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Ionic Strength Effect on the Stability of the V(V) + IDA Complex

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Abstract

In this research the interaction of dioxovanadium(V) with iminodiacetic acid has been considered at 25 °C and pH=1.00–2.50 in an ionic strength range of 0.1 to 1.0 mol⋅dm−3 of NaClO4 by UV spectrophotometric and potentiometric techniques. Only one species, VO2H2L+, was assumed on the basis of two stoichiometric models. The extended Debye-Hückel theory predicts the first order effects in simple electrolyte solutions. Interactions between the reacting species and the ionic medium are taken into account in the specific ion interaction model. Parabolic, specific ion interaction, and extended Debye-Hückel models have been compared and it has been shown that the parabolic model with two coefficients is satisfactory for this complexation reaction. The results have also been compared with the literature values.

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Authors and Affiliations

  1. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Kavosh Majlesi, Saghar Rezaienejad, Samira Mehnatfarsa & Karim Zare

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  1. Kavosh Majlesi
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  2. Saghar Rezaienejad
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  3. Samira Mehnatfarsa
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  4. Karim Zare
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Correspondence to Kavosh Majlesi.

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Majlesi, K., Rezaienejad, S., Mehnatfarsa, S. et al. Ionic Strength Effect on the Stability of the V(V) + IDA Complex. J Solution Chem 40, 545–560 (2011). https://doi.org/10.1007/s10953-011-9661-y

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  • DOI: https://doi.org/10.1007/s10953-011-9661-y

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