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Densities, Viscosities, Speeds of Sound, FT-IR and 1H-NMR Studies of Binary Mixtures of n-Butyl Acetate with Ethanol, Propan-1-ol, Butan-1-ol and Pentan-1-ol at 298.15, 303.15, 308.15 and 313.15 K

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Abstract

Densities, viscosities and speeds of sound of binary mixtures of ethanol, propan-1-ol, butan-1-ol and pentane-1-ol with n-butyl acetate have been measured over the entire range of composition at temperatures of 298.15, 303.15, 308.15 and 313.15 K and atmospheric pressure. From the experimental densities, viscosities and speeds of sound, the excess molar volumes V E, deviations in viscosity Δη, and deviations in isentropic compressibility Δκ S have been calculated. The excess molar volumes and deviations in isentropic compressibility are positive for all the binary systems studied over the whole composition, while deviations in viscosities are negative for all of the binary mixtures. The excess molar volumes, deviations in viscosity, and deviations in isentropic compressibility have been fitted to a Redlich–Kister type polynomial equation. FTIR and 1H-NMR studies of these mixtures are also reported.

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References

  1. Nikam, P.S., Shirsat, L.N., Hasan, M.: Density and viscosity studies of binary mixtures of acetonitrile with methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol, 2-methylpropan-1-ol, 2-methylpropan-2-ol at (298.15, 303.15, 308.15 and 313.15) K. J. Chem. Eng. Data 43, 732–737 (1998)

    Article  CAS  Google Scholar 

  2. Nikam, P.S., Jadhav, M.C., Hasan, M.: Volumetric, viscometric and ultrasonic behaviour of dimethylsulfoxide with normal alcohols (C1–C4) at 308.15 K. J. Mol. Liquids 76, 1–11 (1998)

    Article  CAS  Google Scholar 

  3. Nikam, P.S., Jadhav, M.C., Hasan, M.: Molecular interactions in mixtures of dimethylsulfoxide with some alkanols—an ultrasonic study. Acustica Acta Acoust. 83, 86–89 (1997)

    CAS  Google Scholar 

  4. Nikam, P.S., Mahale, T.R., Hasan, M.: Ultrasonic study of alkanols (C1–C4) in binary mixtures containing ethyl acetate as common component. Acustica Acta Acoust. 84, 579–584 (1998)

    CAS  Google Scholar 

  5. Nikam, P.S., Jagdale, B.S., Sawant, A.B., Hasan, M.: Ultrasonic study of binary liquid mixtures of benzonitrile with alkanols (C1–C3) at various temperatures. Acoust. Lett. 22, 199–203 (1999)

    CAS  Google Scholar 

  6. Kadam, U.B., Hiray, A.P., Sawant, A.B., Hasan, M.: Densities, viscosities and ultrasonic velocity studies of binary mixtures of methanol with propan-1-ol and butan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data 51, 60–63 (2006)

    Article  CAS  Google Scholar 

  7. Hasan, M., Kadam, U.B., Hiray, A.P., Sawant, A.B.: Densities, viscosities and ultrasonic velocity studies of binary mixtures of methanol with pentan-1-ol, hexan-1-ol and heptan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data 51, 671–675 (2006)

    Article  CAS  Google Scholar 

  8. Kadam, U.B., Hiray, A.P., Sawant, A.B., Hasan, M.: Densities, viscosities, and ultrasonic velocity studies of binary mixtures of trichloromethane with methanol, ethanol, propan-1-ol, and butan-1-ol at T=(298.15 and 308.15) K. J. Chem. Thermodyn. 38, 1675–1683 (2006)

    Article  CAS  Google Scholar 

  9. Hasan, M., Shirude, D.F., Hiray, A.P., Kadam, U.B., Sawant, A.B.: Densities, viscosities and ultrasonic velocities of binary mixtures of methylbenzene with hexan-2-ol, heptan-2-ol and octan-2-ol at T=(298.15 and 308.15) K. Fluid Phase Equilib. 252, 89–95 (2007)

    Article  Google Scholar 

  10. Hasan, M., Shirude, D.F., Hiray, A.P., Kadam, U.B., Sawant, A.B.: Densities, viscosities and speed of sound studies of binary mixtures of methylbenzene with heptan-1-ol, octan-1-ol and decan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data 51, 1922–1926 (2006)

    Article  CAS  Google Scholar 

  11. Hasan, M., Shirude, D.F., Hiray, A.P., Kadam, U.B., Sawant, A.B.: Densities, viscosities and ultrasonic velocity studies of binary mixtures of toluene with heptan-1-ol, octan-1-ol and decan-1-ol at 298.15 and 308.15 K. J. Mol. Liquids 135, 32–37 (2007)

