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Copolymerization of N-(4-carboxyphenyl)maleimide with acrylonitrile and the properties of its membrane

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Abstract

N-(4-Carboxyphenyl)maleimide (N-4-CPMI, M1) was copolymerized with acrylonitrile (AN, M2) to prepare the copolymer. The monomer reactivity ratios and Alfrey-Price Q, e values were determined as r1 = 0.56, r2 = 0.84, Q 1 = 2.0, Q 2 = 0.6 and e 1 = 2.06, e 2 = 1.2. The membrane of copolymer containing 0.25% CPMI had a good tensile property (67.3 MPa). The 0.75 mole% membrane had an excellent selectivity factor (α = 45.3).

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Authors and Affiliations

  1. Department of Chemical Engineering, Tatung University, Taipei, 10451, Taiwan

    Wen-Yen Chiang & Fan-Chun Ding

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  1. Wen-Yen Chiang
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  2. Fan-Chun Ding
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Correspondence to Wen-Yen Chiang.

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Chiang, WY., Ding, FC. Copolymerization of N-(4-carboxyphenyl)maleimide with acrylonitrile and the properties of its membrane. J Polym Res 7, 251–255 (2000). https://doi.org/10.1007/s10965-006-0127-7

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  • DOI: https://doi.org/10.1007/s10965-006-0127-7

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