Skip to main content
SpringerLink
Log in

Structural thermodynamic parameters and intermolecular interactions in aqueous solutions of secondary amides

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Structural thermodynamic parameters are calculated for aqueous solutions of secondary amides of carboxylic acids. Specific and nonspecific contributions to the total energy of intermolecular interactions are determined and the boundaries of concentration regions for a various structural organization of solutions are found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. A. Karapetyan and V. N. Éichis, Physical and Chemical Properties of Non Electrolyte Aqueous Solutions [in Russian], Khimiya, Moscow (1989).

    Google Scholar 

  2. V. P. Belousov and M. Y. Panov, Thermodynamic Properties of Aqueous Solutions of Organic Substances, Boca Raton, CRC Press, Tokyo (1994).

    Google Scholar 

  3. Yu. M. Kessler and A. L. Zaitsev, Solvophobic Effects: Theory, Experiments and Practice [in Russian], Khimiya, Leningrad (1989).

    Google Scholar 

  4. A. M. Zaichikov and O. E. Golubinskii, Zh. Fiz. Khim., 70, No. 7, 1175–1179 (1996).

    CAS  Google Scholar 

  5. A. M. Zaichikov, Zh. Obsh. Khim., 67, No. 9, 1443–1448 (1997).

    Google Scholar 

  6. M. N. Rodnikova, Zh. Fiz. Khim., 67, No. 3, 275–280 (1993).

    CAS  Google Scholar 

  7. V. N. Kartsev, M. N. Rodnikova, S. N. Shtykov, and J. Bartel, ibid., 77, No. 8, 1456–1462 (2003).

    CAS  Google Scholar 

  8. E. V. Ivanov and V. K. Abrosimov, Zh. Strukt. Khim., 46, No. 5, 889–895 (2005).

    Google Scholar 

  9. C. De Visser, P. Pel, and G. Somsen, J. Solut. Chem., 6, No. 9, 571–580 (1977).

    Article  Google Scholar 

  10. P. I. Victor and D. K. Hazra, J. Chem. Eng. Data, 47, No. 1, 79–82 (2002).

    Article  CAS  Google Scholar 

  11. P. Assarsson and F. R. Eirich, J. Phys. Chem., 72, No. 8, 2710–2719 (1968).

    Article  CAS  Google Scholar 

  12. F. Kawaizumi, M. Ohno, and Y. Miyahara, Bull. Chem. Soc. Jpn., 50, No. 9, 2229–2233 (1977).

    Article  CAS  Google Scholar 

  13. A. M. Kolker, M. V. Kulikov, and G. A. Krestov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 28, No. 6, 11–14 (1985).

    CAS  Google Scholar 

  14. A. B. De Haan and J. Gmehling, J. Chem. Eng. Data., 41, No. 3, 474–478 (1996).

    Article  Google Scholar 

  15. Y. Marcus, Ion Solvation, Wiley, New York (1985).

    Google Scholar 

  16. A. J. Easteal and L. A. Woolf, J. Chem. Soc., Faraday Trans. I, 81, No. 11, 2821–2833 (1985).

    Article  CAS  Google Scholar 

  17. J. Zielkiewicz, J. Chem. Soc., Faraday Trans., 94, No. 12, 1713–1719 (1998).

    Article  CAS  Google Scholar 

  18. V. A. Mikhailov and A. N. Kirgintsev, Zh. Fiz. Khim., 36, No. 9, 2085–2089 (1962).

    CAS  Google Scholar 

  19. B. Garcia, R. Alcade, J. M. Leal, and J. S. Matos, J. Phys. Chem. B, 101, No. 40, 7991–7997 (1997).

    Article  CAS  Google Scholar 

  20. O. D. Bonner and Y. S. Choi, Spectrochim. Acta., 31A, No. 9, 1975–1979 (1975).

    CAS  Google Scholar 

  21. J. N. Spenser, S. K. Berger, K. R. Powell, et al., J. Phys. Chem., 85, No. 9, 1236–1241 (1981).

    Article  Google Scholar 

  22. T. B. Hoover, ibid., 73, No. 1, 57–61 (1969).

    Article  CAS  MathSciNet  Google Scholar 

  23. Yu. G. Bushuev and V. P. Korolev, Concentrated and Saturated Solutions [in Russian], Nauka, Moscow (2002), pp. 255–313.

