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Low-temperature heat capacities and thermodynamic properties of Mn3(HEDTA)2·10H2O

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Abstract

The low-temperature molar heat capacity of crystalline Mn3(HEDTA)2·10H2O was measured by temperature-modulated differential scanning calorimetry (TMDSC) for the first time. The thermodynamic parameters such as entropy and enthalpy relative to 298.15 K were calculated based on the above molar heat capacity data. The compound was characterized by powder XRD, FT-IR spectrum. Moreover, the thermal decomposition characteristics of Mn3(HEDTA)2·10H2O were investigated by thermogravimetry–mass spectrometer (TG–MS). The experimental result through TG measurement shows that a three-step mass loss process exists. H2O, CO2, NO, and NO2 were observed as products for oxidative degradation of Mn3(HEDTA)2·10H2O from the MS curves.

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References

  1. Zubkowski JD, Perry DL, Valente EJ, Lott S. A seven coordinate co-EDTA complex. Crystal and molecular structure of aquo(ethylenediaminetriacetatoacetic acid)cobalt(III) dihydrate. Inorg Chem. 1996;35:6352.

    Article  CAS  Google Scholar 

  2. Zasurskaya LA, Polyakova IN, Poznyak AL, Polynova TN, Sergienko. Crystal structure of strontium aqua(ethylenediaminetetraacetato)cobaltate(II) tetrahydrate Sr[CoEdta(H2O)]·4H2O. Crystallogr Rep. 2001;46:377–82.

  3. Davidovich RL, Gerasimenko AV, Logvinova VB. Synthesis and crystal structure of manganese(II) ethylenediaminetetraacetatoplumbate(II) tetrahydrate. Russ J Inorg Chem. 2004;49:694–9.

    Google Scholar 

  4. Wang J, Wang Y, Zhang ZH, Zhang XD, Tong J, Liu XZ, et al. Syntheses, characterization, and structure determination of nine-coordinate Na[Y-III(edta)(H2O)3]·5H2O and eight-coordinate Na[Y-III(cydta)(H2O)2]·5H2O complexes. J Struct Chem. 2005;46:895–905.

    Article  CAS  Google Scholar 

  5. Antsyshkina AS, Sadikov GG, Sergienko VS, Poznyak AL. The crystal structure of [Mg(H2O)6][VO(edta)]·3.5H2O. Russ J Inorg Chem. 2007;52:510–7.

    Article  Google Scholar 

  6. Huang HM, Yang HB, Li XY, Ren FF. Diammonium aqua(ethylenediaminetetraacetato) iron(II) trihydrate. Acta Crystallogr Sect E Struct Rep Online. 2009;65:m87–m88.

    Article  Google Scholar 

  7. Liu B, Gao J, Wang J, Wang YF, Xu R, Hu P, et al. Synthesis and structures of nine-coordinate K[Dy(Edta)(H2O)3]·3.5H2O, (NH4)3[Dy(Ttha)]·5H2O, and eight-coordinate NH4[Dy(Cydta)(H2O)2]·4.5H2O complexes. Russ J Coord Chem. 2009;35:422–8.

    Article  CAS  Google Scholar 

  8. Wang XF, Gao J, Wang J, Zhang ZH, Wang YF, Chen LJ, et al. Crystal structures of seven-coordinate (NH4)2[Mn-II(edta)(H2O)]·3H2O, (NH4)2[Mn-II(cydta)(H2O)]·4H2O and K-2[MNII(Hdtpa)]·3.5H2O complexes. J Struct Chem. 2008;49:724–31.

    Article  CAS  Google Scholar 

  9. Polyakova IN, Poznyak AL, Sergienko VS, Stopolyanskaya LV. Crystal structures of acid ethylenediaminetetraacetates [Cd(H2Edta)(H2O)]·2H2O and [Mn(H2O)4][Mn(HEdta)(H2O)]2 ·4H2O. Crystallogr Rep. 2001;46:40–5.

    Article  Google Scholar 

  10. Yi T, Gao S, Li BG. Edta-linked 4f–3d heterometallic two dimensional sheet in Ln2M3(edta)3(H2O)11·12H2O (Ln = Nd, Gd; M = Mn, Co). Polyhedron. 1998;17:2243–8.

    Article  CAS  Google Scholar 

  11. Richards S, Pedersen B, Silverton JV, Hoard JL. Stereochemistry of ethylenediamine tetraacetato complexes. I. The structure of crystalline Mn3(HY)10H2O and the configuration of the seven-coordinate Mn (OH2)Y−2 ion. Inorg Chem. 1964;3:27–33.

    Article  CAS  Google Scholar 

  12. Judzentiene A, Jagminas A, Padarauskas A. Application of ion interaction chromatography in the electroplating industry. Chem Anal (Warsaw). 1997;42:527–34.

    CAS  Google Scholar 

  13. AlMasri MS, Hamwi A, Mikhlallaty H. Radiochemical determination of lead-210 in environmental water samples using Cerenkov counting. J Radioanal Nucl Chem. 1997;219:73–5.

    Article  CAS  Google Scholar 

  14. Chen L, Li YQ, Huang XJ, Zhou MY. One-pot synthesis of 2-amino-2-chromenes catalyzed by tetrasodium ethylenediaminetetraacetate. Chin J Org Chem. 2009;29:437–40.