    Article  CAS  Google Scholar 

  12. Nikam, P.S., Hasan, M., Shewale, R.P., Sawant, A.B.: Limiting ionic partial molar volumes of Cs+, Na+, (C4H9)4N+, Cl−, Br−, I−, \(\mathrm{BPh}_{4}^{ -}\) in aqueous acetone at 298.15 K. J. Solution Chem. 32, 987–995 (2003)

    Article  CAS  Google Scholar 

  13. Marsh, K.N.: Recommended Reference Materials for the Realisation of Physicochemical Properties. Blackwell Sci., Oxford (1987)

    Google Scholar 

  14. Redlich, O., Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

  15. Iloukhani, H.Z., Nojini, B.: Volumetric and acoustic properties of butyl acetate with some alkan-1-ols (C1–C6) at 298.15 K. Phys. Chem. Liq. 43, 429–440 (2005)

    Article  CAS  Google Scholar 

  16. Kiyohara, O., Benson, G.C.: Ultrasonic speeds and isentropic compressibilities of n-alkanol + n-heptane mixtures at 298.15 K. J. Chem. Thermodyn. 11, 861–873 (1979)

    Article  CAS  Google Scholar 

  17. Rai, R.D., Shukla, R.K., Shukla, A.K., Pandey, J.D.: Ultrasonic speeds and isentropic compressibilities of ternary liquid mixtures at (298.15±0.01) K. J. Chem. Thermodyn. 21, 125–129 (1989)

    Article  CAS  Google Scholar 

  18. Riddick, J.A., Bunger, W.B., Sakano, T.K.: Organic Solvents, Physical Properties and Methods of Purification, Techniques of Chemistry, vol. II, 4th edn. Wiley–Interscience, New York (1986)

    Google Scholar 

  19. Aminabhavi, T.M., Phayde, H.T.S., Khinnavar, R.K., Bindu, G.: Densities, refractive indices, speeds of sound, and viscosities of diethylene glycol dimethyl ether + butyl acetate at 298.15, 303.15, 308.15, 313.15, and 318.15 K. J. Chem. Eng. Data 38, 542–545 (1993)

    Article  CAS  Google Scholar 

  20. Aminabhavi, T.M., Patil, V.B.: Density, viscosity, and speed of sound in binary mixtures of 1-chloronaphthalene with methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, and hexan-1-ol in the temperature range (298.15–308.15) K. J. Chem. Eng. Data 43, 504–508 (1998)

    Article  CAS  Google Scholar 

  21. Aminabhavi, T.M., Aralaguppi, M.I., Harogoppad, S.B., Balundgi, R.H.: Densities, viscosities, refractive indices, and speeds of sound for methyl acetoacetate + aliphatic alcohols (C1–C8). J. Chem. Eng. Data 38, 31–39 (1993)

    Article  CAS  Google Scholar 

  22. Aminabhavi, T.M., Banerjee, K.: Density, viscosity, refractive index, and speed of sound in binary mixtures of 2-chloroethanol with alkanols (C1–C6) at 298.15, 303.15, and 308.15 K. J. Chem. Eng. Data 43, 509–513 (1998)

    Article  CAS  Google Scholar 

  23. Sastry, N.V., Valand, M.K.: Viscosities and densities for heptane + 1-pentanol, + 1-hexanol, + 1-heptanol, + 1-octanol, + 1-decanol, and + 1-dodecanol at 298.15 K and 308.15 K. J. Chem. Eng. Data 41, 1426–1428 (1996)

    Article  CAS  Google Scholar 

  24. Sastry, N.V., Valand, M.K.: Densities, viscosities, and relative permittivities for pentane + 1-alcohols (C1 to C12) at 298.15 K. J. Chem. Eng. Data 43, 152–157 (1998)

    Article  CAS  Google Scholar 

  25. Tu, C.H., Lee, S.L., Peng, I.H.: Excess volumes and viscosities of binary mixtures of aliphatic alcohols (C1–C4) with nitromethane. J. Chem. Eng. Data 46, 151–155 (2001)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, Pin, 423 105, India

    Mehdi Hasan, Apoorva P. Hiray, Ujjan B. Kadam & Arun B. Sawant

  2. Arts, Science and Commerce College, Nampur, India

    Dinesh F. Shirude & Keshav J. Kurhe

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  1. Mehdi Hasan
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  2. Apoorva P. Hiray
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  3. Ujjan B. Kadam
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  4. Dinesh F. Shirude
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  6. Arun B. Sawant
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Correspondence to Mehdi Hasan.

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Hasan, M., Hiray, A.P., Kadam, U.B. et al. Densities, Viscosities, Speeds of Sound, FT-IR and 1H-NMR Studies of Binary Mixtures of n-Butyl Acetate with Ethanol, Propan-1-ol, Butan-1-ol and Pentan-1-ol at 298.15, 303.15, 308.15 and 313.15 K. J Solution Chem 40, 415–429 (2011). https://doi.org/10.1007/s10953-011-9657-7

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  • DOI: https://doi.org/10.1007/s10953-011-9657-7

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