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Nickel selenate: a deep and efficient characterization

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Abstract

This work aims to determine the nickel selenate hexahydrate thermal behavior by simultaneous thermogravimetry–differential thermal analysis and differential scanning calorimetry and characterize its thermal intermediates decomposition. Moreover, at 25 °C, this material is a green-colored compound; however, with the temperature increase (until 420 °C), a color change from yellowish green to yellowish orange and finally to yellow was observed. This characteristic is due to the water molecules release, changing the ultraviolet–visible/near-infrared spectroscopy analysis absorption spectra and consequently modifying the crystal structure, as confirmed by X-ray powder diffraction, and resulting in visual changes in photo-DSC. The new data are essential to determine the better conditions to use this material as a precursor in synthesis and also to use it in future applications.

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Acknowledgements

The authors wish to thank CAPES (grant 024/2012 Pro-equipment), CNPq (grant No. 421469/2016-1) and FAPESP (grants No. 2017/14936-9, No. 2018/03460-6, No. 2018/12463-9 and No. 2018/24378-6) for financial support.

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Authors and Affiliations

  1. UNESP-São Paulo State University, Chemistry Department, School of Sciences, Bauru, SP, 17033-260, Brazil

    Caroline Gaglieri, Rafael T. Alarcon, Aniele de Moura & Flávio J. Caires

  2. UNESP-São Paulo State University, Institute of Chemistry, Araraquara, SP, 14800-060, Brazil

    Flávio J. Caires

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  1. Caroline Gaglieri
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  2. Rafael T. Alarcon
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Correspondence to Flávio J. Caires.

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Photo-DSC video of nickel selenate hexahydrate (MP4 1827 kb)

MIR spectra of H2SeO4 (a), NiSeO4·6H2O (b), and NiSeO4·0.5H2O (c) (TIFF 83 kb)

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Gaglieri, C., Alarcon, R.T., de Moura, A. et al. Nickel selenate: a deep and efficient characterization. J Therm Anal Calorim 139, 1707–1715 (2020). https://doi.org/10.1007/s10973-019-08623-9

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