    CAS  Google Scholar 

  15. Bhor MD, Panda AG, Jagtap SR, Bhanage BM. Hydrogenation of alpha, beta-unsaturated carbonyl compounds using recyclable water-soluble Fe-II/EDTA complex catalyst. Catal Lett. 2008;124:157–64.

    Article  CAS  Google Scholar 

  16. Ahmed MJ, Haque ME. A rapid spectrophotometric method for the determination of molybdenum in industrial, environmental, biological and soil samples using 5, 7-dibromo-8-hydroxyquinoline. Anal Sci. 2002;18:433–9.

    Article  CAS  Google Scholar 

  17. Wunderlich B. The tribulations and successes on the road from DSC to TMDSC in the 20th century the prospects for the 21st century. J Therm Anal Calorim. 2004;78(1):7–31.

    Article  CAS  Google Scholar 

  18. Qi YN, Zhang J, Qiu SJ, Sun LX, Xu F, Zhu M, et al. Thermal stability, decomposition and glass transition behavior of PANI/NiO composites. J Therm Anal Calorim. 2009;98:533–7.

    Article  CAS  Google Scholar 

  19. Androsch R. Heat capacity measurements using temperature-modulated heat flux DSC with close control of the heater temperature. J Therm Anal Calorim. 2000;61(1):75–89.

    Article  CAS  Google Scholar 

  20. Reading M, Elliot D, Hill VL, Some aspects of the theory and practise of modulated differential scanning calorimetry. In: Proceedings of the 21st North American Thermal Analysis Society Conference, Atlanta, Georgia; 1992. p. 145–150.

  21. Chau J, Garlicka I, Wolf C, Teh J. Modulated DSC as a tool for polyethylene structure characterization. J Therm Anal Calorim. 2007;90:713–9.

    Article  CAS  Google Scholar 

  22. Ishida H, Rimdusit S. Heat capacity measurement of boron nitride-filled polybenzoxazine—The composite structure-insensitive property. J Therm Anal Calorim. 1999;58(3):497–507.

    Article  CAS  Google Scholar 

  23. Zhang J, Zeng JL, Liu YY, Sun LX, Xu F, You WS, et al. Thermal decomposition kinetics of the synthetic complex Pb(1, 4-BDC)·(DMF)(H2O). J Therm Anal Calorim. 2008;91:189–93.

    Article  CAS  Google Scholar 

  24. Wunderlich B, Jin YM, Boller A. Mathematical-description of differential scanning calorimetry based on periodic temperature modulation. Thermochim Acta. 1994;238:277–93.

    Article  CAS  Google Scholar 

  25. Danley RL. New modulated DSC measurement technique. Thermochim Acta. 2003;402:91–8.

    CAS  Google Scholar 

  26. Wunderlich B. The contributions of MDSC to the understanding of the thermodynamics of polymers. J Therm Anal Calorim. 2006;85:179–87.

    Article  CAS  Google Scholar 

  27. Archer DG. Thermodynamic properties of synthetic sapphire (Alpha-Al2O3), standard reference material 720 and the effect of temperature-scale differences on thermodynamic properties. J Phys Chem Ref Data. 1993;22:1441–53.

    Article  CAS  Google Scholar 

  28. Ginnings DC, Furukawa GT. Heat capacity standards for the range 14°K to 1200°K. J Am Chem Soc. 1953;75:522–7.

    Article  CAS  Google Scholar 

  29. Stavila V, Gulea A, Popa N, Shova S, Merbach A, Simonov YA, et al. A novel 3D Nd(III)-Bi(III) coordination polymer generated from EDTA ligand. Inorg Chem Commun. 2004;7(5):634–7.

    Article  CAS  Google Scholar 

  30. Qiu SJ, Chu HL, Zhang J, Qi YN, Sun LX, Xu F. Heat capacities and thermodynamic properties of CoPc and CoTMPP. J Therm Anal Calorim. 2008;91:841–8.

    Article  CAS  Google Scholar 

  31. Zhang J, Liu YY, Zeng JL, Xu F, Sun LX, You WS, et al. Thermodynamic properties and thermal stability of the synthetic zinc formate dihydrate. J Therm Anal Calorim. 2008;91:861–6.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the financial support for this study from the National Natural Science Foundation of China (No. 20833009, 20903095, 20873148, and U0734005) and the National Basic Research Program (973 program) of China (2010CB631303).

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Authors and Affiliations

  1. Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, People’s Republic of China

    Cheng-Li Jiao, Li-Fang Song, Chun-Hong Jiang, Jian Zhang, Xiao-Liang Si, Shu-Jun Qiu, Shuang Wang, Li-Xian Sun & Fen Li

  2. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Fen Xu

  3. Graduate School of the Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Cheng-Li Jiao, Li-Fang Song, Chun-Hong Jiang, Xiao-Liang Si, Shu-Jun Qiu & Shuang Wang

  4. Laboratory of Materials Modification by Laser, Electron, and Ion Beams, Dalian University of Technology, Dalian, 116024, China

    Ji-Jun Zhao

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  1. Cheng-Li Jiao
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  2. Li-Fang Song
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Correspondence to Li-Xian Sun.

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Jiao, CL., Song, LF., Jiang, CH. et al. Low-temperature heat capacities and thermodynamic properties of Mn3(HEDTA)2·10H2O. J Therm Anal Calorim 102, 1155–1160 (2010). https://doi.org/10.1007/s10973-010-0879-5

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  • DOI: https://doi.org/10.1007/s10973-010-0879-5

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