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Effect of polycarbodiimide on the structure and mechanical properties of PLA/PBAT blends

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Abstract

In this paper, the effects of two epoxy chain extenders and polycarbodiimide on the mechanical properties, crystallization behavior, morphology and thermal stability of poly(L-lactic acid) (PLLA)/poly(butylene adipate-co-terephthalate) (PBAT) blends were studied. The addition of the chain extenders and polycarbodiimide could improve the compatibility of PLA and PBAT. Polycarbodiimide could effectively improve the mechanical properties of PLLA/PBAT blends. PLA/PBAT (50/50) blend with polycarbodiimide could be used as an additive to prepare PLA/PBAT (70/30) blend, and the obtained PLA/PBAT (70/30) blend had good compatibility and the elongation at break of 368%. Polycarbodiimide modified PLA/PBAT blend can be used as a compatibilizer for common PLA/PBAT blends to improve mechanical properties.

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References

  1. Somsunan R, Noppakoon S and Punyodom W (2019) Effect of G40 plasticizer on the properties of ternary blends of biodegradable PLA/PBS/G40. J Polym Res 26

  2. Anderson KS, Hillmyer MA (2004) The influence of block copolymer microstructure on the toughness of compatibilized polylactide/polyethylene blends. Polymer 45:8809–8823

    Article  CAS  Google Scholar 

  3. Li Y, Shimizu H (2009) Improvement in toughness of poly(l-lactide) (PLLA) through reactive blending with acrylonitrile–butadiene–styrene copolymer (ABS): Morphology and properties. Eur Polymer J 45:738–746

    Article  CAS  Google Scholar 

  4. Hongdilokkul P, Keeratipinit K, Chawthai S, Hararak B, Seadan M, Suttiruengwong S (2015) A study on properties of PLA/PBAT from blown film process. IOP Conf Ser Mater Sci Eng 87:012112

    Article  Google Scholar 

  5. Wu N, Zhang H (2017) Mechanical properties and phase morphology of super-tough PLA/PBAT/EMA-GMA multicomponent blends. Mater Lett 192:17–20

    Article  CAS  Google Scholar 

  6. Yeh J, Tsou C, Huang C, Chen K, Wu C, Chai W (2010) Compatible and crystallization properties of poly(lactic acid)/poly(butylene adipate- co -terephthalate) blends. J Appl Polym Sci 116:680–687

    CAS  Google Scholar 

  7. Wang B, Jin Y, Kang K, Yang N, Weng Y, Huang Z, Men S (2020) Investigation on compatibility of PLA/PBAT blends modified by epoxy-terminated branched polymers through chemical micro-crosslinking. e-Polymers 20:39–54

  8. Andrzejewski J, Nowakowski M (2021) Development of toughened flax fiber reinforced composites. Modification of poly(lactic acid)/poly(butylene adipate-co-terephthalate) Blends by Reactive Extrusion Process. Materials 14:1523

  9. Wang X, Shi M, Yu X, Peng S, Zhao X (2019) High performance and fully biodegradable poly (lactic acid) (PLA) composites modified by poly (butylene adipate-co-terephtha late) (PBAT):a review. Mater Rev 33:1897–1909

    Google Scholar 

  10. Coltelli M, Toncelli C, Ciardelli F, Bronco S (2011) Compatible blends of biorelated polyesters through catalytic transesterification in the melt. Polym Degrad Stab 96:982–990

    Article  CAS  Google Scholar 

  11. Lin S, Guo W, Chen C, Ma J, Wang B (2012) Mechanical properties and morphology of biodegradable poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends compatibilized by transesterification. Mater Des 36:604–608

    Article  CAS  Google Scholar 

  12. Lyu Y, Chen Y, Lin Z, Zhang J, Shi X (2020) Manipulating phase structure of biodegradable PLA/PBAT system: Effects on dynamic rheological responses and 3D printing. Compos Sci Technol 200:108399

    Article  Google Scholar 

  13. Andrzejewski J, Cheng J, Anstey A, Mohanty AK, Misra M (2020) Development of toughened blends of poly(lactic acid) and poly(butylene adipate-co-terephthalate) for 3D printing applications: compatibilization methods and material performance evaluation. ACS Sustain Chem Eng 8:6576–6589

