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Molecule-Based Magnetic Compounds Made Up from Dinuclear Ruthenium(II,III) Carboxylate and Dicyanidoargentate(I)

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Abstract

Mixed-metal complexes constructed from mixed-valent dinuclear ruthenium(II,III) carboxylate and dicyanidoargentate(I), K[Ru2(O2CCH3)4Ag(CN)2]⋅4H2O (1) and K2.5[Ru2{O2CC(CH3)3}4(Ag(CN)2)3.5]⋅3H2O (2), were synthesized and characterized by elemental analysis and IR and UV-visible-NIR spectroscopies. These data supported the formulation of mixed-metal adduct of Ru2(O2CCH3)4 + with two Ag(CN)2 − for 1 and mixed-metal dimer of Ru2{O2CC(CH3)3}4 + with aggregated {Ag(CN)2 −}2or3 through argentophilic Ag ⋅⋅⋅ Ag interaction for 2, respectively. A broadband (δ(Ru2) → δ ∗(Ru2)) at near-IR and two bands(δ ∗/π ∗ (Ru2) → σ ∗□u−O and π(Ru-O, Ru2) → π ∗(Ru2)) at visible region were observed in the diffused reflectance spectra (920sh, 634, and 444 nm for 1 and 930sh, 638, and 478 nm for 2, respectively). Temperature dependence of magnetic susceptibility measurement (4.5–300 K) showed that the former is paramagnetic (S = 3/2) with D (zero-field splitting parameter) = 78 cm−1 and the latter weakly antiferromagnetic with g = 2.07, zJ (the exchange integral multiplied by the number of interacting neighbors) =−0.5 cm−1, and D = 90 cm−1.

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References

  1. Cotton, F.A., Murillo, C.A., Walton, R.A., 3rd ed.: Multiple bonds between metal atoms. Springer, New York (2005)

    Book  Google Scholar 

  2. Mikuriya, M.: Bull. Jpn. Soc. Coord. Chem. 52, 17 (2008)

    Article  Google Scholar 

  3. Mikuriya, M., Yoshioka, D., Handa, M.: Coord. Chem. Rev. 250, 2194 (2006)

    Article  Google Scholar 

  4. Aquino, M.A.S.: Coord. Chem. Rev. 248, 1025 (2004)

    Article  Google Scholar 

  5. Aquino, M.A.S.: Coord. Chem. Rev. 170, 141 (1998)

    Article  Google Scholar 

  6. Sayama, Y., Handa, M., Mikuriya, M., Hiromitsu, I., Kasuga, K.: Bull. Chem. Soc. Jpn. 73, 2499 (2000)

    Article  Google Scholar 

  7. Ishida, H., Handa, M., Hiromitsu, I., Mikuriya, M.: Chem. Papers 67, 743 (2013)

    Article  Google Scholar 

  8. Yoshioka, D., Mikuriya, M., Handa, M.: Chem. Lett. 31, 1044 (2002)

    Article  Google Scholar 

  9. Vos, T.E., Liao, Y., Shum, W.W., Her, J.-H., Stephens, P.W., Reiff, W.M., Miller, J.S.: J. Am. Chem. Soc. 126, 11630 (2004)

    Article  Google Scholar 

  10. Vos, T.E., Miller, J.S.: Angew. Chem. Int. Ed. 44, 2416 (2005)

    Article  Google Scholar 

  11. Matoga, D., Mikuriya, M., Handa, M., Szklarzewicz, J.: Chem. Lett. 34, 1550 (2005)

    Article  Google Scholar 

  12. Mikuriya, M., Yoshioka, D., Borta, A., Luneau, D., Matoga, D., Szklarzewicz, J., Handa, M.: New J. Chem. 35, 1226 (2011)

    Article  Google Scholar 

  13. Pham, D.M., Rios, D., Olmstead, M.M., Balch, A.L.: Inorg. Chim. Acta 358, 4261 (2005)

    Article  Google Scholar 

  14. Cernak, J., Abboud, K.A., Chomic, J., Meisel, M.W., Orendac, M., Orendacova, A., Feher, A.: Inorg. Chim. Acta 311, 126 (2000)

    Article  Google Scholar 

  15. Dong, W., Wang, Q.-L., Si, S.-F., Liao, D.-Z., Jiang, Z.-H., Yan, S.-P., Cheng, P.: Inorg. Chem. Commun. 6, 873 (2003)

    Article  Google Scholar 

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Acknowledgments

The present work was partially supported by Grant-in-Aid for Scientific Research No. 26410080 from the Ministry of Education, Culture, Sports, Science and Technology (MEXT, Japan) and the MEXT-Supported Program for the Strategic Research Foundation at Private Universities, 2010–2014.

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Authors and Affiliations

  1. Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, 669-1337, Japan

    Masahiro Mikuriya, Yusuke Tanaka & Daisuke Yoshioka

  2. Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan

    Makoto Handa

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  1. Masahiro Mikuriya
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  2. Yusuke Tanaka
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  3. Daisuke Yoshioka
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  4. Makoto Handa
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Correspondence to Masahiro Mikuriya.

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Mikuriya, M., Tanaka, Y., Yoshioka, D. et al. Molecule-Based Magnetic Compounds Made Up from Dinuclear Ruthenium(II,III) Carboxylate and Dicyanidoargentate(I). J Supercond Nov Magn 28, 1013–1016 (2015). https://doi.org/10.1007/s10948-014-2646-5

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  • DOI: https://doi.org/10.1007/s10948-014-2646-5

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