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Layered Rare Earth Hydroxides React with Formamide to Give [Ln(HCOO)3 · 2(HCONH2)]

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Abstract

The long-term (longer than 30 days) stability of dispersions in formamide of layered REE (Y, Gd, and Eu) hydroxides intercalated with dodecyl sulfate anion has been studied for the first time. It has been shown that layered yttrium, gadolinium, and europium hydroxides intercalated with dodecyl sulfate anion react with formamide to form [Ln(HCOO)3 · 2(HCONH2)] (Ln = Y, Gd, or Eu). The structure of the obtained compounds has been determined by single-crystal X-ray diffraction. Obtained data indicate that the colloidal solutions of quasi 2D crystals of layered REE hydroxides in formamide remain stable for several days.

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Funding

This work was performed under the State assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of Fundamental research with the use of equipment of the Shared Facility Center, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, operating under the State assignment for the Kurnakov Institute of General and Inorganic Chemistry, in the field of Fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Rodina, A. D. Yapryntsev, A. V. Churakov & A. E. Baranchikov

  2. Moscow State University, 119991, Moscow, Russia

    A. A. Rodina

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  1. A. A. Rodina
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  2. A. D. Yapryntsev
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  3. A. V. Churakov
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  4. A. E. Baranchikov
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Correspondence to A. E. Baranchikov.

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Translated by I. Kudryavtsev

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Rodina, A.A., Yapryntsev, A.D., Churakov, A.V. et al. Layered Rare Earth Hydroxides React with Formamide to Give [Ln(HCOO)3 · 2(HCONH2)]. Russ. J. Inorg. Chem. 66, 125–132 (2021). https://doi.org/10.1134/S0036023621020169

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