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Synthesis and crystal structure of copper(II) bis-chelate comprising a nitrile derivative of 3-imidazoline nitroxide

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Abstract

Syntheses of a nitroxide radical 2-(1-oxyl-2,2,5,5-tetramethyl-imidazolin-4-yliden)-3-oxo-5-phenylpentannitrile \((HL^{CH_2 CH_2 Ph} )\) and its copper(II) complex are reported. The coordination compound is characterized by the single crystal X-ray diffraction analysis (a = 11.647(2) Å, b = 13.269(3) Å, c = 13.844(3) Å, α = 61.83(2)°, β = 88.13(2)°, γ = 74.12(2)°, space group \(P\bar 1\)). The \(Cu(L^{CH_2 CH_2 Ph} )_2 (H_2 O)\) complex has a molecular structure.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    A. B. Burdukov & N. V. Pervukhina

  2. N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    G. I. Roschupkina & V. A. Reznikov

Authors
  1. A. B. Burdukov
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  2. N. V. Pervukhina
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  3. G. I. Roschupkina
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  4. V. A. Reznikov
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Original Russian Text Copyright © 2007 by A. B. Burdukov, N. V. Pervukhina, G. I. Roschupkina, and V. A. Reznikov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No.1, pp.122–127, January–February, 2007.

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Burdukov, A.B., Pervukhina, N.V., Roschupkina, G.I. et al. Synthesis and crystal structure of copper(II) bis-chelate comprising a nitrile derivative of 3-imidazoline nitroxide. J Struct Chem 48, 122–127 (2007). https://doi.org/10.1007/s10947-007-0018-8

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  • DOI: https://doi.org/10.1007/s10947-007-0018-8

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