    Google Scholar 

  24. T. Sato, A. Chiba, and R. Nozaki, J. Chem. Phys., 112, No. 8, 2924–2930 (2000).

    Article  ADS  CAS  Google Scholar 

  25. M. R. Dack, Austral. J. Chem., 28, No. 8, 1643–1648 (1975).

    Article  CAS  Google Scholar 

  26. A. Holtzer and M. F. Emerson, J. Phys. Chem., 73, No. 1, 26–35 (1969).

    Article  CAS  Google Scholar 

  27. V. A. Durov Nonelectrolyte Solutions in Liquids [in Russian], Nauka, Moscow (1989), pp. 36–102.

    Google Scholar 

  28. N. B. Vargaftik, Handbook on Thermophysical Properties of Gases and Liquids [in Russian], Nauka, Moscow (1972).

    Google Scholar 

  29. G. Barone, G. Castronuovo, G. Della Gatta, et al., Fluid Phase Equil., 21, Nos. 1/2, 157–164 (1985).

    Article  CAS  Google Scholar 

  30. A. M. Zaichikov and M. A. Krest’yaninov, Zh. Obsh. Khim., 74, No. 11, 1789–1796 (2004).

    Google Scholar 

  31. A. M. Zaichikov, Zh. Strukt. Khim., 47, Supplement, S77–S84 (2006).

    Google Scholar 

  32. G. G. Karamyan and M. I. Shakhparonov, Modern Problems of Physical Chemistry [in Russian], MGU, Moscow (1980), pp. 306–330.

    Google Scholar 

  33. F. Hammami, S. Nasr, M. Oumezzine, and R. Cortes, Biomol. Engin., 19, No. 1, 201–205 (2002).

    Article  CAS  Google Scholar 

  34. S. Trabelsi and S. Nasr, J. Chem. Phys., 121, No. 13, 6380–6385 (2004).

    Article  PubMed  ADS  CAS  Google Scholar 

  35. J. Gao, J. J. Pavelites, and D. Habibollazadeh, J. Phys. Chem., 100, No. 7, 2689–2697 (1996).

    Article  CAS  Google Scholar 

  36. V. A. Durov and B. D. Bursulaya, Zh. Fiz. Khim., 65, No. 8, 2066–2070 (1991).

    CAS  Google Scholar 

  37. J. N. Spenser, R. C. Garret, F. J. Mayer, et al., Canad. J. Chem., 58, No. 5, 1372–1375 (1980).

    Article  Google Scholar 

  38. M. Lindheimer, G. Etienne, and B. Brun, J. Chim. Phys., 5, No. 4, 829–837 (1972).

    Google Scholar 

  39. Y. Koga, J. Phys. Chem., 100, No. 13, 5172–5181 (1996).

    Article  CAS  Google Scholar 

  40. M. I. Davis and M. E. Hernandez, J. Chem. Eng. Data., 40, No. 3, 674–678 (1995).

    Article  CAS  Google Scholar 

  41. J. Zielkiewicz, J. Chem. Thermodyn., 31, No. 12, 1597–1604 (1999).

    Article  CAS  Google Scholar 

  42. J. F. Hinton and K. H. Ladner, Spectrochim. Acta., 28A, No. 9, 1731–1740 (1972).

    Google Scholar 

  43. A. S. Lileev, Doctoral Dissertation in Chemistry, Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow (2004).

    Google Scholar 

  44. G. Eaton, M. C. R. Symons, and P. P. Rastogi, J. Chem. Soc., Faraday Trans. I, 85, No. 10, 3257–3271 (1989).

    Article  CAS  Google Scholar 

  45. J. G. Kirkwood and F. P. Buff, J. Chem. Phys., 19, No. 6, 774–777 (1951).

    Article  CAS  MathSciNet  Google Scholar 

  46. Y. Marcus, J. Chem. Soc., Faraday Trans. I, 86, No. 12, 2215–2224 (1990).

    Article  CAS  Google Scholar 

  47. J. Zielkiewicz, J. Chem. Thermodyn., 27, No. 11, 1275–1279 (1995).

    Article  CAS  Google Scholar 

  48. J. Zielkiewicz, ibid., 31, No. 8, 819–825 (1999).

    Article  CAS  Google Scholar 

  49. J. Zielkiewicz, ibid., 28, No. 8, 887–894 (1996).

    Article  CAS  Google Scholar 

  50. E. Matteoli, J. Phys. Chem. B, 101, No. 47, 9800–9810 (1997).

    Article  CAS  Google Scholar 

  51. I. M. Klotz and J. S. Franzen, J. Am. Chem. Soc., 84, No. 18, 3461–3466 (1962).

    Article  CAS  Google Scholar 

  52. A. I. Mishustin and Yu. M. Kessler, Zh. Strukt. Khim., 15, No. 1, 205–209 (1974).

    CAS  Google Scholar 

  53. R. Zhang, H. Li, Y. Lei, and S. Han, J. Phys. Chem. B, 108, No. 33, 12596–12601 (2004).

Download references

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, Russia

    A. M. Zaichikov

Authors
  1. A. M. Zaichikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text Copyright © 2007 by A. M. Zaichikov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 1, pp. 95–104, January–February, 2007.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zaichikov, A.M. Structural thermodynamic parameters and intermolecular interactions in aqueous solutions of secondary amides. J Struct Chem 48, 94–103 (2007). https://doi.org/10.1007/s10947-007-0014-z

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-007-0014-z

Keywords

Search

Navigation