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Tin Dioxide-Based Superacid Aerogels Produced Using Propylene Oxide

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Tin dioxide-based aerogels were produced by supercritical drying of gels, synthesized using propylene oxide, in CO2 and isopropanol. Aerogels consisted of nanocrystalline cassiterite and had a specific surface area of 210–270 m2/g. Sulfation with sulfuryl chloride imparted superacidic properties to the aerogels (the Hammett acidity function H0 reached values within the range – 11.99 ≥ H0 ≥ –12.7). Superacid SnO2 aerogels demonstrated high catalytic activity in 1-hexene oligomerization and isomerization.

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Authors and Affiliations

  1. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    S. A. Lermontov, L. L. Yurkova & E. A. Straumal

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. E. Baranchikov & V. K. Ivanov

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    I. G. Shunina & E. I. Knerel’man

  4. Lomonosov Institute of Fine Chemical Technologies, Moscow, 119571, Russia

    V. K. Ivanov

Authors
  1. S. A. Lermontov
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  2. L. L. Yurkova
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  3. E. A. Straumal
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  4. A. E. Baranchikov
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  5. I. G. Shunina
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  6. E. I. Knerel’man
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  7. V. K. Ivanov
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Corresponding author

Correspondence to S. A. Lermontov.

Additional information

Original Russian Text © S.A. Lermontov, L.L. Yurkova, E.A. Straumal, A.E. Baranchikov, I.G. Shunina, E.I. Knerel’man, V.K. Ivanov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 3, pp. 283–288.

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Lermontov, S.A., Yurkova, L.L., Straumal, E.A. et al. Tin Dioxide-Based Superacid Aerogels Produced Using Propylene Oxide. Russ. J. Inorg. Chem. 63, 303–307 (2018). https://doi.org/10.1134/S0036023618030142

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  • DOI: https://doi.org/10.1134/S0036023618030142

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