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Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]·6H2O and Cs4[Re6Se8(OH)6]·8H2O

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Abstract

The salts Cs4[Re6S8(OH)6]·6H2O (1) and Cs4[Re6Se8(OH)6]·8H2O (2) were obtained by the reactions of Re6S8Br2 and Re6Se8Br2 with a CsOH melt with further solution of the products in water and crystallization of 1 and 2 from the aqueous solutions. The structure of the compounds was established by X-ray single crystal diffraction analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 14.175(2) Å, b = 11.321(2) Å, c = 17.503(2) Å, V = 2808.5(7) Å3, Z = 4, d calc = 5.003 g/cm3; compound 2 crystallizes in the triclinic space group \(P\bar 1\) with unit cell parameters a = 9.020(4) Å, b = 9.127(4) Å, c = 10.289(4) Å, α = 79.589(7)°, β = 75.829(7)°, γ = 72.186(7)°, V = 776.8(6) Å3, Z = 1, d calc = 5.402 g/cm3.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    K. A. Brylev, Yu. V. Mironov & V. E. Fedorov

  2. EWHA Women’s University, Seoul, Korean Republic

    K. A. Brylev & S.-J. Kim

Authors
  1. K. A. Brylev
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  2. Yu. V. Mironov
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  3. S.-J. Kim
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  4. V. E. Fedorov
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Correspondence to K. A. Brylev.

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Original Russian Text Copyright © 2007 by K. A. Brylev, Yu. V. Mironov, S.-J. Kim, and V. E. Fedorov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 6, pp. 1183–1188, November–December, 2007.

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Brylev, K.A., Mironov, Y.V., Kim, SJ. et al. Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]·6H2O and Cs4[Re6Se8(OH)6]·8H2O. J Struct Chem 48, 1118–1123 (2007). https://doi.org/10.1007/s10947-007-0179-5

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  • DOI: https://doi.org/10.1007/s10947-007-0179-5

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