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Ethylethanolammonium 4-nitrobenzoate

Synthesis, structural characterization, thermal analysis, non-isothermal kinetic investigations and corrosion inhibitor efficiency

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A Correction to this article was published on 11 June 2018

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Abstract

The demand for corrosion inhibitors with low toxicity has increased in the last years in a wide range of sectors. Our study presents the synthesis, X-ray structure, thermal and kinetic investigation of ethylethanolammonium 4-nitrobenzoate (EEA4NB) as corrosion inhibitor for iron in 3% NaCl solution. Proton transfer and hydrogen bonding in the organic salt were elucidated and confirmed by infrared spectroscopy and single-crystal X-ray diffraction. Simultaneous TGA–DTA and heat flow analysis were used to study the thermal and kinetic behavior of EEA4NB. The results provided useful information about thermal stability and thermal decomposition. The non-isothermal kinetic parameters were estimated by using three different kinetic methods. Electrochemical corrosion measurements show corrosion inhibitor efficiency of EEA4NB for iron in 3% NaCl solution higher than 92% and a decrease of corrosion current and corrosion rate as a result of adsorption of EEA4NB molecules at the metal/solution interface.

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  • 11 June 2018

    The author group was published incompletely in the original publication. The complete author group is given in this erratum. The original article has been corrected.

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Acknowledgements

This work was developed through a bilateral project between Romania and Moldova, CCCDI-UEFISCDI, PN3-P3-217/24BM/19.09.2016 (Romania), 16.80013.5007.04/RO (Moldova) and Romanian Academy Program No. 2 of Institute of Chemistry Timisoara.

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Authors and Affiliations

  1. Institute of Chemistry, Timisoara of Romanian Academy, 24 Mihai Viteazul Boulevard, 300223, Timisoara, Romania

    Manuela Crisan, Nicoleta Plesu & Mihaela Petric

  2. Research Center: Thermal Analysis in Environmental Problems, West University of Timisoara, Pestalozzi Street 16, 300115, Timisoara, Romania

    Gabriela Vlase & Titus Vlase

  3. Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Street 5, 2028, Chişinău, Republic of Moldova

    Lilia Croitor, Victor Kravtsov, Yurii Chumakov & Paulina Bourosh

  4. Gebze Institute of Technology, 41400, Cayirova, Kocaeli, Turkey

    Yurii Chumakov

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  1. Manuela Crisan
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Correspondence to Gabriela Vlase.

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The original version of this article was revised: The author group was published incompletely in the original publication. The complete author group is updated.

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Crisan, M., Vlase, G., Plesu, N. et al. Ethylethanolammonium 4-nitrobenzoate. J Therm Anal Calorim 134, 343–352 (2018). https://doi.org/10.1007/s10973-018-7296-6

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