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Vibrational spectroscopic study of sol–gel layered double hydroxides containing different tri- and tetravalent cations

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Abstract

Five different layered double hydroxides were synthesized from magnesium ethoxide in the presence of aluminium, gallium, indium, tin and zirconium acetylacetonates by using the sol–gel technique. The colloid suspensions initially obtained were gelled and separated by centrifugation. XRD patterns confirmed that the five solids thus obtained possessed a layered double hydroxide structure. Also, IR and Raman spectra revealed differences between the solids.

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Acknowledgments

The authors wish to acknowledge funding of this work by Spain’s Ministerio de Educación, Cultura y Deporte (Project MAT-2013-44463-R), Junta de Andalucía and FEDER Funds.

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Authors and Affiliations

  1. Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie, Carretera Nnal. IV-A km. 396, 14071, Córdoba, Spain

    Daniel Cosano, César Jiménez-Sanchidrián & José Rafael Ruiz

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  1. Daniel Cosano
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  2. César Jiménez-Sanchidrián
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  3. José Rafael Ruiz
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Correspondence to José Rafael Ruiz.

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Cosano, D., Jiménez-Sanchidrián, C. & Ruiz, J.R. Vibrational spectroscopic study of sol–gel layered double hydroxides containing different tri- and tetravalent cations. J Sol-Gel Sci Technol 76, 614–620 (2015). https://doi.org/10.1007/s10971-015-3812-3

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  • DOI: https://doi.org/10.1007/s10971-015-3812-3

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