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Heat capacities and thermodynamic properties of Ni9(btz)12(DMA)6(NO3)6

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Abstract

The low-temperature molar heat capacity of crystalline Ni9(btz)12(DMA)6(NO3)6 (1) (btz = benzotriazolate; DMA = N,N′-dimethylacetamide) was measured by temperature-modulated differential scanning calorimetry for the first time. The thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 K were obtained based on the above molar heat capacity data. The compound was synthesized by solvothermal method and characterized by powder X-ray diffraction and FT-IR spectra. Moreover, the thermal stability and the decomposition mechanism of Ni9(btz)12(DMA)6(NO3)6 were investigated by thermogravimetry (TG) analysis under air atmosphere from 300 to 873 K. The experimental results through TG measurement demonstrate that the compound has a two-stage mass loss in air flow.

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Acknowledgements

The authors wish to acknowledge the financial support from the National Basic Research Program (973 Program) of China (2010CB631303), the National Natural Science Foundation of China (Nos. 20833009, 20873148, 20903095, 50901070, 51071146, 51071081, and U0734005), National Natural Science Foundation of Liaoning (No. 20102224).

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Authors and Affiliations

  1. Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, People’s Republic of China

    Yi-Xi Zhou, Li-Xian Sun, Chun-Hong Jiang, Cheng-Li Jiao, Hui Zhang, Jian Zhang, Fen Li, Zi-Ming Zhao & Huang-Zhi Zhang

  2. School of Chemistry and Biological Engineering, Changsha University of Science and Technology, Changsha, 410004, People’s Republic of China

    Yi-Xi Zhou, Zhong Cao & Hui Zhang

  3. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Fen Xu

  4. Department of Material Science & Engineering, Guilin University of Electrical Technology, Guilin, 541004, China

    Huai-Ying Zhou

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  1. Yi-Xi Zhou
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  2. Li-Xian Sun
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  3. Zhong Cao
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  4. Fen Xu
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  9. Huai-Ying Zhou
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  10. Fen Li
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Correspondence to Li-Xian Sun, Zhong Cao or Fen Xu.

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Zhou, YX., Sun, LX., Cao, Z. et al. Heat capacities and thermodynamic properties of Ni9(btz)12(DMA)6(NO3)6 . J Therm Anal Calorim 111, 1603–1608 (2013). https://doi.org/10.1007/s10973-012-2475-3

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  • DOI: https://doi.org/10.1007/s10973-012-2475-3

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