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Crystal Structure of the Octahedral Rhenium Cluster Complex (Bu4N)4[Re6S8(OC6H4-p-NO2)6]

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Abstract

A cluster complex with the composition (Bu4N)4[Re6S8(CC6H4-p-NC2)6] having terminal phenoxide ligands is obtained by the reaction of (Bu4N)4[Re6S8Cl6] with silver p-nitrophenolate. The compound crystallizes in the orthorhombic space group Pccn with the following unit cell parameters: a = 19.507(2) Å, b = 31.645(3) Å, c = 19.237(2) Å, V = 19.237(2) Å3, Z = 4, dcalc = 1.774 g/cm3.

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Authors and Affiliations

  1. Graduate School of Science and Engineering, Saitama University, Saitama, Japan

    S. Nagashima, S. Kawada & H. Kobayashi

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  1. S. Nagashima
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  2. S. Kawada
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  3. H. Kobayashi
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Correspondence to S. Nagashima.

Additional information

Zhurnal Strukturnoi Khimii, Vol. 60, No. 2, pp. 311–313, February, 2019.

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Nagashima, S., Kawada, S. & Kobayashi, H. Crystal Structure of the Octahedral Rhenium Cluster Complex (Bu4N)4[Re6S8(OC6H4-p-NO2)6]. J Struct Chem 60, 299–301 (2019). https://doi.org/10.1134/S0022476619020173

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  • DOI: https://doi.org/10.1134/S0022476619020173

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