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Studies of Co(II), Ni(II), Cu(II) and Cd(II) chelates with different phosphonic acids

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Abstract

Co(II), Ni(II), Cu(II) and Cd(II) chelates with 1-aminoethylidenediphosphonic acid (AEDP, H4L1), α-amino benzylidene diphosphonic acid (ABDP, H4L2), 1-amino-2-carboxyethane-1,1-diphosphonic acid (ACEDP, H5L3), 1,3-diaminopropane-1,1,3,3-tetraphosphonicacid (DAPTP, H8L4), ethylenediamine-N,N′-bis(dimethylmethylene phosphonic)acid (EDBDMPO, H4L5), O-phenylenediamine-N,N′-bis(dimethyl methylene phosphonic)acid (PDBDMPO, H4L6), diethylene triamine-N,N,N′,N′,N″N″-penta(methylene phosphonic)acid (DETAPMPO, H10L7) and diethylene triamine-N,N″-bis(dimethyl methylene phosphonic)acid (DETBDMPO, H4L8) have been synthesised and were characterised by elemental and thermal analyses as well as by IR, UV–VIS, EPR and magnetic measurements. The first stage in the thermal decomposition process of these complexes shows the presence of water of hydration, the second denotes the removal of the coordinated water molecules. After the loss of water molecules, the organic part starts decomposing. The final decomposition product has been found to be the respective MO·P2O5. The data of the investigated complexes suggest octahedral geometry with respect to Co(II) and Ni(II) and tetragonally distorted octahedral geometry with respect to Cu(II). Antiferromagnetism has been inferred from magnetic moment data. Infrared spectral studies have been carried out to determine coordination sites.

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Acknowledgements

Thanks are due to C.S.I.R fellowships to Dr. B.V.R. Thanks are also due to Management of ALC for encouragement.

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  1. Department of Chemistry, Andhra Loyola College (Autonomous), Vijayawada, Andhra Pradesh, India

    B. Venkateswara Rao

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Rao, B.V. Studies of Co(II), Ni(II), Cu(II) and Cd(II) chelates with different phosphonic acids. J Therm Anal Calorim 100, 577–587 (2010). https://doi.org/10.1007/s10973-009-0512-7

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