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Thermal characterization of novel magnesium oxyhalide bismo-borate glass doped with VO2+ ions

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Abstract

In the present report, physical and thermal characterizations of magnesium oxyhalide bismuth borate glasses in the composition range of \( x{\text{Mg}}X_{2} \left( {X = {\text{F}},\,{\text{Br}}} \right) \, \cdot \, \left( {30 - x} \right){\text{MgO }}\cdot \, 50{\text{B}}_{2} {\text{O}}_{3} \cdot \, 20{\text{Bi}}_{2} {\text{O}}_{3} \) (x = 0, 2, 5, 7 and 10) containing 2 mol% of V2O5 prepared by standard melt-quench technique have been discussed. The non-crystalline nature of prepared glasses has been identified through peak free X-ray diffraction profiles. Density (D), molar volume (V m) and oxygen packing density have been measured/calculated, and varying trends are discussed by relating with physical changes governed in prepared glass structures on increasing/changing the halogen (fluoride/bromide) ions. The differential thermal analysis (DTA) and thermogravimetry have been carried out in the temperature range of 200–900 °C. Glass transition temperature (T g) and melting temperature (T m) are determined from the DTA thermographs. The glass stability parameter, T g/T m is calculated from the obtained values of characteristic temperatures and a sudden decrease in stability at x = 5.0 is observed in both series which reflects that halide ions (F−/Br−) modify the glass structure at low concentrations (up to 5.0 mol%) and contribute to glass network formation at high concentrations (>5.0 mol%). Infrared absorption spectra have been recorded in the mid-IR range and evaluated to report the possible cause of band vibrations present in the spectra.

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Acknowledgements

This work was supported by University Grant Commissions, New Delhi, under Major Research Project (F. No. 40-461/2011(SR)) and Department of Science and Technology, New Delhi, under INSPIRE Fellowship No. IF130355. Thermal measurement facilities were provided by Central Instrumentation Laboratory at Deenbandhu Chhotu Ram University of Science and Technology, Murthal.

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Authors and Affiliations

  1. Department of Physics, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, 131039, Haryana, India

    M. S. Dahiya & S. Khasa

  2. Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar, 125001, Haryana, India

    A. Agarwal

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  1. M. S. Dahiya
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  2. S. Khasa
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  3. A. Agarwal
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Correspondence to M. S. Dahiya.

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Dahiya, M.S., Khasa, S. & Agarwal, A. Thermal characterization of novel magnesium oxyhalide bismo-borate glass doped with VO2+ ions. J Therm Anal Calorim 123, 457–465 (2016). https://doi.org/10.1007/s10973-015-4913-5

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