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Mono- and dinuclear palladium(II) compounds containing N,S donor ligands

Synthesis, characterization and thermal behavior

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Abstract

Synthesis, spectroscopic characterization and thermal analysis of the compounds [Pd2(dmba)2(μ-NCO)(μ-2-qnS)] (1), [Pd2(dmba)2(μ-NCO)(μ-8-qnS)] (2), [Pd(2-qnS)2] (3) and [Pd(8-qnS)2] (4) (dmba=N,N-dimethylbenzylamine; 2-qnS=2-quinolinethiolate; 8-qnS=8-quinolinethiolate) are described. The thermal decomposition of these compounds occurs in four consecutive steps and the final decomposition products were identified as Pd(0) by X-ray powder diffraction. The thermal stability order of the complexes is 4>3>1>2.

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Authors and Affiliations

  1. Instituto de Química de Araraquara, UNESP, Araraquara, Brazil, 14801-970, SP, C.P. 355

    A. C. Moro, A. E. Mauro, A. Stevanato & A. O. Legendre

  2. Departamento de Análises Clínicas, Faculdade de Ciências Farmacêuticas, UNESP, Araraquara, Brazil, 14801-902, SP, C.P. 502

    S. R. Ananias

Authors
  1. A. C. Moro
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  2. A. E. Mauro
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  3. S. R. Ananias
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  4. A. Stevanato
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  5. A. O. Legendre
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Correspondence to A. E. Mauro.

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Moro, A.C., Mauro, A.E., Ananias, S.R. et al. Mono- and dinuclear palladium(II) compounds containing N,S donor ligands. J Therm Anal Calorim 87, 721–724 (2007). https://doi.org/10.1007/s10973-006-7770-4

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  • DOI: https://doi.org/10.1007/s10973-006-7770-4

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