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Volumetric, Ultrasonic and Viscosimetric Studies for the Binary Mixture (1, 4-Dioxane + Water) at T = (295.15, 298.15, 301.15, 304.15, 307.15, 310.15 and 313.15) K

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Abstract

Density, speed of sound and viscosity data for the binary mixtures (1,4-dioxane (1) + water (2)), were measured over the whole composition range at temperatures T = (295.15, 298.15, 301.15, 304.15, 307.15, 310.15 and 313.15) K and at the atmospheric pressure. From experimental data, the excess molar volume, isobaric thermal expansion coefficient, excess of isobaric thermal expansion coefficient, excess speed of sound, isentropic compressibility, excess of isentropic compressibility, intermolecular free-length, the excess intermolecular free-length, the viscosity deviation, the excess free Gibbs energies of activation of viscous flow, the internal pressure, excess internal pressure, acoustic impedance, the excess acoustic, and the free volume were calculated. The excess parameters were fitted by the Redlich–Kister polynomial equation to derive the coefficients and estimate the standard error values. The nature of molecular interactions between the two components of the mixture, have been discussed by means of the thermodynamic properties.

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  1. Laboratoire de Physique des Liquides Critiques, Département de Physique, Faculté́ des Sciences de Bizerte, Université́ de Carthage, Zarzouna, 7021, Bizerte, Tunisia

    Imen Mejri, Taoufik Kouissi, Adel Toumi & Moncef Bounaz

  2. Laboratoire des Matériaux Nanostructurés, d’Optique Quantique et Non Linéaire, Département de Physique, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire Farhat Hached, 2092, Tunis El Manar, Tunisia

    Imen Mejri, Taoufik Kouissi, Adel Toumi & Moncef Bounaz

  3. Laboratoire Biophysique et de Technologies Médicales LR13ES07, Institut Supérieur des Technologies Médicales de Tunis, Université de Tunis El Manar, 9 Avenue Dr. Zouhaier Essafi, 1006, Tunis, Tunisia

    Noureddine Ouerfelli

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Mejri, I., Kouissi, T., Toumi, A. et al. Volumetric, Ultrasonic and Viscosimetric Studies for the Binary Mixture (1, 4-Dioxane + Water) at T = (295.15, 298.15, 301.15, 304.15, 307.15, 310.15 and 313.15) K. J Solution Chem 50, 1131–1168 (2021). https://doi.org/10.1007/s10953-021-01109-z

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