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A new way to prepare tin oxide precursor polymeric gels

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Abstract

Transparent tin oxide gels are elaborated in the isopropoxide/toluene/isopropanol system. The gelation occurs at room temperature without any acid or base additions. The formation of the SnO2 precursor gels polymeric network is evidenced by Fourier transform infrared spectroscopy. The gelation time is studied as a function of the complexing ratio R = [acac]/[Sn(OR)4], the hydrolysis ratio W = [H2O]/[Sn(OR)4], the concentration of tin oxide precursor C = [Sn(OR)4], and the volume fraction of toluene P = (toluene volume) / (total solvent volume).

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Authors and Affiliations

  1. Laboratoire Sciences des Procédés Céramiques et de Traitements de Surface, SPCTS, UMR CNRS 6638, ENSCI, 47 Avenue Albert Thomas, 87065, Limoges Cedex, France

    W. Hamd, A. Boulle, E. Thune & R. Guinebretiere

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  1. W. Hamd
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  2. A. Boulle
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  3. E. Thune
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  4. R. Guinebretiere
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Correspondence to R. Guinebretiere.

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Hamd, W., Boulle, A., Thune, E. et al. A new way to prepare tin oxide precursor polymeric gels. J Sol-Gel Sci Technol 55, 15–18 (2010). https://doi.org/10.1007/s10971-010-2206-9

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  • DOI: https://doi.org/10.1007/s10971-010-2206-9

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