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Anionic Copolymerization of Acrylonitrile with Methyl Acrylate under the Action of a Novel Initiating System Based on a Bicyclic Tertiary Amine and Ethylene Oxide

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Anionic copolymerization of acrylonitrile with methyl acrylate under the action of the 1,4-diazabicyclo[2.2.2]octane–ethylene oxide initiating system was studied. Similarly to the anionic homopolymerization of acrylonitrile, the copolymerization is accompanied by the intra- and intermolecular chain transfer to the polymer. The influence of the copolymerization conditions on the intensity of the chain transfer leading to the formation of highly branched and hyperbranched copolymers was examined. The acrylonitrile–methyl acrylate copolymerization constants were determined: r1 = 1.25 ± 0.06 and r2 = 0.18 ± 0.07. Quantum-chemical calculations of the thermodynamic parameters of the copolymerization were made.

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REFERENCES

  1. Varshavskii, V.Ya., Uglerodnye volokna (Carbon Fibers), Moscow: Varshavskii, 2007.

    Google Scholar 

  2. Wang, J., Zhang, M., Fu, Z., Zhou, T., Xu, X., and Liu, B., Fibers Polym., 2015, vol. 16, no. 12, pp. 2505–2512. https://doi.org/10.1007/s12221-015-5573-6

    Article  CAS  Google Scholar 

  3. Morgan, P., Carbon Fibers and Their Composites, Boca Raton: Taylor & Francis, 2005.

    Book  Google Scholar 

  4. Wiles, K.B., Bhanu, V.A., Pasquale, A.J., Long, T.E., and McGrath, J.E., J. Polym. Sci., Part A: Polym. Chem., 2004, vol. 42, no. 12, pp. 2994–3001. https://doi.org/10.1002/pola.20149

    Article  CAS  Google Scholar 

  5. Devasia, R., Reghunadhan Nair, C.P., and Ninan, K.N., Eur. Polym. J., 2002, vol. 38, no. 10, pp. 2003–2010. https://doi.org/10.1016/S0014-3057(02)00086-1

    Article  CAS  Google Scholar 

  6. RF Patent 2565767, Publ. 2015.

  7. Estrin, Y.I., Grishchuk, A.A., Tarasov, A.E., Perepilitsyna, E.O., and Badamshina, E.R., Polym. Sci., Ser. B, 2016, vol. 58, no. 1, pp. 19–26. https://doi.org/10.1134/S1560090416010012

    Article  CAS  Google Scholar 

  8. Estrin, Y.I., Tarasov, A.E., Grishchuk, A.A., Chernyak, A.V., and Badamshina, E.R., RSC Adv. Royal Soc. Chem., 2016, vol. 6, no. 108, pp. 106064–106073. https://doi.org/10.1039/C6RA21181J

    Article  CAS  Google Scholar 

  9. Tarasov, A.E., Grishchuk, A.A., Karpov, S.V., Podval’naya, Yu.V., Chernyak, A.V., Garifullin, N.O., and Badamshina, E.R., Polym. Sci., Ser. B, 2020, vol. 62, no. 2, pp. 82–93. https://doi.org/10.1134/S1560090420010108

    Article  Google Scholar 

  10. Pitto, V., Voit, B.I., Loontjens Ton, J.A., and van Benthem Rolf, A.T.M., Macromol. Chem. Phys., 2004, vol. 205, no. 17, pp. 2346–2355. https://doi.org/10.1002/macp.200400319

    Article  CAS  Google Scholar 

  11. Huang, W., Liu, C., Yang, H., Xue, X., Jiang, B., Zhang, D., Kong, L., Zhang, Y., and Komarneni, S., Polym. Chem., 2014, vol. 5, no. 10, pp. 3326–3334. https://doi.org/10.1039/c3py01751f

    Article  CAS  Google Scholar 

  12. Podval’naya, Yu.V., Lodygina, V.P., Grishchuk, A.A., and Badamshina, E.R., in Novye polimernye kompozitsionnye materialy. Mikitaevskie chteniya: Materialy XV Mezhdunarodnoi nauchno-prakticheskoi konferentsii (New Polymer Composite Materials. Mikitaev Readings: Proc. XV Int. Scientific and Practical Conf.), Nalchik: Print Tsentr, 2019.

  13. Zhao, Y. and Truhlar, D.G., Theor. Chem. Acc., 2008, vol. 120, nos. 1–3, pp. 215–241. https://doi.org/10.1007/s00214-007-0310-x

    Article  CAS  Google Scholar 

  14. Tomasi, J., Mennucci, B., and Cammi, R., Chem. Rev., 2005, vol. 105, no. 8, pp. 2999–3094. https://doi.org/10.1021/cr9904009

    Article  CAS  PubMed  Google Scholar 

  15. Ono, H., Hisatani, K., and Kamide, K., Polym. J., 1993, vol. 25, no. 3, pp. 245–265. https://doi.org/10.1295/polymj.25.245

    Article  CAS  Google Scholar 

  16. Holtel, D., Burgath, A., and Frey, H., Acta Polym., 1997, vol. 48, pp. 30–35. https://doi.org/10.1002/actp.1997.010480105

    Article  Google Scholar 

  17. Cai, J.Y., McDonnell, J., Brackley, C., O’Brien, L., Church, J.S., Millington, C.K., and Phair-Sorensen, N., Mater. Today Commun., 2016, vol. 9, pp. 22–29. https://doi.org/10.1016/j.mtcomm.2016.09.001

    Article  CAS  Google Scholar 

  18. Polymer Handbook, Brandrup, J., Immergut, E.H., and Grulke, E.A., Eds., New York: Wiley, 1975.

    Google Scholar 

  19. Encyclopedia of Polymer Science and Technology, Mark, H.F., Ed., Hoboken: Wiley, 2003.

    Google Scholar 

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Funding

The study was financially supported by the Russian Foundation for Basic Research (project nos. 18-03-00612 and 18-29-17058). The study was performed in accordance with government assignment no. 0089-2019-0008 using the equipment of the Analytical Center for Shared Use at the Institute of Problems of Chemical Physics, Russian Academy of Sciences, and Center for Shared Use “New Petrochemical Processes, Polymer Composites, and Adhesives.”

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    A. E. Tarasov, A. A. Grishchuk, S. V. Karpov, Yu. V. Podval’naya, A. V. Chernyak & E. R. Badamshina

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    S. A. Korchagina

Authors
  1. A. E. Tarasov
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  2. A. A. Grishchuk
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  3. S. V. Karpov
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  4. Yu. V. Podval’naya
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  5. A. V. Chernyak
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  6. S. A. Korchagina
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  7. E. R. Badamshina
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Correspondence to A. E. Tarasov.

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Tarasov, A.E., Grishchuk, A.A., Karpov, S.V. et al. Anionic Copolymerization of Acrylonitrile with Methyl Acrylate under the Action of a Novel Initiating System Based on a Bicyclic Tertiary Amine and Ethylene Oxide. Russ J Appl Chem 93, 1009–1018 (2020). https://doi.org/10.1134/S1070427220070101

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  • DOI: https://doi.org/10.1134/S1070427220070101

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