Skip to main content
SpringerLink
Log in

New cobalt and rare earth metal tungstates CoRE2W2O10

Their synthesis and some properties

  • Regular Papers
  • Complexes
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

A new family of cobalt and rare-earth metal tungstates (CoRE2W2O10 where RE=Y, Dy, Ho and Er) were synthesized by heating in the solid-state equimolar CoWO4/RE2WO6 mixtures. The obtained compounds are isostructural and crystallize in the monoclinic system. They melt incongruently in an inert atmosphere at 1494 K (CoY2W2O10), 1523 K (CoDy2W2O10), 1517 K (CoHo2W2O10) and 1493 K (CoEr2W2O10). For each CoRE2W2O10 compound the solid product of melting is an adequate RE2WO6.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Sulcova and M. Trojan, J. Therm. Anal. Cal., 83 (2006) 557.

    Article  CAS  Google Scholar 

  2. K. Akiyama, H. Aoyama, N. Abe, T. Tojo, H. Kawaji and T. Atake, J. Therm. Anal. Cal., 81 (2005) 583.

    Article  CAS  Google Scholar 

  3. P. Sulcova, J. Therm. Anal. Cal., 82 (2005) 51.

    Article  CAS  Google Scholar 

  4. G. Blasse and B. C. Grabmaier, Luminescent Materials, Springer, Berlin, Heidelberg 1994.

    Google Scholar 

  5. C. Feldmann, T. Jüstel, C. R. Ronda and P. J. Schmidt, Adv. Funct. Mater., 13 (2003) 511.

    Article  CAS  Google Scholar 

  6. Y. Zhou and J. Lin, J. Solid State Chem., 178 (2005) 441.

    Article  CAS  Google Scholar 

  7. P. Zhang, Z. Hong, M. Wang, X. Fang, G. Qian and Z. Wang, J. Lumin., 113 (2005) 89.

    Article  CAS  Google Scholar 

  8. R. Scheps, Prog. Quant. Electron, 20 (1996) 271.

    Article  CAS  Google Scholar 

  9. E. Downing, L. Hesselink, J. Raltson and R. Macfarlane, Science, 273 (1996) 1185.

    Article  CAS  Google Scholar 

  10. E. Tomaszewicz, Solid State Sci., 8 (2006) 508.

    Article  CAS  Google Scholar 

  11. E. Tomaszewicz, Thermochim. Acta, 447 (2006) 69.

    Article  CAS  Google Scholar 

  12. D. Taupin, J. Appl. Cryst., 1 (1968) 78.

    Article  Google Scholar 

  13. D. Taupin, J. Appl. Cryst., 6 (1973) 380.

    Article  CAS  Google Scholar 

  14. D. Louer and M. Louer, J. Appl. Cryst., 5 (1972) 271.

    Article  CAS  Google Scholar 

  15. A. Boultif and D. Louer, J. Appl. Cryst., 24 (1991) 987.

    Article  CAS  Google Scholar 

  16. V. I. Tsaryuk and V. F. Zolin, Spectrochim. Acta, A57 (2001) 355.

    Google Scholar 

  17. J. Hanuza, M. Mączka and J. H. van der Maas, J. Solid State Chem., 117 (1995) 177.

    Article  CAS  Google Scholar 

  18. M. Daturi, G. Busca, M. M. Borel, A. Leclaire and P. Piaggio, J. Phys. Chem., B101 (1997) 4358.

    Google Scholar 

  19. J. Hauck and A. Fadini, Z. Naturforsch., B25 (1970) 422.

    Google Scholar 

  20. M. Mączka, J. Solid State Chem., 129 (1997) 287.

    Article  Google Scholar 

  21. J. Hanuza, L. Macalik, M. Mączka, E. T. G. Lutz and J. H. van der Maas, J. Mol. Struct., 511–512 (1999) 85.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, Szczecin University of Technology, Al. Piastow 42, 71065, Szczecin, Poland

    E. Tomaszewicz

Authors
  1. E. Tomaszewicz
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Tomaszewicz.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tomaszewicz, E. New cobalt and rare earth metal tungstates CoRE2W2O10 . J Therm Anal Calorim 90, 255–259 (2007). https://doi.org/10.1007/s10973-006-7721-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7721-0

Keywords

Search

Navigation