Abstract
A rhenium cluster complex (2,2′-bipyH2)2[Re4Se4(CN)12] · (2,2′-bipy)·7H2O (1) is obtained and characterized. The compound crystallizes in a monoclinic space group C2/c with the unit cell parameters: a = 16.9191(6) Å, b = 18.7458(6) Å, c = 19.0139(5) Å, β = 108.568(1)°, V = 5716.6(3) Å3, Z = 4, d x = 2.291 g/cm3. The crystal structure is a packing of bipyridylium cations (2,2′-bipyH2)2+, cluster anions [Re4Se4(CN)12]4−, bipyridyl molecules, and crystal water molecules, which are linked together by a system of hydrogen bonds.
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M. Laing, P. M. Kiernan, and W. P. Griffith, J. Chem. Soc. Chem. Commun., No. 7, 221/222 (1977).
Y. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers, Inorg. Chem., 36, No. 5, 944–946 (1997).
E. Schulz Lang, U. Abram, and J. Strahle, Z. Anorg. Allg. Chem., 622, No. 2, 251–253 (1996).
Y. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers, Z. Kristallogr. New Cryst. Struct., 212, 308–310 (1997).
Yu. V. Mironov, A. V. Virovets, S. B. Artemkina, and V. E. Fedorov, J. Struc. Chem., 40, No. 2, 313–316 (1999).
Y. V. Mironov, A. V. Virovets, W. S. Sheldrick, and V. E. Fedorov, Polyhedron, 20, Nos. 9/10, 969–974 (2001).
O. A. Efremova, Y. V. Mironov, N. V. Kuratieva, and V. E. Fedorov, Acta Crystallogr., E60, No. 12, m1817–m1818 (2004).
APEX2 (Version 1.08), SAINT (Version 7.03), SADABS (Version 2.11), SHELXTL (Version 6.12). Bruker AXS Inc., Madison, Wisconsin, USA (2004).
B. N. Figgis, B. W. Skelton, and A. H. White, Aust. J. Chem., 31, No. 1, 57–64 (1978).
L. Cunha-Silva, F.-N. Shi, F. A. A. Paz, M. J. Hardie, J. Klinowski, T. Trindade, and J. Rocha, Inorg. Chim. Acta, 362, No. 1, 263–270 (2009).
T. Shibahara, K. Kohda, A. Ohtsuji, K. Yasuda, and H. Kuroya, J. Am. Chem. Soc., 108, No. 10, 2757/2758 (1986).
M. Stojanovic, N. J. Robinson, T. Ngo, and R. E. Sykora, J. Chem. Cryst., 41, No. 10, 1425–1432 (2011).
B. F. Ali and R. Al-Far, J. Chem. Cryst., 38, No. 9, 689–693 (2008).
B. F. Ali, R. Al-Far, and S. F. Haddad, Acta Crystallogr., E68, No. 10, o3033 (2012).
A. Linden, M. A. James, M. B. Millikan, L. M. Kivlighon, A. Petridis, and B. D. James, Inorg. Chim. Acta, 284, No. 2, 215–222 (1999).
S. I. Gorelsky, A. B. Ilyukhin, P. V. Kholin, V. Yu Kotov, B. V. Lokshin, and N. V. Sapoletova, Inorg. Chim. Acta, 360, No. 8, 2573–2582 (2007).
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Original Russian Text © 2014 Ya. M. Gaifulin, A. I. Smolentsev, Yu. V. Mironov.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 5, pp. 966–968, September–October, 2014.
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Gaifulin, Y.M., Smolentsev, A.I. & Mironov, Y.V. Crystal structure of the ionic cluster complex (2,2′-bipyH2)2[Re4Se4(CN)12]·(2,2′-bipy)·7H2O. J Struct Chem 55, 920–922 (2014). https://doi.org/10.1134/S0022476614050187
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DOI: https://doi.org/10.1134/S0022476614050187