Abstract
The organic fraction of urban solid residues disposed of in sanitary landfills during the decomposition yields biogas and leachate, which are sources of pollution. Leachate is a resultant liquid from the decomposition of substances contained in solid residues and it contains in its composition organic and inorganic substances. Literature shows an increase in the use of thermoanalytical techniques to study the samples with environmental interest, this way thermogravimetry is used in this research. Thermogravimetric studies (TG curves) carried out on leachate and residues shows similarities in the thermal behavior, although presenting complex composition. Residue samples were collected from landfills, composting plants, sewage treatment stations, leachate, which after treatment, were submitted for thermal analysis. Kinetic parameters were determined using the Flynn–Wall–Ozawa method. In this case they show little divergence between the kinetic parameter that can be attributed to different decomposition reaction and presence of organic compounds in different phases of the decomposition with structures modified during degradation process and also due to experimental conditions of analysis.
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References
Companhia de tecnologia de saneamento ambiental. Inventário estadual de resíduos sólidos do estado de São Paulo. 2009. http://www.cetesb.sp.gov.br. Accessed 21 July 2010.
Lima JD. Gestão de resíduos Sólidos no Brasil. Campina Grande: Inspira Comunicação e Design; 2003
Slack RJ, Gronow JR, Voulvoulis N. Household hazardous waste in municipal landfills: contaminants in leachate. Sci Total Environ. 2005;337:119–37.
Yyazawa M, Pavan MA, Oliveira EL, Yonashiro M, Silva AK. Gravimetric determination of soil organic matter. Braz Arch Biol Tech. 2000;43:475–8.
Pietro M, Paola C. Thermal analysis for the evaluation of the organic matter evolution during municipal solid waste aerobic composting process. Thermochim Acta. 2004;413:209–14.
Biosssolidos na agricultura. 2nd ed. São Paulo: Associação Brasileira de Engenharia Sanitária e Ambiental—ABES. 2002.
Kiehl JE. Manual de compostagem: maturação e qualidade do composto. Piracicaba: Editado pelo autor; 2002.
Dell’abate MT. Thermal methods of organic matter maturation monitoring during a composting process. J Therm Anal Calorim. 2000;61:389–96.
Instituto brasileiro de geografia e estatística. Pesquisa Nacional de Saneamento. 2008. http://www.ibge.gov.br/home/presidencia. Accessed 21 June 2010.
Companhia de tecnologia de saneamento ambiental. http://pt.wikipedia.org/wiki/Companhia_de_Saneamento_B%C3%A1sico_do_Estado_de_S%C3%A3o_Paulo. Accessed 29 July 2010.
Rocha JC, Rosa AH. Substâncias húmicas aquáticas: interação com espécies metálicas. São Paulo: UNESP; 2003.
Flynn JH, Wall L. General treatment of the thermogravimetry of polymer. Polym Lett. 1966;70A:487–523.
Ozawa T. Non-isothermal kinetics and generalized time. Thermochim Acta. 1986;100:109–18.
Vyazovkin S. Model-free kinetics. Staying free of multiplying entities without necessity. J Therm Anal Calorim. 2000;83:45–51.
Liu N, Zong R, Shu L, Zhou J, FAN W. Kinetic compensation effect in thermal decomposition of cellulosic materials in air atmosphere. J Appl Polym Sci. 2003;89:135–41.
Silva AR, Crespi MS, Ribeiro CA, Oliveira SC, Silva MRS. Kinetic of thermal decomposition of residues from different kinds of composting. J Therm Anal Calorim. 2004;75:401–9.
São Carlos. In: WIKIPÉDIA: enciclopédia livre. http://pt.wikipedia.org/wiki/Categoria:S%C3%A3o_Carlos. Accessed 13 August 2010.
Associação Brasileira de Normas Técnicas. NBR 10.004-resíduos sólidos: classificação. ABNT: Rio de Janeiro; 2004.
Associação Brasileira de Normas Técnicas. NBR 10.007-amostragem de resíduos sólidos. ABNT: Rio de Janeiro; 2004.
Garcia AN, Marcila A, Font R. Termogravimetric kinetic study of the pyrolysis of municipal solid waste. Thermochim Acta. 1995;254:277–304.
Crespi MS, Silva AR, Ribeiro CA, Oliveira SC, Santiago-Silva MRS. Composting of urban solid residues (USR) by different disposition kinetic of thermal decomposition. J Therm Anal Calorim. 2003;72:1049–56.
Oliveira LC, Ribeiro CA, Rosa AH, Botero WG, Rocha JC, Romão L PC, Santos A. Thermal decomposition kinetics of humic substance extracted from mi-Rio Negro (Amazon basin) soil sample. J Braz Chem Soc. 2009;20:1003–10.
Almeida S, Lima EM, Crespi MS, Ribeiro CA, Salch V. Kinetic studies of urban solid residues and leachate from sanitary landfill. J Therm Anal Calorim. 2009;97:529–33.
Lima EN, Crespi MS, Ribeiro CA, Almeida S. Non-isothermal kinetic for lyophilized leachate from sanitary landfill and composting usine. J Therm Anal Calorim. 2007;90:823–6.
Capana AS. Caracterização e estudo do comportamento térmico de resíduo (lodo) proveniente de estação de tratamento de água e esgoto no município de Araraquara (Mestrado em Química). Araraquara: Instituto de Química, UNESP; 2009.
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The authors thank Instituto de Química de Araraquara, UNESP; Academia da Força Aérea (AFA) Pirassununga, SP and Fundação de Apoio à Ciência, Tecnologia e Educação (FACTE).
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de Almeida, S., Bernabé, G., Crespi, M.S. et al. Relation between kinetic parameters for reactions of organic matter degradation in waste environmental matrix. J Therm Anal Calorim 105, 461–465 (2011). https://doi.org/10.1007/s10973-011-1390-3
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DOI: https://doi.org/10.1007/s10973-011-1390-3