Abstract
Three different hydrotalcites were synthesized from magnesium ethoxide, and aluminium, gallium and indium acetylacetonate, using the sol–gel technique. The colloid suspensions initially obtained were gelled and separated by centrifugation. XRD diffraction patterns confirmed that all solids thus obtained possessed a hydrotalcite structure. The resulting hydrotalcites were characterized by mid-infrared (MIR) and near-infrared (NIR) spectroscopies. The two types of spectra were found not to depend on the synthetic medium or trivalent metal used and were thus quite similar. The MIR spectra for the three solids included a strong band at 3500–3000 cm−1 due to stretching vibrations of the different types of O–H groups in them. The signal at about 1370 cm−1 observed for all solids indicates that the sole interlayer anion present was carbonate. The NIR spectra exhibited the bands for the first and second overtone of the O–H stretching vibration in addition to various combination bands.
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References
Rives V (2001) Layered double hydroxides: present and future. Nova Science Publishers, New York
Cavani F, Trifiro F, Vaccari A (1991) Hydrotalcite-type anionic clays: preparation, properties and applications. Catal Today 11:173–301
Forano C, Hibino T, Leroux F, Taviot-Gueho C (2006) Handbook of clay science, Developments in clay science vol. 1. Elsevier, Amsterdam
Arizaga GGC, Satyanarayana KG, Wypych F (2007) Layered hydroxide salts: synthesis, properties and potential applications. Solid State Ionics 178:1143–1162
Constantino U, Marmottini F, Nocchetti M, Vivani R (1998) New synthetic routes to hydrotacite-like compounds. Characterization and properties of the obtained materials. Eur J Inorg Chem 1443–1446
Rao MM, Reddy BR, Jayalakshmi M, Jaya VS, Sridar B (2005) Hydrotermal synthesis of Mg-Al hydrotalcites by urea hydrolisis. Mat Res Bull 40:347–359
Ramos E, Topez T, Bosch P, Asomoza M, Gomez R (1997) Thermal stability of sol-gel hydrotalcites. J Sol-Gel Sci Technol 8:437–442
Greenwall HC, Holliman PJ, Jones W, Velasco BV (2006) Studies of the effects of synthetic procedure on base catalysis using hydroxide-intercalated layer double hydroxides. Catal Today 114:397–402
Othman MR, Kim J (2008) The study of the conversion of intercalated compounds synthesized from a sol-gel procedure. J Sol-Gel Sci Technol 47:274–282
Frost RL, Spratt HJ, Palmer SJ (2009) Infrared and near-infrared spectroscopic study of synthetic hydrotalcites with variable divalent/trivalent cationic ratios. Spectrochim Acta 72:984–988
Frost RL, Erickson KL (2005) Near-infrared spectroscopy of stitchtite, iowaite, desautelsite and arsenate exchanged takovite and hydrotalcite. Spectrochim Acta 61:51–56
Aramendia MA, Avilés Y, Benítez JA, Borau V, Jiménez C, Marinas JM, Ruiz JR, Urbano FJ (1999) Comparative study of Mg/Al and Mg/Ga layered double hydroxides. Microp Mesop Mater 29:319–328
Aramendia MA, Borau V, Jiménez C, Marinas JM, Luque JM, Ruiz JR, Urbano FJ (2000) Synthesis and characterization of a novel Mg/In hydrotalcite-like compound. Mater Lett 43:118–121
Kagunya W, Baddour-Hadjean R, Kooli F, Jones W (1998) Vibrational modes in layered double hydroxides and their calcined derivatives. Chem Phys 236:225–234
Mora M, Jiménez-Sanchidrián C, Ruiz JR (2006) Heterogeneous Suzuki cross coupling reactions over palladium/hydrotalcite catalysts. J Coll Interf Sci 302:568–575
Aramendía MA, Avilés Y, Borau V, Luque JM, Marinas JM, Ruiz JR, Urbano FJ (1999) Thermal decomposition of Mg/Al and Mg/Ga layered double hydroxides: a spectroscopic study. J Mater Chem 9:1603–1607
Clause O, Gazzano M, Trifiro F, Vaccari A, Zatorski L (1991) Preparation and thermal reactivity of nickel/chromium and nickel/aluminium hydrotalcite-type precursors. Appl Catal 73:217–236
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The authors wish to acknowledge funding of this work by Spain’s Ministry of Science and Education (Project MAT2006-04847), Junta de Andalucía and FEDER Funds.
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Mora, M., López, M.I., Jiménez-Sanchidrián, C. et al. MIR and NIR spectroscopy of sol–gel hydrotalcites with various trivalent cations. J Sol-Gel Sci Technol 55, 59–65 (2010). https://doi.org/10.1007/s10971-010-2213-x
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DOI: https://doi.org/10.1007/s10971-010-2213-x