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Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals

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Abstract

Potassium acid phthalate (KAP) which is also known as potassium hydrogen phthalate (KC8H5O4), a semi-organic compound was grown from its aqueous solution only by slow evaporation method at room temperature. The effect of metallic salts HgCl2 and PbCl2 as dopants in the growth aspects, thermal properties and SHG efficiency of KAP were determined using UV-VIS, FTIR spectral studies, thermal (TG and DTA) analysis and NLO test. There is only one significant mass loss step on TG curve of pure and doped KAP crystal. DTA curve exhibit a higher peak temperature in case of doped KAP crystal compared to those of pure KAP crystals.

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Authors and Affiliations

  1. Department of Chemistry, A.V.C. College, Mayiladuthurai, Tamilnadu, India

    G. Vasudevan & P. AnbuSrinivasan

  2. Department of Chemistry, ADM College, Nagapattinam, Tamilnadu, India

    G. Madhurambal

  3. Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, ON, M5S 3E5, Canada

    S. C. Mojumdar

  4. Department of Engineering, University of New Brunswick, Saint John, NB, E2L 4L5, Canada

    S. C. Mojumdar

Authors
  1. G. Vasudevan
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  2. P. AnbuSrinivasan
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  3. G. Madhurambal
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  4. S. C. Mojumdar
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Correspondence to S. C. Mojumdar.

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Vasudevan, G., AnbuSrinivasan, P., Madhurambal, G. et al. Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim 96, 99–102 (2009). https://doi.org/10.1007/s10973-008-9880-7

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  • DOI: https://doi.org/10.1007/s10973-008-9880-7

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