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Formation of nanocomposites on the basis of poly-1-vinyl-1,2,4-triazole during thermolysis of silver nitrate polymer salt

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A Correction to this article was published on 03 March 2023

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Abstract

By thermal treatment of a polymer complex of silver nitrate based on poly-1-vinyl-1,2,4-triazole without the use of an additional reducing agent we have synthesized new insoluble polymer nanocomposites containing zero-valent Ag0 silver nanoparticles in the polymeric matrix. The received nanocomposites are paramagnetic with a spin concentration of about 1018 spin g−1 and have an average size of silver particles is 4–9 nm. The study of the formation of nanoparticles in the polymeric matrix was carried out by the method of electron paramagnetic resonance involving methods of synchronous thermal analysis. It was shown by monitoring the synthesis that the formation of a nanosystem is accompanied by the oxidation of the matrix and reduction of silver ions Ag+ and Ag2+. It was found that the formation of a nanocomposite was accompanied by structural changes in the polymer matrix, which can make a negligible contribution to the overall magnetism of the resulting nanocomposite.

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Acknowledgements

The authors are grateful to the Center of Instrumental Analysis (R. Agladze Institute of Inorganic Chemistry and Electrochemistry, TSU (Tbilisi, Georgia)) and the Baikal Analytical Center of Collective Use SB RAS (A.E. Favorsky Irkutsk Institute of Chemistry SB RAS) for spectral and analytical measurements. Thermoanalytical studies were performed by M.V. Penzik and A.N. Kozlov and were carried out in the framework of the State Assignment Project (FWEU-2021-0005) of the Fundamental Research Program of the Russian Federation 2021–2030 using the resources of the High-Temperature Circuit Multi-Access Research Center (Melentiev Energy Systems Institute SB RAS), Ministry of Science and Higher Education of the Russian Federation (Project no 13.ЦКП.21.0038).

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Authors and Affiliations

  1. R. Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, 11 Mindeli St., 0186, Tbilisi, Georgia

    Spartak S. Khutsishvili

  2. A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, 1 Favorskogo St., Irkutsk, 664033, Russia

    Nikolay I. Tikhonov, Nadezhda P. Kuznetsova, Artem I. Emel’yanov & Aleksandr S. Pozdnyakov

  3. Melentiev Energy Systems Institute of the Siberian Branch of the Russian Academy of Sciences, 130 Lermontov St., Irkutsk, 664033, Russia

    Maksim V. Penzik & Aleksandr N. Kozlov

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  1. Spartak S. Khutsishvili
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The original online version of this article was revised: The figure captions of figures 2, 3 and 4 were interchanged by mistake. The figure captions were corrected.

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Khutsishvili, S.S., Tikhonov, N.I., Kuznetsova, N.P. et al. Formation of nanocomposites on the basis of poly-1-vinyl-1,2,4-triazole during thermolysis of silver nitrate polymer salt. J Therm Anal Calorim 148, 2389–2397 (2023). https://doi.org/10.1007/s10973-022-11916-1

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