Skip to main content
SpringerLink
Log in

bis(N,N-diethylnicotinamide) p-chlorobenzoate complexes of Ni(II), Zn(II) and Cd(II)

Synthesis and characterization

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Three novel mixed ligand complexes of Ni(II), Zn(II) and Cd(II) with p-chlorobenzote and N,N-diethylnicotinamide were synthesised and characterized on the basis of elemental analysis, FTIR spectroscopic analysis, solid state UV-Vis spectrometric and magnetic susceptibility data. The thermal behavior of the complexes was studied by simultaneous TG-DTA methods in static air atmosphere and the mass spectra data were recorded.

According to microanalytical results, formulas of complexes are C34H40N4O8ClNi, C34H40N4O8ClZn and C34H44N4O10ClCd. The complexes contain two moles of coordination waters, two moles p-chlorobenzoate and two mole N,N-diethylnicotinamide (dena) ligands per formula unit. In these complexes, the p-chlorobenzoate and N,N-diethylnicotinamide behave as monodentate ligand through acidic oxygen and nitrogen of pyridine ring. The decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data. The final decomposition products were found to be as metal oxides.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. Bakhtiar and E. I. Ochiai, General Pharmacology, 32 (1999) 525.

    Article  CAS  Google Scholar 

  2. A. Hossaini, J. J. Larsen and J. C. Larsen, Food Chem. Toxicology, 38 (2000) 19.

    Article  Google Scholar 

  3. K. B. Diehl, Am. Fam. Physician, 54 (1996) 1687.

    CAS  Google Scholar 

  4. D. Russell and A. D. Russell, J. Infect., 24 (1992) 333.

    Article  CAS  Google Scholar 

  5. J. R. J. Sorensen and H. Sigel, Metal Ions in Biological Systems, Marcel Dekker, New York, 14 (1982) 77.

    Google Scholar 

  6. M. Kato and Y. Muto, Coord. Chem. Rev., 92 (1988) 45.

    Article  CAS  Google Scholar 

  7. R. Nagar, J. Inorg. Biochem., 40 (1990) 349.

    Article  CAS  Google Scholar 

  8. G. Cavigiolio, L. Benedetto, E. Boccaleri, D. Colangelo, I. Viano and D. Osella, Inorg. Chim. Acta, 305 (2000) 61.

    Article  CAS  Google Scholar 

  9. U. Brühlmann and E. Hayon, J. Am. Chem. Soc., 96 (1974) 6169.

    Article  Google Scholar 

  10. M. R. Sundberg, R. Uggla and R. Kivekas, Inorg. Chim. Acta, 232 (1995) 1.

    Article  CAS  Google Scholar 

  11. T. Hökelek and H. Necefoǧlu, Anal. Sci., 15 (1999) 1043.

    Article  Google Scholar 

  12. N. N. Hoang, F. Valanch and M. Melnik, Z. Kristalogr., 208 (1999) 27.

    Article  Google Scholar 

  13. T. Hökelek and H. Necefoǧlu, Acta Cryst., C53 (1997) 187.

    Google Scholar 

  14. H. Necefoǧlu, W. Clegg and A. J. Scott, Acta Cryst., E57 (2001) 462.

    Google Scholar 

  15. D. A. Köse, Russ. J. Inorg. Chem., 52 (2007) 1384.

    Article  Google Scholar 

  16. W. Wolodkiewicz, J. Coord. Chem., 55 (2002) 727.

    Article  CAS  Google Scholar 

  17. W. Wolodkiewicz and T. Glowiak, J. Coord. Chem., 56 (2003) 563.

    Article  CAS  Google Scholar 

  18. T. S. Khodashova, M. A. Poray-Koshits, B. Ya., Rubinchik, L. A. Butman and G. V. Tsintzade, Koord. Khim., 4 (1978) 1753.

    CAS  Google Scholar 

  19. M. A. Poray-Koshits, B. Ya. Rubinchik, L. A. Butman, G. V. Tsintzade and V. S. Segienko, Koord. Khim., 4 (1978) 1760.

    Google Scholar 

  20. F. Bigoli, A. Braibanti, M. A. Pellinmghelli and A. Tiripicchio, Acta Cryst., B28 (1972) 962.

    Google Scholar 

  21. V. N. Shurkina, T. S. Khodashova, M. A. Poray-Koshits, G. V. Tsintzade and V. S. Segienko, Koord. Khim., 6 (1980) 1606.

