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Volumetric, Viscometric and Speed of Sound Studies of Binary Mixtures of Tert-butyl Acetate with Fluorobenzene, Chlorobenzene and Bromobenzene at (298.15 and 308.15) K and at Atmospheric Pressure 0.087 MPa

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Abstract

Volumetric, viscometric and speed of sound studies of binary mixtures of tert-butyl acetate with fluorobenzene, chlorobenzene and bromobenzene have been made over the entire range of composition, at (298.15 and 308.15) K and at atmospheric pressure (p = 0.089 MPa). From the experimental values of density, viscosity, and speed of sound, the excess molar volumes VE, deviations in viscosity ∆η and deviation in isentropic compressibility ΔK S have been calculated. The VE and ΔK S values are negative while the ∆η the values are positive over the entire composition range for the binary mixtures. The derived parameters have been fitted with the Redlich–Kister polynomial equation. The interaction parameters of McAllister model are used to correlate the experimental values of density, viscosity and speed of sound.

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Acknowledgements

The author is thankful to the Principal, M.S.G. College, Malegaon Campus for providing laboratory facilities and University Grants Commission, New Delhi for financial assistance.

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  1. Department of Chemistry, S. P. H. Mahila College, Malegaon Campus, Malegaon, Nashik, MS, 423105, India

    Rajashri B. Sawant

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Correspondence to Rajashri B. Sawant.

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Sawant, R.B. Volumetric, Viscometric and Speed of Sound Studies of Binary Mixtures of Tert-butyl Acetate with Fluorobenzene, Chlorobenzene and Bromobenzene at (298.15 and 308.15) K and at Atmospheric Pressure 0.087 MPa. J Solution Chem 47, 787–795 (2018). https://doi.org/10.1007/s10953-018-0752-x

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