Skip to main content
SpringerLink
Log in

Properties of novel polyimides containing bismaleimide and cyclic phosphine oxide

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

New polyimide polymers with phosphorus in the main chain were obtained from synthesized bismaleimide (EPBMI) cured with three types of curing agents: 4,4′-bismaleimidodiphenylmethane (BDM), 4,4′-bismaleimidodiphenyl- ether (BDE), and 4,4′-bismaleimidodiphenylsulfone (BDS). In addition, the compositions of the new polymers synthesized with these three curing agents (BDM, BDE, and BDS) were used to compare the curing reactivity and thermal properties of EPBMI to conventional bismaleimide (EBMI). The reactivities were measured by differential scanning calorimetry. Thermogravimetric analysis revealed the polymers, obtained through the curing reactions between EPBMI and the three curing agents mentioned also demonstrated excellent thermal properties and a high char yield compared to the EPBMI homopolymer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Lee H, Neville K (1967) Handbook of epoxy resins. McGraw-Hill, New York

    Google Scholar 

  2. Harper CA (ed) (1992) Handbook of plastics, elastomers, and composites. McGraw-Hill, New York, pp 1–57

  3. Lubin G (ed) (1982) Handbook of composites. Van Nostrand Reinhold, New York, pp 57–88

  4. Ghosh MK, Mittal KL (eds) (1996) Polyimides: fundamentals and applications. Marcel Dekker, New York, pp 7–48

  5. Park JO, Tang SH (1992) J Polym Sci Part Polym Chem 30:723–729. doi:10.1002/pola.1992.080300504

    Article  CAS  Google Scholar 

  6. Hergenrother PM (1984) Polymer Prepr 25:97–99

    CAS  Google Scholar 

  7. Stenzenberger HD (1988) Br Polym J 20:383–396. doi:10.1295/polymj.20.383

    Article  CAS  Google Scholar 

  8. Stenzenberger HD, Herzog M, Romer W, Scheiblish R, Reeves NJ (1983) Br Polym J 15:1–12. doi:10.1295/polymj.15.1

    Article  Google Scholar 

  9. Varma IK, Gupta AK, Varma DS (1983) J Appl Polym Sci 28:191–199. doi:10.1002/app.1983.070280116

    Article  CAS  Google Scholar 

  10. Evans JR, Owell RA, Tang SS (1985) J Polym Sci, Polym Chem Ed 23:971–980

    Article  CAS  Google Scholar 

  11. Liu YL, Tsai SH, Wu CS, Jeng RJ (2004) J Polym Sci Polym Chem 42:5921–5928. doi:10.1002/pola.20448

    Article  CAS  Google Scholar 

  12. Hariharan R, Bhuvana S, Anitha Malbi M, Sarojadevi M (2004) J Appl Polym Sci 93:1846–1853. doi:10.1002/app.20650

    Article  CAS  Google Scholar 

  13. Rao BS (1988) J Polym Sci Polym Lett 26:3–10

    Article  CAS  Google Scholar 

  14. Mahesh KPO, Alagar M, Jothibasu S (2006) J Appl Polym Sci 99:3592–3602. doi:10.1002/app.22982

    Article  CAS  Google Scholar 

  15. Mikroyannidis JA, Kourties DA (1984) J Appl Polym Sci 29:197–209. doi:10.1002/app.1984.070290118

    Article  CAS  Google Scholar 

  16. Ichino T, Hasuda Y (1987) J Appl Polym Sci 34:1667–1675. doi:10.1002/app.1987.070340425

    Article  CAS  Google Scholar 

  17. Shau MD, Lin CW, Yang WH, Lin HR (2002) J Appl Polym Sci 84:950–961. doi:10.1002/app.10146

    Article  CAS  Google Scholar 

  18. Liu YL, Hsiue GH, Chiu YS, Jeng RJ, Perng LH (1996) J Appl Polym Sci 61:613–621 doi:10.1002/(SICI)1097-4628(19960725)61:4<613::AID-APP5>3.0.CO;2-O

    Article  CAS  Google Scholar 

  19. Wang CS, Lin CH (1999) Polymer (Guildf) 40:5665–5673. doi:10.1016/S0032-3861(98)00786-1

    Article  CAS  Google Scholar 

  20. Liu YL, Liu YL, Jeng RJ, Chiu YS (2001) J Polym Sci Part Polym Chem 39:1716–1725. doi:10.1002/pola.1149

    Article  CAS  Google Scholar 

  21. Krevelen DW (1975) Polymer (Guildf) 16:615–620. doi:10.1016/0032-3861(75)90157-3

    Article  Google Scholar 

  22. Shau MD, Tsai PF, Teng WY, Hsu WH (2006) Eur Polym J 42:1899–1907. doi:10.1016/j.eurpolymj.2006.02.016

    Article  CAS  Google Scholar 

  23. Melissaris AP, Mikroyannidis JA (1998) J Polym Sci Part Polym Chem 26:1165–1178. doi:10.1002/pola.1988.080260417

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Occupational Safety and Health, Chia Nan University of Pharmacy and Science, Tainan, 71701, Taiwan, Republic of China

    Pai-Feng Tsai

  2. Department of Applied Chemistry, Chia Nan University of Pharmacy and Science, Tainan, 71701, Taiwan, Republic of China

    Chyong-Fen Wu

  3. Department of Biomechatronic Engineering, National Chiayi University, Chiayi, 60004, Taiwan, Republic of China

    Yu-Che Hsiao

  4. Department of Biotechnology, Chia Nan University of Pharmacy and Science, Tainan, 71701, Taiwan, Republic of China

    Min-Da Shau

Authors
  1. Pai-Feng Tsai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chyong-Fen Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu-Che Hsiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Min-Da Shau
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Min-Da Shau.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tsai, PF., Wu, CF., Hsiao, YC. et al. Properties of novel polyimides containing bismaleimide and cyclic phosphine oxide. J Polym Res 16, 673–680 (2009). https://doi.org/10.1007/s10965-009-9272-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10965-009-9272-0

Keywords

Search

Navigation