Skip to main content
SpringerLink
Log in

Solution Equilibria of Ternary Systems Involving Nickel(II) Ion, Picolinic Acid, and the Amino Acids Histidine, Cysteine, Aspartic and Glutamic Acids

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Solution equilibria of the ternary systems Ni(II)–picolinic acid (Hpic) and the amino acids aspartic acid (H2asp), glutamic acid (H2glu), cysteine (H2cys) and histidine (Hhis), where the amino acids are denoted as H i L, have been studied pH-metrically. The formation constants of the resulting mixed ligand complexes have been determined at 25 °C using a ionic strength 1.0 mol·dm−3 NaCl. In the Ni(II)–Hpic–H2asp and Ni(II)–Hpic–H2glu systems, the complexes [Ni(pic)H2L]+, Ni(pic)HL, [Ni(pic)L]− and [Ni(pic)L(OH)]2− were detected. In the Ni(II)–Hpic–H2cys system the complexes [Ni(pic)H2L]+ and [Ni(pic)L]− are present. Additionally, in the Ni(II)–Hpic–Hhis system the species [Ni(Hpic)HL]2+, Ni(pic)L and [Ni(pic)L(OH)]− were identified. The species distribution diagrams as functions of pH are briefly discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Crans, D.C., Smee, J.J., Gaidamauskas, E., Yang, L.: The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds. Chem. Rev. 104, 849–902 (2004)

    Article  CAS  Google Scholar 

  2. Lubes, V.: Vanadium(III) complexes with picolinic acid and dipicolinic acid in aqueous solution. J. Solution Chem. 34, 899–915 (2005)

    Article  CAS  Google Scholar 

  3. Yasumatsu, N., Yoshikawa, Y., Adachi, Y., Sakurai, H.: Antidiabetic copper(II) –picolinate: impact of the first transition metal in the metallopicolinate complexes. Bioorg. Med. Chem. 15, 4917–4922 (2007)

    Article  CAS  Google Scholar 

  4. Fukui, K., Fujisawa, Y., Ohya-Nishiguchi, H., Kamada, H., Sakurai, H.: In vivo coordination structural changes of a potent insulin-mimetic agent, bis(picolinato)oxovanadium(IV), studied by electron spin-echo envelope modulation spectroscopy. J. Inorg. Biochem. 77, 215–224 (1999)

    Article  CAS  Google Scholar 

  5. Martell, A.E., Smith, M., Motekaitis, R.J.: NIST Critical Stability Constants of Metal Complexes Database. US Department of Commerce, Gaithersburg (1993)

    Google Scholar 

  6. Powell, K.J., Pettit, L.D.: IUPAC Stability Constants Database. Academic Software, Otley (1997)

    Google Scholar 

  7. Kolthoff, I.M., Stenger, V.A.: Volumetric Analysis, vol. II, p. 94. Interscience Publishers, New York (1947)

    Google Scholar 

  8. Jeffery, G.H., Bassett, J., Mendham, J., Denney, R.C.: Vogel’s Textbook of Quantitative Chemical Analysis, 5th edn, p. 327. Longman Scientific and Technical, New York (1989)

    Google Scholar 

  9. Gran, G.: Determination of the equivalence point in potentiometric titrations. Part II. Analyst 77, 661–671 (1952)

    Article  CAS  Google Scholar 

  10. Biedermann, G., Sillén, L.G.: The hydrolysis of metal ions. IV. Liquid-junction potentials and constancy of activity factors in NaClO4–HClO4 ionic medium. Ark. Kemi 5, 425–540 (1953)

    CAS  Google Scholar 

  11. Brito, F., Araujo, M.L., Lubes, V., D’Ascoli, A., Mederos, A., Gili, P., Domínguez, S., Chinea, E., Hernández-Molina, R., Armas, M.T., Baran, E.J.: Emf(H) data analysis of weak metallic complexes using reduced formation functions. J. Coord. Chem. 58, 501–512 (2005)

    Article  CAS  Google Scholar 

  12. Sillén, L.G., Warnqvist, B.: High-speed computers as a supplement to graphical methods. VI. A strategy for two-level Letagrop adjustment of common and “group” parameters. Features that avoid divergence. Ark. Kemi 31, 315–339 (1969)

    Google Scholar 

  13. Veliz, L., Martínez, J.D., Araujo, M.L., Brito, F., Lubes, G., Rodríguez, M., Lubes, V.: Estudio de la hidrólisis del ion Niquel(II) y de la formación de los complejos de Niquel(II) con los ácidos Picolínico y Dipicolínico en NaCl 1,0 mol.dm −3 a 25 °C. Avances en Quím. 6, 3–11 (2011)

  14. Lema, J.: Estudio de formación de los complejos de níquel(II) con lo aminoácidos: ácido aspártico, ácido glutámico, histidina y cisteína mediante medidas de emf(H) en NaCl 1,0 M a 25 °C. Undergraduate Thesis, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Caracas (2010)

  15. Alderighi, L., Gans, P., Ienco, A., Peters, D., Sabatini, A., Vacca, A.: Hyperquad simulation and speciation (HySS): a utility program for the investigation of equilibria involving soluble and partially soluble species. Coord. Chem. Rev. 184, 311–318 (1999)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful for financing provided by the Decanato de Investigación y Desarrollo, from the Simon Bolivar University. Lino Hernández and Edgar Del Carpio thank Simon Bolivar University for scholarships.

Author information

Authors and Affiliations

  1. Centro de Equilibrios en Solución, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela (UCV), Caracas, Venezuela

    María Magdalena Centeno, José Daniel Martínez, Mary Lorena Araujo & Felipe Brito

  2. Departamento de Química, Universidad Simón Bolívar (USB), Apartado 89000, Caracas, 1080 A, Venezuela

    Edgar Del Carpio, Lino Hernández & Vito Rocco Lubes

Authors
  1. María Magdalena Centeno
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. José Daniel Martínez
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mary Lorena Araujo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Felipe Brito
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Edgar Del Carpio
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Lino Hernández
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Vito Rocco Lubes
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Vito Rocco Lubes.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Centeno, M.M., Martínez, J.D., Araujo, M.L. et al. Solution Equilibria of Ternary Systems Involving Nickel(II) Ion, Picolinic Acid, and the Amino Acids Histidine, Cysteine, Aspartic and Glutamic Acids. J Solution Chem 43, 1011–1018 (2014). https://doi.org/10.1007/s10953-014-0185-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-014-0185-0

Keywords

Search

Navigation