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Growth, vibrational, optical, thermal, magnetic and dielectric behavior of organo-metallic tetramethylammonium cadmium chloride crystal

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Abstract

Single crystals of tetramethylammonium cadmium chloride were grown by slow evaporation technique. The single-crystal X-ray diffraction revealed that the crystal belongs to hexagonal crystal system with P63/m space group. The crystalline nature of the grown crystal was measured by power X-ray diffraction. The presence of functional groups was identified using Fourier transform infrared and Fourier transform Raman studies. The optical absorption studies showed that the grown crystal transmit most of the incident radiation in the range of 200–800 nm. The diamagnetic property of the grown crystal has been analyzed by vibrating sample magnetometer. The mechanical stability of crystal is analyzed by Vickers microhardness study. Dielectric measurements were taken to analyze the dielectric constant and dielectric loss at different frequencies and temperatures. The thermal stability of grown crystals was confirmed by thermogravimetry/differential thermal analysis. Thermal stability of the compound was entered up to 208 °C.

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Authors and Affiliations

  1. Research and Development Center, Bharathiar University, Coimbatore, 641 046, India

    N. Bhuvaneswari

  2. Department of Physics, Dr.N.G.P. Arts and Science College, Coimbatore, 641 048, India

    N. Bhuvaneswari & N. Priyadharsini

  3. Department of Mechanical Engineering, Hindusthan College of Engineering and Technology, Coimbatore, 641 032, India

    S. Sivakumar

  4. Department of Physics, Government Arts College (Autonomous), Coimbatore, 641 018, India

    K. Venkatachalam

  5. Department of Physics, International Research Centre, Kalasalingam Academy of Research and Education, Krishnankoil, 626 126, India

    V. Siva

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  1. N. Bhuvaneswari
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  2. N. Priyadharsini
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  4. K. Venkatachalam
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  5. V. Siva
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Correspondence to N. Bhuvaneswari.

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Bhuvaneswari, N., Priyadharsini, N., Sivakumar, S. et al. Growth, vibrational, optical, thermal, magnetic and dielectric behavior of organo-metallic tetramethylammonium cadmium chloride crystal. J Therm Anal Calorim 136, 411–417 (2019). https://doi.org/10.1007/s10973-018-7908-1

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  • DOI: https://doi.org/10.1007/s10973-018-7908-1

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