Abstract
Mixed-metal complex constructed from diruthenium(II,III) acetate and tetracyanidoplatinate(II), [{Ru2(O2 CCH3)4}2Pt(CN)4] n (1), was synthesized and characterized. The crystal structure of 1 was determined by the synchrotron-radiation single-crystal X-ray diffraction method at 100 K. It crystallizes in the triclinic space group \(P\bar {{1}}\) with a = 8.522(7) Å, b = 12.160(10) Å, c = 12.221(10) Å, α = 115.643(12), β = 101.14(2), γ = 104.46(2)°, V = 1037.5(14) Å3, D x = 1.882 g cm−3, and Z = 1. The R1 [ I>2σ(I)] and wR2 (all data) values are 0.1759 and 0.4753, respectively, for all 7499 independent reflections. The crystal structure revealed an alternating arrangement of Ru2(O\(_{2}\textit {CCH}_{3})_{4}^{+}\) and Pt(CN)\(_{4}^{2-}\) ions in two-dimensional sheet with a porous network. Temperature dependence of magnetic susceptibility measurement (4.5–300 K) showed that a weak antiferromagnetic interaction through the tetracyanidoplatinate(II) between the Ru2(O\(_{2}\textit {CCH}_{3})_{4}^{+}\) units with g = 2.10, zJ (the exchange integral multiplied by the number of interacting neighbors) = −0.10 cm−1 and D (zero-field splitting parameter) = 45 cm−1. The adsorption isotherm measurement showed an adsorption property of coexistence of types I and IV with a S BET value of 273.49 m2 g−1.
Similar content being viewed by others
References
Cotton, F.A., Murillo, C.A., Walton, R.A.: Multiple Bonds between Metal Atoms, 3rd edn. Springer Science and Business Media, New York (2005)
Mikuriya, M., Yoshioka, D., Handa, M.: Coord. Chem. Rev. 250, 2194 (2006)
Aquino, M.A.S.: Coord. Chem. Rev. 248, 1025 (2004)
Aquino, M.A.S.: Coord. Chem. Rev. 170, 141 (1998)
Sayama, Y., Handa, M., Mikuriya, M., Hiromitsu, I., Kasuga, K.: Bull. Chem. Soc. Jpn. 73, 2499 (2000)
Ishida, H., Handa, M., Hiromitsu, I., Mikuriya, M.: Chem. Papers 67, 743 (2013)
Yoshioka, D., Mikuriya, M., Handa, M.: Chem. Lett. 31, 1044 (2002)
Vos, T.E., Liao, Y., Shum, W.W., Her, J.-H., Stephens, P.W., Reiff, W.M., Miller, J.S.: J. Am. Chem. Soc. 126, 11630 (2004)
Vos, T.E., Miller, J.S.: Angew. Chem. Int. Ed. 44, 2416 (2005)
Matoga, D., Mikuriya, M., Handa, M., Szklarzewicz, J.: Chem. Lett. 34, 1550 (2005)
Mikuriya, M., Yoshioka, D., Borta, A., Luneau, D., Matoga, D., Szklarzewicz, J., Handa, M.: New J. Chem. 35, 1226 (2011)
Mikuriya, M., Tanaka, Y., Yoshioka, D., Handa, M.: J. Supercond. Nov. Magn. 28, 1013 (2015)
Mikuriya, M., Ono, K., Kawauchi, S., Yoshioka, D., Mitsuhashi, R, Handa, M.: Chem. J. Moldova 10(2), 48 (2015)
Barral, M.C., Gonzalez-Prieto, B., Jimenez-Aparicio, R., Priego, J.L., Torres, M.R., Urbanos, F.A.: Eur. J. Inorg. Chem., 4229 (2006)
Acknowledgments
The present work was partially supported by Grant-in-Aid for Scientific Research No. 26410080 from the Ministry of Education, Culture, Sports, Science and Technology (MEXT, Japan) and the MEXT-Supported Program for the Strategic Research Foundation at Private Universities, 2010–2014. The synchrotron radiation experiments were performed at SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (Proposal No. 2015B1001).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mikuriya, M., Kawauchi, S., Ono, K. et al. Two-Dimensional Chain Complex Based on Diruthenium (II, III) Acetate and Tetracyanidoplatinate(II). J Supercond Nov Magn 30, 2007–2010 (2017). https://doi.org/10.1007/s10948-016-3643-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-016-3643-7