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Refractive Indices and Their Related Properties for Binary Mixtures Containing 2-Diethylethanolamine with 1-Propanol and 1-Butanol

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Abstract

Experimental refractive index, \(n_{{\text{D}}}\), data for eleven binary systems of 2-diethylethanolamine (2-DEEA) + 1-propanol/1-butanol at different temperatures from T = 293.15 to 313.15 K and at atmospheric pressure, over the whole concentration range, are reported. The molar refractions (\(R_{{\text{m}}}\)), molecular radii \(\left( r \right)\), reduced molar free volumes \(\left( {{{V_{{\text{m}}} } \mathord{\left/ {\vphantom {{V_{{\text{m}}} } {R_{{\text{m}}} }}} \right. \kern-\nulldelimiterspace} {R_{{\text{m}}} }}} \right)\), internal pressure, \(\left( {P_{{\text{int}}} } \right)\) and the deviations of refractive indices \(\left( {\Delta n_{{\text{D}}} } \right)\), molar refraction \(\left( {\Delta R_{{\text{m}}} } \right)\), reduced molar free volumes \(\Delta \left( {{{V_{{\text{m}}} } \mathord{\left/ {\vphantom {{V_{{\text{m}}} } {R_{{\text{m}}} }}} \right. \kern-\nulldelimiterspace} {R_{{\text{m}}} }}} \right)\), and internal pressure \(\Delta \left( {P_{{\text{int}}} } \right)\) were also calculated from the experimental data. Nine mixing rules, viz. those of Arago and Biot, Newton, Heller, Gladstone and Dale, Eyring and John, Eykman, Lorentz and Lorentz, Weiner and Oster are used to predict the refractive indices of the binary liquid systems. Among all, the Weiner method (W) is in best agreement with the experimental results.

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Acknowledgements

The author Vikash Verma is thankful to the University Grants Commission, New Delhi, India providing financial support (Ref. No.—20/12/2015(ii) EU-V).

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Authors and Affiliations

  1. Material Science Research Laboratory, Department of Physics, University of Lucknow, Lucknow, 226 007, India

    Vrijesh Kumar Pandey, Vikash Verma, Reetesh Srivastava & Aashees Awasthi

  2. Faculty of Engineering & Technology, Dr. Shakuntala Misra National Rehabilitation University, Lucknow, 226 017, India

    Anjali Awasthi

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  1. Vrijesh Kumar Pandey
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Pandey, V.K., Verma, V., Srivastava, R. et al. Refractive Indices and Their Related Properties for Binary Mixtures Containing 2-Diethylethanolamine with 1-Propanol and 1-Butanol. J Solution Chem 49, 1459–1472 (2020). https://doi.org/10.1007/s10953-020-01032-9

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