaviors of dental implant screw surface,” Mater. Sci. Forum, 539–543, 726–730 (2007). https://doi.org/10.4028/0-87849-428-6.726

    Article  Google Scholar 

  13. O. V. Tkachuk, I. M. Pohrelyuk, R. V. Proskurnyak, J. Guspiel, E. Beltowska-Lehman, and J. Morgiel, “Electrochemical behavior of Ti–6Al–4V alloy in Ringer’s solution after oxynitriding,” Mater. Sci., 54, No. 4, 542–546 (2019). https://doi.org/10.1007/s11003-019-00215-0

    Article  CAS  Google Scholar 

  14. W.-H. Kao, Y.-L. Su, J.-H. Horng, and Y.-T. Hsieh, “Improved tribological properties, electrochemical resistance and biocompatibility of AISI 316L stainless steel through duplex plasma nitriding and TiN coating treatment,” J. of Biomater. Appl., 32, Is. 1, 12–27 (2017). https://doi.org/10.1177/0885328217712109

  15. R. Ali, M. Sebastiani, and E. Bemporad, “Influence of Ti–TiN multilayer PVD-coatings design on residual stresses and adhesion,” Mater. & Design, 75, 47–56 (2015). https://doi.org/10.1016/j.matdes.2015.03.007

    Article  CAS  Google Scholar 

  16. G. S. Kim, S. Y. Lee, J. H. Hahn, B. Y. Lee, J. G. Han, J. H. Lee, and S. Y. Lee, “Effects of the thickness of Ti buffer layer on the mechanical properties of TiN coatings,” Surf. Coating. Technol., 171, Iss. 1–3, 83–90 (2003). https://doi.org/10.1016/S0257-8972(03)00243-3

  17. I. M. Pohrelyuk, S. E. Sheykin, S. M. Dub, A. G. Mamalis, I. Y. Rostotskii, O. V. Tkachuk, and S. M. Lavrys, “Increasing of functionality of c.p. titanium/UHMWPE tribo-pairs by thermodiffusion nitriding of titanium component,” Biotribology, 7, 38–45 (2016). https://doi.org/10.1016/j.biotri.2016.08.002

    Article  Google Scholar 

  18. H. O. Pierson, Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing and Applications, Elsevier Science, Westwood NJ (1996).

  19. ISO 2819:2017. Metallic Coatings on Metallic Substrates – Electrodeposited and Chemically Deposited Coatings, Review of Methods Available for Testing Adhesion (2017).

  20. Daimler Benz Adhesion Test VDI 3198, VDI Verlag, Dusseldorf (1992).

  21. N. Vidakis, A. Antoniadis, and N. Bilalis, “The VDI 3198 indentation test evaluation of a reliable qualitative control for layered compounds,” J. of Mater. Proces. Technol., 143–144, Is. 1, 481–485 (2003). https://doi.org/10.1016/S0924-0136(03)00300-5

  22. V. V. Vasil’ev, A. A. Luchaninov, E. N. Reshetnyak, V. E. Strel’nitskij, G. N. Tolmatcheva, and M. V. Reshetnyak, “Structure and hardness of Ti–N and Ti–Si–N coatings deposited from the filtered vacuum-arc plasma,” Probl. Atomic Sci. Technol., 2009, Is. 2, 173–180 (2009).

  23. V. P. Kolesnyk, O. M. Chuhai, D. V. Slyusar, O. S. Kalakhan, O. O. Voloshyn, S. V. Oleinyk, and H. H. Veselivs’ka, “Structure and properties of ionic-plasma WC coatings,” Mater. Sci., 55, No. 2, 214–218 (2019). https://doi.org/10.1007/s11003-019-00292-1

  24. V. F. Horban, I. V. Serdiuk, O. M. Chuhai, O. O. Voloshyn, S. V. Oliinyk, H. H. Veselivska, M. I. Danylenko, D. V. Sliusar, V. A. Stolbovyi, and O. S. Kalahan, “Specific features of the structure and electrophysical characteristics of nitride coatings based on Ti–V–Zr–Nb–Hf high-entropy alloy,” Mater. Sci., 57, No. 3, 428–433 (2021). https://doi.org/10.1007/s11003-021-00557-8

    Article  CAS  Google Scholar 

  25. A. S. Kuprin, S. A. Leonov, V. D. Ovcharenko, E. N. Reshetnyak, V. A. Belous, R. L. Vasilenko, G. N. Tolmachova, V. I. Kovalenko, and I. O. Klimenko, “Deposition of TiN-based coatings using vacuum arc plasma in increased negative substrate bias voltage,” Probl. Atomic Sci. Technol., 2019, Is. 5, 154–160 (2019).

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Authors and Affiliations

  1. Karpenko Physico-Mechanical Institute, National Academy of Sciences of Ukraine, Lviv, Ukraine

    H. H. Veselivska, I. M. Pohrelyuk & R. V. Proskurnyak

  2. National Science Center “Kharkiv Institute of Physics and Technology”, National Academy of Sciences of Ukraine, Kharkiv, Ukraine

    O. S. Kuprin

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  1. H. H. Veselivska
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  2. I. M. Pohrelyuk
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  3. R. V. Proskurnyak
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  4. O. S. Kuprin
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Correspondence to H. H. Veselivska.

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 59, No. 4, 89–94, July–August, 2023.

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Veselivska, H.H., Pohrelyuk, I.M., Proskurnyak, R.V. et al. Adhesion Strength of TiN Coatings Deposited on VT1-0 Titanium with Different Surface Conditions. Mater Sci 59, 474–479 (2023). https://doi.org/10.1007/s11003-024-00800-y

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