Skip to main content
SpringerLink
Log in

Study of the crystallization fields of nickel(II) selenites in the system NiSeO3–SeO2–H2O

  • regular
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The solubility of NiSeO3–SeO2–H2O system in the temperature region 298–573 K was studied. The compounds of the three-component system were identified by the Schreinemakers’ method. The phase diagram of nickel(II) selenites was drawn and the crystallization fields for the different phases were determined. Depending on the conditions for hydrothermal synthesis, NiSeO3·2H2O, α-NiSeO3·1/3H2O, β-NiSeO3·1/3H2O, NiSeO3 and NiSe2O5 were obtained. The different phases were proved and characterized by chemical, powder X-ray diffraction and thermal analyses as well as IR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. VG Chukhlantcev GP Tomashevskii (1957) Zh. Anal. Khim. 12 296

    Google Scholar 

  2. NM Selivanova ZL Leshchinskaya AI Maier IS Streltsov EYu Muzalev (1963) Zh. Fiz. Khim. 37 1563 Occurrence Handle1:CAS:528:DyaF3sXksFyqsr8%3D

    CAS  Google Scholar 

  3. ZL Leshchinskaya NM Selivanova AI Maier IS Srteltsov EYu Muzilev (1963) Zh. Vses. Obsh. D. Mendeleeva 8 577 Occurrence Handle1:CAS:528:DyaF2cXitVWhsA%3D%3D

    CAS  Google Scholar 

  4. NM Selivanova ZL Leshchinskaya (1964) Zh. Neorg. Khim. 9 259 Occurrence Handle1:CAS:528:DyaF2cXls1Oqtw%3D%3D

    CAS  Google Scholar 

  5. OJ Lieder G Gattow (1967) Naturwissenschaften 54 318 Occurrence Handle1:CAS:528:DyaF2sXkvVGku7k%3D Occurrence Handle10.1007/BF00640616

    Article  CAS  Google Scholar 

  6. OJ Lieder G Gattow (1967) Naturwissenschaften 54 443 Occurrence Handle1:CAS:528:DyaF1cXjtl2ktQ%3D%3D Occurrence Handle10.1007/BF00603149

    Article  CAS  Google Scholar 

  7. RA Muldagalieva AS Pashinkin EA Buketov SS Bakeeva (1969) Trudy Khim. Metalurg. Inst. Acad. Nauk Kazakh. SSR 9 11 Occurrence Handle1:CAS:528:DyaE3cXks1aiu7g%3D

    CAS  Google Scholar 

  8. SS Bakeeva EA Buketov AS Pashinkin (1969) Trudy Khim.Metalurg. Inst. Acad. Nauk Kazakh. SSR 9 16 Occurrence Handle1:CAS:528:DyaE3cXksF2ktbo%3D

    CAS  Google Scholar 

  9. VN Makatun RYa Melnikova VV Pechkovskii LM Afanasev (1973) Dokl. Akad. Nauk SSSR, Ser. Khim. 213 353 Occurrence Handle1:CAS:528:DyaE2cXhtVegt7g%3D

    CAS  Google Scholar 

  10. VN Makatun VV Pechkovskii RYa Melnikova MN Ryer (1974) Russ. J. Inorg. Chem. 19 1851

    Google Scholar 

  11. K Kohn K Inone O Horie S Akimoto (1976) J. Solid State Chem. 18 27 Occurrence Handle1:CAS:528:DyaE28XksFGjsr4%3D Occurrence Handle10.1016/0022-4596(76)90075-X

    Article  CAS  Google Scholar 

  12. M Ebert Z Mička I Peková (1982) Coll. Czech. Chem. Comm. 47 2069 Occurrence Handle1:CAS:528:DyaL38Xmt1yqtbk%3D

    CAS  Google Scholar 

  13. M Wildner (1991) Monatsh. Chem. 122 585 Occurrence Handle1:CAS:528:DyaK3MXms12jt7s%3D Occurrence Handle10.1007/BF00811457

    Article  CAS  Google Scholar 

  14. AVP McManus WTA Harrison AK Cheethan (1991) J. Solid State Chem. 92 253 Occurrence Handle1:CAS:528:DyaK3MXlsVyrt7o%3D Occurrence Handle10.1016/0022-4596(91)90333-D

    Article  CAS  Google Scholar 

  15. K Unterderweide B Engelen K Boldt (1994) J. Mol. Struct. 322 233 Occurrence Handle1:CAS:528:DyaK2cXlsVOmtr8%3D Occurrence Handle10.1016/0022-2860(94)87040-3

    Article  CAS  Google Scholar 

  16. B Engelen K Boldt K Unterderweide U Baumer (1995) Z. Anorg. Allg. Chem. 621 331 Occurrence Handle1:CAS:528:DyaK2MXktFygu7c%3D Occurrence Handle10.1002/zaac.19956210220

    Article  CAS  Google Scholar 

  17. U Baumer K Boldt B Engelen H Muller K Unterderweide (1999) Z. Anorg. Allg. Chem. 625 395 Occurrence Handle10.1002/(SICI)1521-3749(199903)625:3<395::AID-ZAAC395>3.0.CO;2-L

    Article  Google Scholar 

  18. VP Verma (1999) Thermochim. Acta 327 63 Occurrence Handle1:CAS:528:DyaK1MXhtFKgtr4%3D Occurrence Handle10.1016/S0040-6031(98)00577-2

