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Three-parametric equation in evaluation of thermal dissociation of reference compound

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Abstract

Further considerations concerning thermal decomposition of reference material — CaCO3, described by three-parametric equation in version (3), have been presented. It was established that in linear relationship between coefficients of Eq. (3) a 2 is the argument of a 1, which reaches minimal value of thermodynamic character (δH/vR) when a 2=0 (equilibrium relationship). During thermal decomposition connection between system atmosphere — rich in CO2 or vacuum, caused by fast evacuation of gaseous products — and activation energy value, as well as maximal temperature of reaction process. Conditions of this kind may be explained by Zawadzki-Bretsznajder law.

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Authors and Affiliations

  1. Department of Inorganic Chemistry and Technology, Silesian University of Technology, Krzywoustego 6, 44-100, Gliwice, Poland

    A. Mianowski & Izabela Baraniec

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  1. A. Mianowski
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  2. Izabela Baraniec
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Correspondence to A. Mianowski.

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Mianowski, A., Baraniec, I. Three-parametric equation in evaluation of thermal dissociation of reference compound. J Therm Anal Calorim 96, 179–187 (2009). https://doi.org/10.1007/s10973-008-9559-0

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