    Article  CAS  Google Scholar 

  14. Zhang N, Zeng C, Wang L, Ren J (2013) Preparation and properties of biodegradable poly(lactic acid)/Poly(butylene adipate- co -terephthalate) blend with epoxy-functional styrene acrylic copolymer as reactive agent. J Polym Environ 21:286–292

    Article  CAS  Google Scholar 

  15. Wang X, Peng S, Chen H, Yu X, Zhao X (2019) Mechanical properties, rheological behaviors, and phase morphologies of high-toughness PLA/PBAT blends by in-situ reactive compatibilization. Compos B Eng 173:107028

    Article  CAS  Google Scholar 

  16. Li X, Yan X, Yang J, Pan H, Gao G, Zhang H, Dong L (2018) Improvement of compatibility and mechanical properties of the poly(lactic acid)/poly(butylene adipate- co -terephthalate) blends and films by reactive extrusion with chain extender. Polym Eng Sci 58(10):1868–1878

    Article  CAS  Google Scholar 

  17. Racha A, Khalid L, Abderrahim M (2012) Improvement of thermal stability, rheological and mechanical properties of PLA, PBAT and their blends by reactive extrusion with functionalized epoxy. Polym Degrad Stab 97:1898–1914

    Article  Google Scholar 

  18. Ai X, Li X, Yu Y, Pan H, Yang J, Wang D, Yang H, Zhang H, Dong L (2019) The mechanical, thermal, rheological and morphological properties of PLA/PBAT blown films by using bis(tert‐butyl dioxy isopropyl) benzene as crosslinking agent. Polym Eng Sci 59

  19. Signori F, Boggioni A, Righetti MC, Rondán CE, Bronco S, Ciardelli F (2015) Evidences of transesterification, chain branching and cross-linking in a biopolyester commercial blend upon reaction with dicumyl peroxide in the melt. Macromol Mater Eng 300:153–160

    Article  CAS  Google Scholar 

  20. Zhang R, Cai C, Liu Q, Hu S (2017) Enhancing the melt strength of poly(lactic acid) via micro-crosslinking and blending with poly(butylene adipate- co -butylene terephthalate)for the preparation of foams. J Polym Environ 25:1335–1341

    Article  CAS  Google Scholar 

  21. Chu M, Li M, Wu G (2019) Preparation and properties of hydrolysis-resistant PLA modified materials. China Plast Ind 47:65

    Google Scholar 

  22. Huang S, Sun X, Zhu S (2019) Study on the toughness modification of PLA with TPSiU. Plast Sci Technol 47:49

  23. Najafi N, Heuzey MC, Carreau PJ (2013) Crystallization behavior and morphology of polylactide and PLA/clay nanocomposites in the presence of chain extenders. Polym Eng Sci 53:1053–1064

    Article  CAS  Google Scholar 

  24. Cao K, Yan Y, Xu X (2010) Effect of polycarbodiimide on the hydrothermal stability of polylactic acid. China Plast Ind 38:11

    Google Scholar 

  25. Al-Itry R, Lamnawar K, Maazouz A (2012) Improvement of thermal stability, rheological and mechanical properties of PLA, PBAT and their blends by reactive extrusion with functionalized epoxy. Polym Degrad Stab 97:1898–1914

    Article  CAS  Google Scholar 

  26. Ding Y, Lu B, Wang P, Wang G, Ji J (2018) PLA-PBAT-PLA tri-block copolymers: Effective compatibilizers for promotion of the mechanical and rheological properties of PLA/PBAT blends. Polym Degrad Stab 147:41–48

    Article  CAS  Google Scholar 

  27. Sun Z, Zhang B, Bian X, Feng L, Zhang H, Duan R, Sun J, Pang X, Chen W, Chen X (2015) Synergistic effect of PLA–PBAT–PLA tri-block copolymers with two molecular weights as compatibilizers on the mechanical and rheological properties of PLA/PBAT blends. RSC Adv 5:73842–73849

    Article  CAS  Google Scholar 

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Ming, M., Zhou, Y., Wang, L. et al. Effect of polycarbodiimide on the structure and mechanical properties of PLA/PBAT blends. J Polym Res 29, 371 (2022). https://doi.org/10.1007/s10965-022-03227-8

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  • DOI: https://doi.org/10.1007/s10965-022-03227-8

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