    Google Scholar 

  22. E. F. Öztürkkan, D. A. Köse, H. Necefoǧlu and I. Uzun, Asian J. Chem., 19 (2007) 4880.

    Google Scholar 

  23. D. A. Köse, H. İçbudak and H. Necefoǧlu, Hacettepe J. Biol. Chem., 35 (2007) 123.

    Google Scholar 

  24. H. Icbudak, H. Olmez, O. Z. Yesilel, F. Arslan, P. Naumov, G. Jovanovski, A. R. Ibrahim, A. Usman, H. K. Fun, S. Chantrapromma and S. W. Ng, J. Mol. Struct., 657 (2003) 255.

    Article  CAS  Google Scholar 

  25. H. Icbudak, V. T. Yilmaz and H. Ölmez, J. Thermal Anal., 53 (1998) 843.

    Article  Google Scholar 

  26. O. Şahin, O. Büyükgüngör, D. A. Köse, E. F. Ozturkkan and H. Necefoǧlu, Acta Cryst., C63 (2007) m243.

    Google Scholar 

  27. W. Wolodkiewicz and W. Brzyska, J. Therm. Anal. Cal., 55 (1999) 639.

    Article  CAS  Google Scholar 

  28. J. Skorsepa, E. Godocikova and J. Cernak, J. Therm. Anal. Cal., 75 (2004) 773.

    Article  CAS  Google Scholar 

  29. W. Brzyska and W. Wolodkiewicz, Thermochim. Acta, 242 (1994) 131.

    Article  CAS  Google Scholar 

  30. D. A. Köse, A. Kaya and H. Necefoǧlu, Russ. J. Coord. Chem., 33 (2007) 422.

    Article  CAS  Google Scholar 

  31. E. Regulska, M. Samsonowicz, R. Swisłocka and W. Lewandowski, J. Mol. Struct., 744 (2005) 353.

    Article  CAS  Google Scholar 

  32. D. A. Köse, B. Zümreoglu-Karan, O. Şahin and O. Büyükgüngör, J. Mol. Struct., 789 (2006) 147.

    Article  CAS  Google Scholar 

  33. W. Wolodkiewicz and W. Brzyska, Pol. J. Chem., 72 (1998) 2366.

    CAS  Google Scholar 

  34. H. Icbudak, Z. Heren, D. A. Köse and H. Necefoglu, J. Therm. Anal. Cal., 76 (2004) 837.

    Article  CAS  Google Scholar 

  35. K. Györyova, E. Szunyogova, J. Kovarova, D. Hudecova, D. Mudronova and E. Juhaszova, J. Therm. Anal. Cal., 72 (2003) 587.

    Article  Google Scholar 

  36. J. Zsakó, G. Pokol, Cs. Novák, Cs. Várhelyi, A. Dobó and G. Liptay, J. Therm. Anal. Cal., 64 (2001) 843.

    Article  Google Scholar 

  37. R. Kupriel-Gorgol and W. Bryzyska, Pol. J. Chem., 59 (1985) 345.

    Google Scholar 

  38. M. Sarı, G. Gökçe, S. Gökçe, E. Şahin and H. Necefoǧlu, Acta Cryst., E63 (2007) m2191.

  39. M. Olczak-Kobza, R. Czylkowski and J. Karolak-Wojciechowska, J. Therm. Anal. Cal., 74 (2003) 895.

    Article  CAS  Google Scholar 

  40. W. Ferenc and B. Bocian, J. Therm. Anal. Cal., 74 (2003) 521.

    Article  CAS  Google Scholar 

  41. B. R. Srinivasan and S. C. Sawant, Thermochim. Acta, 402 (2003) 45.

    CAS  Google Scholar 

  42. P. Kokkonen, L. H. J. Lajunen, A. Jaakola and H. Ruotsalainen, Thermochim. Acta, 79 (1984) 289.

    Article  CAS  Google Scholar 

  43. G. A. M. Hussein, H. M. Ismail and S. A. S. Mansour, J. Anal. Appl. Pyrolysis, 36 (1996) 17.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Hacettepe University, Beytepe Campus, 06532, Ankara, Turkey

    D. A. Köse

  2. Faculty of Art and Science, Department of Chemistry, Kafkas University, Pa şaçayırı, 36100, Kars, Turkey

    D. A. Köse, G. Gökçe & S. Gökçe

  3. Department of Mechanical Engineering, Faculty of Engineering, Kýrýkkale University, 71450, Kýrýkkale, Turkey

    İ. Uzun

Authors
  1. D. A. Köse
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Gökçe
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Gökçe
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. İ. Uzun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. A. Köse.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Köse, D.A., Gökçe, G., Gökçe, S. et al. bis(N,N-diethylnicotinamide) p-chlorobenzoate complexes of Ni(II), Zn(II) and Cd(II). J Therm Anal Calorim 95, 247–251 (2009). https://doi.org/10.1007/s10973-008-9150-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-008-9150-8

Keywords

Search

Navigation