Skip to main content
SpringerLink
Log in

Thermal and spectroscopic investigation on N,N-dimethylbenzylamine based cyclopalladated compounds containing isonicotinamide

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Synthesis, spectroscopic characterization and thermal analysis of the [Pd(dmba)(Cl)(iso)] (1), [Pd(dmba)(NCO)(iso)] (2), [Pd(dmba)(N3)(iso)] (3) and [Pd(dmba)(Br)(iso)] (4) (dmba = N,N′-dimethylbenzylamine; iso = isonicotinamide) compounds are described in this work. The complexes were investigated by infrared spectroscopy (IR), differential thermal analysis (DTA) and thermogravimetry (TG) and the residues of the thermal decomposition were identified as Pdo by X-ray powder diffraction. The thermal stability order of the complexes varied as [Pd(dmba)(Cl)(iso)] (1) > [Pd(dmba)(Br)(iso)] (4) > [Pd(dmba)(NCO)(iso)] (2) > [Pd(dmba)(N3)(iso)] (3).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Saccomando DJ, Black C, Cave GWV, Lyndon DP, Rourke JR. Chiral cyclopalladated liquid crystals from amino acids. J Organomet Chem. 2000;601:305–10.

    Article  CAS  Google Scholar 

  2. Dupont J, Gruber AS, Fonseca GS, Monteiro AL, Ebeling G, Burrow BA. Synthesis and catalytic properties of configurationally stable and non-racemic sulfur-containing palladacycles. Organometallics. 2001;20:171–6.

    Article  CAS  Google Scholar 

  3. da Rocha MC, Santana AM, Ananias SR, de Almeida ET, Mauro AE, Placeres MCP, et al. Cytotoxicity and immune response induced by organopalladium(II) compounds in mice bearing Ehrlich ascites tumour. J Braz Chem Soc. 2007;18:1473–80.

    CAS  Google Scholar 

  4. Johnsson K, King DS, Schultz PG. Studies on the mechanism of action of isoniazid and ethionamide in the chemotherapy of tuberculosis. J Am Chem Soc. 1995;117:5009–10.

    Article  CAS  Google Scholar 

  5. Santana AM, Mauro AE, Zorel HE Jr, Mattioli MPD, de Lucca Netto VA. Thermal and spectroscopy investigation of cyclopalladated compounds of the type [Pd(C13H10N)(µ-X)]2 (X = H3CCOO, NCO, SCN, CN). J Therm Anal Calorim. 2002;67:425–31.

    Article  CAS  Google Scholar 

  6. Netto AVG, Santana AM, Mauro AE, Frem RCG, de Almeida ET, Crespi MS, et al. Thermal decomposition of palladium(II) pyrazolyl complexes. Part II. J Therm Anal Calorim. 2005;79:339–42.

    Article  CAS  Google Scholar 

  7. Netto AVG, Frem RCG, Mauro AE, Crespi MS, Zorel HE Jr. Synthesis, spectral and thermal studies on pyrazolate-bridged palladium(II) coordination polymers. J Therm Anal Calorim. 2007;87:789–92.

    Article  CAS  Google Scholar 

  8. Moro AC, Mauro AE, Ananias SR, Stevanato A, Legendre AO. Mono- and dinuclear palladium(II) compounds containing N,S donor ligands. J Therm Anal Calorim. 2007;87:721–4.

    Article  CAS  Google Scholar 

  9. de Lucca Netto VA, Mauro AE, Caires ACF, Ananias SR, de Almeida ET. Synthesis, characterization and thermal behavior of cyclopalladated compounds of the type [Pd{C6H4CH2N(CH3)2}(µ-X)]2 (X = Cl, NCO, SCN, CN). Polyhedron. 1998;18:413–7.

    Article  Google Scholar 

  10. Powder Diffraction File of the Joint Committee on Powder Diffraction Standards. Sets 1-32, published by the International Center of Diffraction Data, Swarthmore, PA 19081, USA (1982).

  11. Ataç A, Yurdakul Ş, Íde S. Synthesis and vibrational spectroscopic studies of isonicotinamide metal(II) halide complexes. J Mol Struct. 2006;783:79–87.

    Article  Google Scholar 

  12. Treu Filho O, Pinheiro JC, da Costa EB, Kondo RT, de Souza RA, Nogueira VM, et al. Theoretical and experimental study of the infrared spectrum of isonicotinamide. J Mol Struct. 2006;763:175–9.

    CAS  Google Scholar 

  13. Golub AM, Köhler H, Skopenko VV. Chemistry of pseudohalides. New York: Elsevier; 1986.

    Google Scholar 

Download references

Acknowledgements

We thank the CNPq, CAPES, and FAPESP for financial support.

Author information

Authors and Affiliations

  1. Instituto de Química de Araraquara, UNESP, C.P. 355, Araraquara, SP, 14801-970, Brazil

    Alessandra Stevanato, Antonio E. Mauro & Adelino V. G. Netto

Authors
  1. Alessandra Stevanato
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Antonio E. Mauro
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Adelino V. G. Netto
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Antonio E. Mauro.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stevanato, A., Mauro, A.E. & Netto, A.V.G. Thermal and spectroscopic investigation on N,N-dimethylbenzylamine based cyclopalladated compounds containing isonicotinamide. J Therm Anal Calorim 97, 149 (2009). https://doi.org/10.1007/s10973-009-0251-9

Download citation

  • Published:

  • DOI: https://doi.org/10.1007/s10973-009-0251-9

Keywords

Search

Navigation