    Article  CAS  Google Scholar 

  19. JA Mandarino (1994) Eur. J. Mineral. 6 337 Occurrence Handle1:CAS:528:DyaK2cXktl2htLk%3D

    CAS  Google Scholar 

  20. LT Vlaev SD Genieva GG Gospodinov (2005) J. Therm. Anal. Cal. 81 469 Occurrence Handle1:CAS:528:DC%2BD2MXnslyqt74%3D Occurrence Handle10.1007/s10973-005-0808-1

    Article  CAS  Google Scholar 

  21. A Kotarski (1965) Chemia Analityczna 10 161 Occurrence Handle1:CAS:528:DyaF28XnsVem

    CAS  Google Scholar 

  22. R Pribil et al. (1980) Complexonometry Izd. Thehnika Sofia

    Google Scholar 

  23. GG Gospodinov MG Stancheva (2004) J. Therm. Anal. Cal. 78 1057 Occurrence Handle1:CAS:528:DC%2BD2cXhtVGmt7rI

    CAS  Google Scholar 

  24. GG Gospodinov MG Stancheva (2005) J. Therm. Anal. Cal. 81 141 Occurrence Handle1:CAS:528:DC%2BD2MXlslOlsbY%3D Occurrence Handle10.1007/s10973-005-0758-7

    Article  CAS  Google Scholar 

  25. GF Pinaev VP Volkova (1976) Zh. Neorg. Khim. 21 1341 Occurrence Handle1:CAS:528:DyaE28XksFCrsbo%3D

    CAS  Google Scholar 

  26. AW Coats JP Redfern (1964) Nature 201 68 Occurrence Handle1:CAS:528:DyaF2cXjsFWltA%3D%3D Occurrence Handle10.1038/201068a0

    Article  CAS  Google Scholar 

  27. AW Coats JP Redfern (1965) J. Polym. Sci. Part B, 3 917

    Google Scholar 

  28. A Simon R Paetzold (1960) Z. Anorg. Allg. Chem. 303 39 Occurrence Handle1:CAS:528:DyaF3cXkvFSmtA%3D%3D Occurrence Handle10.1002/zaac.19603030106

    Article  CAS  Google Scholar 

  29. A Simon R Paetzold (1960) Z. Anorg. Allg. Chem. 303 53 Occurrence Handle1:CAS:528:DyaF3cXkvFSmug%3D%3D Occurrence Handle10.1002/zaac.19603030108

    Article  CAS  Google Scholar 

  30. CA Cody RC Levitt RS Viswanath PJ Miller (1978) J. Solid State Chem. 26 281 Occurrence Handle1:CAS:528:DyaE1MXmtlyhsg%3D%3D Occurrence Handle10.1016/0022-4596(78)90163-9

    Article  CAS  Google Scholar 

  31. RS Viswanath PJ Miller CA Cody (1979) J. Phys. Chem. Solids 40 223 Occurrence Handle1:CAS:528:DyaE1MXltFCltr4%3D Occurrence Handle10.1016/0022-3697(79)90019-2

    Article  CAS  Google Scholar 

  32. RYa Melnikova VN Makatun VV Pechkovskii (1974) Zh. Neorg. Chim. 19 1864 Occurrence Handle1:CAS:528:DyaE2cXltFehsrw%3D

    CAS  Google Scholar 

  33. M Ebert Z Mička I Pekova (1982) Chemicke Zvesti 36 169 Occurrence Handle1:CAS:528:DyaL38XksVymsbs%3D

    CAS  Google Scholar 

  34. GG Gospodinov LM Sukova KI Petrov (1988) Zh. Neorg. Khim. 33 1970 Occurrence Handle1:CAS:528:DyaL1MXjtVKhtA%3D%3D

    CAS  Google Scholar 

  35. VP Verma A Khushu (1989) J. Thermal Anal. 35 1157 Occurrence Handle1:CAS:528:DyaK3cXhvFSmtLw%3D Occurrence Handle10.1007/BF01913033

    Article  CAS  Google Scholar 

  36. VV Pechkovskii VN Makatun RYa Melnikova (1973) Zh. Neorg. Khim. 18 2023 Occurrence Handle1:CAS:528:DyaE3sXltFWgsrg%3D

    CAS  Google Scholar 

  37. VN Makatun RYa Melnikova TI Baranikova (1975) Koord. Khim. 1 920 Occurrence Handle1:CAS:528:DyaE2MXlslShur0%3D

    CAS  Google Scholar 

  38. PA Giguere M Falk (1960) Spectrochim. Acta 16 1 Occurrence Handle1:CAS:528:DyaF3cXnt1Ohsg%3D%3D Occurrence Handle10.1016/0371-1951(60)80064-1

    Article  CAS  Google Scholar 

  39. VV Pechkovskii VN Makatun (1970) Zh. Neorg. Khim. 15 2052 Occurrence Handle1:CAS:528:DyaE3cXltFGrtrs%3D

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department Physical Chemistry, Assen Zlatarov University, Bourgas, Bulgaria, 8010

    L. T. Vlaev, Svetlana D. Genieva & Velyana G. Georgieva

Authors
  1. L. T. Vlaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Svetlana D. Genieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Velyana G. Georgieva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. T. Vlaev.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vlaev, L.T., Genieva, S.D. & Georgieva, V.G. Study of the crystallization fields of nickel(II) selenites in the system NiSeO3–SeO2–H2O. J Therm Anal Calorim 86, 449–456 (2006). https://doi.org/10.1007/s10973-005-7397-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-005-7397-x

Keywords

Search

Navigation