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Pseudohexagonal motif of the arrangement of compex anions in the structure of [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O

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Abstract

The [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O salt was obtained; its crystal structure was analyzed: a = 10.7713(9) Å, b = 13.9602(11) Å, c = 14.7956(11) Å, α = 91.961(3)°, β = 109.985(3)°, γ = 110.030(3)°, V = 1935.3(3) Å3, space group P1¯, Z = 2, d calc = 3.441 g/cm3. In the cluster anion, the Re-Re distances lie in the range from 2.594 Å to 2.612 Å. For two crystallographically independent complex cations, Ru-Nav is 2.105 Å, and Ru-Clav 2.329 Å. A pseudohexagonal motif of the structure was found.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    K. V. Yusenko, I. A. Baidina & S. A. Gromilov

  2. Novosibirsk State University, Russia

    E. A. Shusharina

Authors
  1. K. V. Yusenko
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  2. I. A. Baidina
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  3. E. A. Shusharina
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  4. S. A. Gromilov
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Correspondence to S. A. Gromilov.

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Original Russian Text Copyright © 2008 by K. V. Yusenko, I. A. Baidina, E. A. Shusharina, and S. A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 1, pp. 178–181, January–February, 2008.

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Yusenko, K.V., Baidina, I.A., Shusharina, E.A. et al. Pseudohexagonal motif of the arrangement of compex anions in the structure of [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O. J Struct Chem 49, 170–174 (2008). https://doi.org/10.1007/s10947-008-0024-5

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  • DOI: https://doi.org/10.1007/s10947-008-0024-5

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