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New binuclear ferrocenecarboxylates of rare-earth metals as precursors for ferrites: Syntheses, structures, and solid-phase thermolysis

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Abstract

New ferrocenecarboxylates of rare-earth metals, [Ln2(μ-O,η2-OOCFc)2(μ2-O,O′-OOCFc)2(η2-NO3)2(DMSO)4] (Ln = Gd (I), Tb (II), and Y (III)) and [Gd2(μ-O,η2-OOCFc)2(η2-OOCFc)4(DMSO)2(H2O)2] · 2DMSO · 2CH2Cl2 (IV), are synthesized and characterized by X-ray diffraction analysis. Unlike all earlier known ferrocenecarboxylates of rare-earth metals, in isostructural compounds I–III the Ln atoms are linked by four bridging carboxyl residues, two of which are chelate-bridging (the coordination number of Ln is 9). Binuclear structure IV is formed by two chelate-bridging carboxylate ligands (the coordination number of Gd is 9). Weak antiferromagnetic and weak ferromagnetic interactions between the Gd atoms are observed in complexes I and IV, respectively. The thermal decomposition of the synthesized compounds is studied by differential scanning calorimetry and thermogravimetry. According to the X-ray diffraction data, the final thermolysis products of the complexes in air are garnets Ln3Fe5O12.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    P. S. Koroteev, Zh. V. Dobrokhotova, N. N. Efimov, A. B. Ilyukhin & V. M. Novotortsev

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  1. P. S. Koroteev
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  2. Zh. V. Dobrokhotova
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  3. N. N. Efimov
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  4. A. B. Ilyukhin
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  5. V. M. Novotortsev
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Correspondence to P. S. Koroteev.

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Dedicated to the 80th Anniversary of the Kurnakov Institute of General and Inorganic Chemistry

Original Russian Text © P.S. Koroteev, Zh.V. Dobrokhotova, N.N. Efimov, A.B. Ilyukhin, V.M. Novotortsev, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 7, pp. 438–448.

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Koroteev, P.S., Dobrokhotova, Z.V., Efimov, N.N. et al. New binuclear ferrocenecarboxylates of rare-earth metals as precursors for ferrites: Syntheses, structures, and solid-phase thermolysis. Russ J Coord Chem 40, 495–504 (2014). https://doi.org/10.1134/S1070328414070045

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  • DOI: https://doi.org/10.1134/S1070328414070045

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