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Preparation of LaNiO3 perovskite by oxalate and carbonate precursor method for utilization as catalyst for high-temperature decomposition of N2O

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Abstract

The mixed oxide LaNiO3 with perovskite structure was prepared by two relatively new and unconventional methods including preparation and thermal decomposition of mixed metal oxalate or carbonate precursors. The intermediates were prepared by reaction in a highly concentrated suspension (paste). The thermal decomposition conditions of these intermediates were described, and the final calcination temperatures were determined, which were done using thermal analysis methods and X-ray diffraction. During the decomposition of mixed carbonates, one-phase LaNiO3 is produced directly, and in case of decomposition of oxalates, a mixture of LaNiO3 and La2O3 is produced due to the formation of La2O2CO3 during the heating. Catalytic decomposition of nitrous oxide at high temperature (650–930 °C) and high loading (GHSV = 350,000 h−1) has shown high LaNiO3 activity, even at lower temperatures. The results were compared with the same compound obtained by co-precipitation and by solid-state reaction. Methods of preparation based on decomposition of oxalate and carbonate intermediates lead to the preparation of materials with appropriate composition, morphology, specific surface and high catalytic activity.

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Acknowledgements

The authors acknowledge the assistance provided by the Research Infrastructures NanoEnviCz (Project No. LM2015073) supported by the Ministry of Education, Youth and Sports of the Czech Republic and the project Pro-NanoEnviCz (Reg. No. CZ.02.1.01/0.0/0.0/16_013/0001821) supported by the Ministry of Education, Youth and Sports of the Czech Republic and the European Union—European Structural and Investments Funds in the frame of Operational Programme Research Development and Education.

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Authors and Affiliations

  1. Department of Inorganic Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 95, 532 10, Pardubice, Czech Republic

    Petr Bělina, Galina Sádovská, Veronika Krejčíková, Žaneta Dohnalová & Petra Šulcová

  2. Heyrovský Institute of Physical Chemistry of the Czech Academy of Sciences, Dolejškova 2155/3, 182 23, Prague 8, Czech Republic

    Galina Sádovská

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  1. Petr Bělina
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  2. Galina Sádovská
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  4. Žaneta Dohnalová
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Correspondence to Petr Bělina.

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Bělina, P., Sádovská, G., Krejčíková, V. et al. Preparation of LaNiO3 perovskite by oxalate and carbonate precursor method for utilization as catalyst for high-temperature decomposition of N2O. J Therm Anal Calorim 138, 4197–4202 (2019). https://doi.org/10.1007/s10973-019-08596-9

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