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The kinetics of thermal decomposition of bismuth oxohydroxolaurate

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Abstract

The bismuth salt of lauric (dodecanic) acid Bi6O4(OH)4(C11H23COO)6 was studied earlier. This salt has layer structure (the interlaminar distance=37.50 Å), under heating this liquid-crystalline state has the mesomorphic transformation, turns to the amorphous state, decomposes stepwise with the formation of well-ordered layers of bismuth nanoparticles. DSC-curves were used for the study of the decomposition kinetics in the area of decomposition with small mass loss and exothermic effect (423–483 K).

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Authors and Affiliations

  1. Siberian Branch of Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, Novosibirsk–90, Russia, 630090, Ac. Lavrentyev Ave. 3

    V. Logvinenko

  2. Siberian University of Consumer’s Cooperation, Novosibirsk, Russia, 630087, K. Marx Ave. 26

    K. Mikhailov & Yu. Yukhin

Authors
  1. V. Logvinenko
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  2. K. Mikhailov
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  3. Yu. Yukhin
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Correspondence to V. Logvinenko.

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Logvinenko, V., Mikhailov, K. & Yukhin, Y. The kinetics of thermal decomposition of bismuth oxohydroxolaurate. J Therm Anal Calorim 88, 47–49 (2007). https://doi.org/10.1007/s10973-006-8056-6

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  • DOI: https://doi.org/10.1007/s10973-006-8056-6

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