Abstract
A procedure was developed for preparing Mn(II) and Co(II) triuranates MIIU3O10·6H2O by the reaction of schoepite UO3·2.25H2O with aqueous solutions of Mn(II) and Co(II) nitrates. Methods of hightemperature X-ray diffraction, IR spectroscopy, thermal analysis, and chemical analysis were used for determining the composition and structure of the compounds and for studying their dehydration and thermal decomposition.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Shannon, R.D., Acta Crystallogr., Sect. A, 1976, vol. 32, p. 751.
Lavrukhina, A.K. and Yukina, L.V., Analiticheskaya khimiya margantsa (Analytical Chemistry of Manganese), Moscow: Nauka, 1974.
Pyatnitskii, I.V., Analiticheskaya khimiya kobal’ta (Analytical Chemistry of Cobalt), Moscow: Nauka, 1965.
Nipruk, O.V., Knyazev, A.V., Chernorukov, G.N., and Pykhova, Yu.P., Radiochemistry, 2011, vol. 53, no. 2, pp. 146–150.
Yukhnevich, G.V., Infrakrasnaya spektroskopiya vody (Infrared Spectroscopy of Water), Moscow: Nauka, 1973.
Serezhkina, L.B., Bushuev, N.N., and Serezhkin, V.N., Zh. Neorg. Khim., 1978, vol. 23, no. 3, pp. 756–760.
Serezhkin, V.N., Serezhkina, L.B., and Duboshina, L.V., Radiokhimiya, 1978, vol. 20, no. 4, pp. 575–578.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.V. Nipruk, N.G. Chernorukov, K.A. Chaplieva, G.N. Chernorukov, 2015, published in Radiokhimiya, 2015, Vol. 57, No. 6, pp. 490–493.
Rights and permissions
About this article
Cite this article
Nipruk, O.V., Chernorukov, N.G., Chaplieva, K.A. et al. Synthesis and study of manganese and cobalt triuranates MIIU3O10·6H2O. Radiochemistry 57, 575–579 (2015). https://doi.org/10.1134/S1066362215060028
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1066362215060028